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991.
Rechargeable batteries with flexibility can find tremendous applications in wearable and bendable electronics. One central mission for the advancement of such high‐performance batteries is the exploration of flexible anodes with electrochemical and mechanical robustness. Herein reported is a robust and flexible sodium‐ion anode based on self‐supported hematite nanoarray grown on carbon cloth. The ammonia treatment that results in dual doping of both nitrogen and low‐valent iron renders surface reactivity and electric conductivity to the material. The dual‐doped hematite arrays afford a robust activity for sodium storage, exhibiting reversible capacities of 895 and 382 mAh g?1 at current rates of 0.1 and 5 A g?1, respectively, or 615 and 356 mAh g?1 by removing the contribution of the substrate. They also sustain 85% of the initial capacity upon 200 cycles at 0.2 A g?1. To demonstrate the flexibility, full cells composed of a hematite array anode and Na3V2(PO4)3/C cathode are assembled. The cell is capable of affording an energy density of 201 Wh kg?1 and sustaining repeated bending without performance decay, demonstrating a significant potential in practical application. 相似文献
992.
Janghoon Woo Hyeokjun Lee Changyoon Yi Jaehong Lee Chihyeong Won Saehyuck Oh Janghwan Jekal Chaebeen Kwon Sanggeun Lee Jaekang Song Byungwoo Choi Kyung‐In Jang Taeyoon Lee 《Advanced functional materials》2020,30(29)
Stretchable interconnects with invariable conductivity and complete elasticity, which return to their original shape without morphological hysteresis, are attractive for the development of stretchable electronics. In this study, a polydimethylsiloxane‐coated multifilament polyurethane‐based helical conductive fiber is developed. The stretchable helical fibers exhibit remarkable electrical performance under stretching, negligible electrical and mechanical hysteresis, and high electrical reliability under repetitive deformation (10 000 cycles of stretching with 100% strain). The resistance of the helical fibers barely increases until the applied strain reaches the critical strain, which is based on the helical diameter of each fiber. According to finite element analysis, uniform stress distribution is maintained in the helical fibers even under full stretching, owing to the fibers' true helix structure. In addition, the stretchable helical fibers have the ability to completely return to their original shapes even after being fully compressed in the vertical direction. Cylinder‐shaped connecting pieces made using 3D printing are designed for stable connection between the helical fibers and commercial components. A deformable light‐emitting diode (LED) array and biaxially stretchable LED display are fabricated using helical fibers. A skin‐mountable band‐type oximeter with helical fiber‐based electrodes is also fabricated and used to demonstrate real‐time detection of cardiac activities and analysis of brain activities. 相似文献
993.
Ziyu Wang Xuejie Zhu Shengnan Zuo Ming Chen Cong Zhang Chenyu Wang Xiaodong Ren Zhou Yang Zhike Liu Xixiang Xu Qing Chang Shaofei Yang Fanying Meng Zhengxin Liu Ningyi Yuan Jianning Ding Shengzhong Liu Dong Yang 《Advanced functional materials》2020,30(4)
Multijunction/tandem solar cells have naturally attracted great attention because they are not subject to the Shockley–Queisser limit. Perovskite solar cells are ideal candidates for the top cell in multijunction/tandem devices due to the high power conversion efficiency (PCE) and relatively low voltage loss. Herein, sandwiched gold nanomesh between MoO3 layers is designed as a transparent electrode. The large surface tension of MoO3 effectively improves wettability for gold, resulting in Frank–van der Merwe growth to produce an ultrathin gold nanomesh layer, which guarantees not only excellent conductivity but also great optical transparency, which is particularly important for a multijunction/tandem solar cell. The top MoO3 layer reduces the reflection at the gold layer to further increase light transmission. As a result, the semitransparent perovskite cell shows an 18.3% efficiency, the highest reported for this type of device. When the semitransparent perovskite device is mechanically stacked with a heterojunction silicon solar cell of 23.3% PCE, it yields a combined efficiency of 27.0%, higher than those of both the sub‐cells. This breakthrough in elevating the efficiency of semitransparent and multijunction/tandem devices can help to break the Shockley–Queisser limit. 相似文献
994.
