5Cr套管钢在不同CO2分压下高温高压腐蚀特性研究

为了研究5Cr套管钢在不同CO₂分压下的腐蚀特性,进行了5Cr套管钢高温高压腐蚀失重和高温高压电化学试验,并采用XRD、SEM和EDS等手段对其腐蚀产物进行微观分析。结果表明,在高温高压腐蚀环境下随着CO₂分压从低到高,其表面点蚀坑的深度和直径均无明显变化,而点蚀速率则出现逐渐减小的趋势;其腐蚀产物膜由Cr(OH)₃、FeCO₃和CaCO₃共同组成,且随着CO₂分压的升高Cr的富集量逐渐增加;在电化学测试中,随着CO₂分压的不断升高,5Cr套管钢表现出半钝化特征,产物膜逐渐增厚且致密,且极化电阻逐渐增大,阳极反应受到抑制,电化学反应阻力增大,其抗局部腐蚀能力不断提高。     

上覆不同储盖组合油源断裂输导油气时期厘定方法及其应用

为研究含油气盆地油源断裂带附近不同储盖组合的油气富集规律,在上覆不同储盖组合油源断裂输导油气时期研究的基础上,通过确定油源断裂活动时期、源岩排烃时期和区域性泥岩盖层渗漏时期,组合三者建立了一套上覆不同储盖组合油源断裂输导油气时期的厘定方法。实例应用结果表明：渤海湾盆地歧口凹陷上覆沙一下亚段储盖组合南大港断裂输导油气时期为馆陶组至明化镇组沉积时期,有利于油气在沙一下亚段聚集成藏;上覆东三段储盖组合南大港断裂输导油气时期为明化镇组沉积中期至末期,不利于油气在东三段聚集成藏;上覆馆陶组储盖组合南大港断裂输导油气时期为零,无油气在馆陶组聚集成藏。这与南大港断裂附近目前已发现油气在沙一下亚段相对较多,东三段相对较少和馆陶组无相吻合,表明该方法用于厘定上覆不同储盖组合油源断裂输导油气时期是可行的。     

Annealing effects on the structure and hardness of helium-irradiated Cr2AlC thin films

Cr₂AlC MAX phase thin films prepared by radio-frequency magnetron sputtering were irradiated at room temperature by 100 keV helium ions to a fluence of 1 × 10¹⁷ ions cm⁻². The effects of thermal annealing on the structural and mechanical properties of the helium-irradiated Cr₂AlC films as well as the helium release were investigated by grazing-incidence X-ray diffraction (GIXRD), Raman spectroscopy, and scanning electron microscope (SEM) in combination with nano-indentation and elastic recoil detection (ERD) analysis. The irradiation-induced structural damage in the Cr₂AlC is significantly recovered by thermal annealing at temperatures around 600℃, attributed to high defect diffusivity. After annealing to 750℃, the hardness of irradiated films recovered almost completely, which is ascribes to both defect recombination and reformation of damaged chemical bonds. Substantial helium release occurring at this annealing temperature is closely related to the damage recovery due to helium irradiation.     

Electromagnetic wave absorbing properties of Cr2AlB2 powders and the effect of high-temperature oxidation

The electromagnetic (EM) wave absorbing properties of Cr₂AlB₂ powders and those after high-temperature oxidation were investigated. Coupling of magnetic and dielectric loss enables Cr₂AlB₂ with good absorption properties. The minimum reflection loss (RL) value is −44.9 dB at 8.5 GHz with a thickness of 2.7 mm, and the optimized effective absorption bandwidth (E_AB) is 4.4 GHz (13.0-17.4 GHz) with a thickness of 1.6 mm. After oxidation at 750, 900, and 1000°C for 2 h, the minimum RL values, respectively, are −23.9 dB (17.5 GHz, 1.5 mm), −41.4 dB (16.5 GHz, 1.5 mm), and −39.5 dB (8.0 GHz, 3.0 mm); and the corresponding E_AB values, respectively, are 3.8 GHz (13.6-17.4 GHz, 1.7 mm), 4.1 GHz (13.5-17.6 GHz, 1.6 mm), and 4.4 GHz (13.0-17.4 GHz, 1.7 mm). With an absorber thickness of 1.5-4.0 mm, the E_AB with a RL value of less than −10 dB can be tuned in a broad-frequency range 5.0-18.0 GHz, which basically covers C (4-8 GHz), X (8-12 GHz), and Ku (12-18 GHz) bands. These results demonstrate that Cr₂AlB₂, as a high-efficient and oxidation-resistant absorber, is a promising candidate for microwave absorption applications and can retain good EM wave absorbing properties after high-temperature oxidation.     