Fabiola Navarro‐Pardo Jiabin Liu Omar Abdelkarim Gurpreet S. Selopal Aycan Yurtsever Ana C. Tavares Haiguang Zhao Zhiming M. Wang Federico Rosei 《Advanced functional materials》2020,30(14)
The synergistic effects derived from optimizing the chemical and structural features of electrocatalysts permit them to attain remarkable activity and stability. Herein, 1D/2D cobalt‐based nanohybrid (CoNH) electrodes are developed; the structural design consists of Co3O4 electrospun nanoribbons (NRs) deposited onto a carbon fiber paper substrate where Co3O4 nanosheets are subsequently grown via an electrodeposition step and UV/ozone treatment. The content of noncovalently functionalized carbon nanotubes within the Co3O4 NRs is first tuned to enhance their charge transfer properties and mechanical stability. The electrocatalytic activity of the electrodes is further improved by a phosphorus modification of the 1D NRs, resulting in the formation of NaCoPO4. The optimized 1D/2D CoNH electrode, i.e., ED‐0.09 wt% fCNTs/P‐CoNHs, displays a similar performance to that of platinum in 0.25 m Na2S/0.35 m Na2SO3 (Tafel slope ≈102 mV dec?1 for the former and ≈96 mV dec?1 for the latter) and outstanding stability for up to 48 h. The versatility and high activity of this electrode is also demonstrated according to tests in a conventional water splitting system (cell voltage 1.55V, to produce 10 mA cm?2) and a solar‐driven electrolyzer (1 m KOH). 相似文献
995.
Ting Liu Jirong Mou Ziping Wu Chao Lv Jianlin Huang Meilin Liu 《Advanced functional materials》2020,30(36)
The large‐scale fabrication of efficient and inexpensive bifunctional catalysts is highly desirable but very challenging for oxygen reduction reaction and oxygen evolution reaction (ORR–OER) in metal–air batteries. Here, a facile and scalable approach for the fabrication of hierarchically porous air electrode consisting of cobalt nanoparticles embedded in bamboo‐like nitrogen‐rich carbon nanotubes (Co/N@CNTs), which are in situ grown onto the surface of carbon nanotube macrofilm (CNMF) through a catalytic growth of crosslinked carbon nanotubes is reported. The resulting hybrid macrofilm (Co/N@CNTs@CNMF) can be directly used as a freestanding air electrode without adding any binder or addivities. More importantly, when incorporated in a zinc–air battery (ZAB), the Co/N@CNTs@CNMF electrode demonstrates drastically enhanced ORR and OER activity while maintaining excellent durability during cycling. Further, when it is used to assemble an all‐solid‐state ZAB, the cell also displays excellent mechanical flexibility, implying promising perspectives as power sources for wearable electronics. 相似文献
996.
设计了一个双并联电渗驱动泵,它由三条并联的主通道和叉指型电极两部分组成,其中每条主通道由若干个与电渗流形成方向成45°角的沟槽并联构成。通过选用ITO载玻片作为芯片基底并获得其最佳工艺参数,制作了带电极的PDMS-玻璃微流控芯片。最后对制作的电渗微泵进行测试,通过记录一段时间内单个主通道泵输送液体的体积,得出单个主通道的流速与微泵总流速。实验发现在5V内,微泵泵送液体的能力随着电压的增加而增大,微泵流速可以达到正常人体眼球房水生成速度,该结构在未来房水引流器件制作方面具有潜在的应用价值。 相似文献
997.
998.