形变与热处理对CuCr合金中Cr相形貌及合金性能的影响

研究了CuCr合金在不同形变与热处理制度下，组织中Cr相形貌、合金力学性能及导电性能的变化。结果表明：当变形量达到70％时，合金中的Cr粒子产生严重的变形，且有开裂现象。在随后高温热处理过程中开裂的Cr粒子发生熔断和球化。适当的形变与热处理能改善CuCr合金的力学性能与导电性能，并从微观组织方面对其原因进行了分析。     

高碳Cr—Mo—W钢M／B复相组织疲劳行为研究

用紧凑拉伸试样测定了65Cr5Mo3W2VSiTi(LM2)钢不同贝氏体量和不同回火温度的M/B复相组织的疲劳裂纹扩展速率,根据试验数据估算了各工艺的疲劳门槛值。结果表明,LM2钢M/B复相组织的疲劳裂纹扩展属非连续扩展机制,疲劳裂纹微观扩展速率的计算值和宏观扩展速率的实测值相近     

20Cr11MoVNbNB钢的蠕变性能与组织的关系

研究了20Cr11MoVNbNB钢550—650℃的蠕变性能及组织的变化,发现在550℃,蠕变应力>180MPa时,过渡蠕变应变和蠕变时间的ε_β-ι~(1/3)关系中,呈现前期斜率β_1大于后期β_2的两段线性关系;550℃稳态蠕变速率可用■=Aσ~nexp(-Q_c/RT)来表示,其中n=4.7,Aexp(-Q_c/RT)=5.37×10_(-16);550—650℃的表观蠕变激活能Q_c=430kJ/mol,其值远大于基体Fe原子的自扩散激活能;发现在蠕变过程中,随蠕变应力和蠕变时间增加,沉淀相的总量和其中的Cr,Mo,V含量增加,Fe和Nb含量则下降。     

急冷Ni-Cr-B合金箔带钎料的制备及其可焊性

采用液态急冷单辊法制备了急冷Ni-Cr-B中间合金箔带。利用DSC ,XRD和SEM等方法对急冷Ni-Cr-B合金箔带的固液相线的温度 ,结构及成分分布进行了研究。利用液态金属表面张力仪测定了急冷Ni-Cr-B合金箔带在镍基高温合金上的润湿性。并采用此中间合金对镍基高温合金进行了瞬态液相连接 (TLPBonding) ,测定了连接后的试棒在 10 10℃ / 2 48MPa下的持久寿命。结果表明 ,制备的Ni-Cr -B合金箔带成分均匀 ,熔点适于TLP连接。液态钎料对镍基高温合金基体具有良好的润湿性。采用这种中间合金对镍基高温合金进行TLP连接后的接头持久性能接近于母材     

热处理对1Cr18Ni9Ti钢焊接接头性能的影响

试验研究了固溶＋稳定化处理、固溶处理和去应力退火处理对1Cr18Ni9Ti钢焊接接头力学性能的影响。结果表明：固溶＋稳定化处理试样的屈服强度、伸长率、抗拉强度均最高。扫描电镜观察结果表明：所有的断口均为韧窝型断裂。     

压缩机叶轮用钢——X12Cr13锻件工艺研究

通过对X12Cr13钢中奥氏体与铁素体的相匹配关系的研究,确定出该钢种合理的化学成分和合理的加热及热处理制度,解决了该钢在轧制、锻造等压力加工过程中易产生裂纹的问题。