Design, fabrication and characterization of a high fill-factor micromirror array for wavelength selective switch applications 总被引:1,自引:0,他引:1
Sihua LiAuthor Vitae Jing XuAuthor Vitae Shaolong ZhongAuthor Vitae Yaming WuAuthor Vitae 《Sensors and actuators. A, Physical》2011,171(2):274-282
This paper presents the design, fabrication and characterization of a high fill-factor micromirror array in application of wavelength selective switch (WSS). The micromirror array consists of 52 independent micromirrors. Each micromirror is composed of a cantilever-type micromirror plate (800 μm × 120 μm) with a bumper and an eight-terraced bottom electrode with a limiting plane. A cantilever beam is designed to obtain the rotation angle of micromirror plate and achieve a high fill-factor for the micromirror array. Meanwhile, the bumper and limiting plane are used to prevent the damage possibly caused by the pull-in effect or some vibration instance. An eight-terraced electrode is utilized for reducing the driving voltage. The micromirror array with a high fill-factor in excess of 97% has been successfully achieved using the bulk micromachining technologies. The measured static and dynamic characteristics show that the micromirror can achieve a maximal rotation angle of 0.87° with a Direct Current (DC) driving voltage of 156 V. The turn-on responding time is 0.57 ms, and the turn-off responding time is 4.36 ms. Furthermore micromirror plate can be easily released from the pull-in state without damaged due to the novel bumper design. The switching function between the two output ports of a WSS optical system has also been demonstrated. 相似文献
999.
Rosanne M. GuijtAuthor Vitae James P. ArmstrongAuthor VitaeEsme CandishAuthor Vitae Veronica LefleurAuthor VitaeWilliam J. PerceyAuthor Vitae Sergey ShabalaAuthor VitaePeter C. HauserAuthor Vitae Michael C. BreadmoreAuthor Vitae 《Sensors and actuators. B, Chemical》2011,159(1):307-313
A simple and low budget microfabrication method compatible with mass production was developed for the integration of electrodes for capacitively coupled contactless conductivity detection (C4D) in Lab on a Chip devices. Electrodes were patterned on a printed circuit board using standard processing. This was followed by lamination-photolithography-lamination to cover the electrodes in dry film photoresist (DFR) using an office laminator. This resulted in a flush, smooth surface on top of the detection electrodes, enabling subsequent integration of a microfluidic network at a distance dictated by the thickness of the DFR (17 μm, 30 μm and 60 μm were used in this work). This process was applied to create two types of detectors, re-usable detectors to be used in combination with a separate microfluidic network and integrated detectors where the microfluidic network is irreversibly sealed to the detector. A poly(dimethylsiloxane) (PDMS) slab containing the microfluidic network was positioned on top of the re-usable detectors to create the PDMS hybrid devices. The integrated DFR devices were created by patterning and sealing the microchannel in DFR using subsequent lamination and lithographic steps. The sensitivity of the C4D made using this new technology for small inorganic cations was between 6 and 20 μM, which is comparable with devices made using significantly more advanced technologies. Where the 17 μm film slightly improved the sensitivity, the use of 30 μm thick insulating films was preferred as these did not impose significant restrictions on the applicable field strengths. 相似文献
1000.
Panagiotis A. DimovasilisAuthor VitaeMamas I. ProdromidisAuthor Vitae 《Sensors and actuators. B, Chemical》2011,156(2):689-694
The development of a preconcentrating sensor based on 6-O-palmitoyl-l-ascorbic acid (PAA)-modified graphite (GRA) electrodes for the determination of uranium is described. PAA, a water insoluble compound of ascorbic acid, was immobilized onto the surface of the GRA electrodes through physical adsorption from acetone solutions. Uranium was accumulated by heterogeneous complexation (10 min, in 0.1 M H3BO3, pH 4.3) and then, it was reduced by means of a differential pulse voltammetric scan in 0.1 M H3BO3, pH 3.4. Alternatively, the performance of both preconcentration and voltammetric steps in a single run, at 0.1 M H3BO3, pH 3.65, was also examined; however, in this case the observed current signals were lower by 30%. The experimental variables were investigated and under the selected conditions, a linear calibration curve in the range 2.7-67.5 μg L−1 U(VI) was constructed (r2 = 0.9981). The 3σ limit of detection and the relative standard deviation of the method were 1.8 μg L−1 U(VI) and 8% (n = 5, 20 μg L−1 U(VI), preconcentration time 10 min), respectively. By increasing the preconcentration time to 30 min, a limit of detection as low as 0.26 μg L−1 U(VI) can be achieved. The effect of potential interferences was also examined. The accuracy of the method was established by recovery studies in inoculated tap and lake water samples. A simple and fast procedure based on filtering of the sample through a C-18 microcolumn was successfully used to remove the organic matter from the lake water samples. 相似文献