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221.
In this review, the progress made in the last ten years concerning the synthesis of porous carbon materials is summarized. Porous carbon materials with various pore sizes and pore structures have been synthesized using several different routes. Microporous activated carbons have been synthesized through the activation process. Ordered microporous carbon materials have been synthesized using zeolites as templates. Mesoporous carbons with a disordered pore structure have been synthesized using various methods, including catalytic activation using metal species, carbonization of polymer/polymer blends, carbonization of organic aerogels, and template synthesis using silica nanoparticles. Ordered mesoporous carbons with various pore structures have been synthesized using mesoporous silica materials such as MCM‐48, HMS, SBA‐15, MCF, and MSU‐X as templates. Ordered mesoporous carbons with graphitic pore walls have been synthesized using soft‐carbon sources that can be converted to highly ordered graphite at high temperature. Hierarchically ordered mesoporous carbon materials have been synthesized using various designed silica templates. Some of these mesoporous carbon materials have successfully been used as adsorbents for bulky pollutants, as electrodes for supercapacitors and fuel cells, and as hosts for enzyme immobilization. Ordered macroporous carbon materials have been synthesized using colloidal crystals as templates. One‐dimensional carbon nanostructured materials have been fabricated using anodic aluminum oxide (AAO) as a template. 相似文献
222.
Jinyong ZHANG+ Zhengyi FU Weimin WANGState Key Lab of Advanced Technology for Materials Synthesis Processing Wuhan University of Technology Wuhan China 《材料科学技术学报》2005,21(6):841-844
1. IntroductionTitanium diboride ceramic has some special proper-ties, such as high melting points, high hardness, highelectrical and thermal conductivity. These special prop-erties make it has a great potential to be used as contactmaterials. However, this application is still limited forpoor sinterability and brittle of TiB2[1~3]. To improve itssinterability and toughness, some metals were selected asadditives for liquid phase sintering of TiB2. Metals likeFe, Co and Ni were studied in m… 相似文献
223.
Theiron basedcatalystsforammoniasynthesishavethecommonproblemsoflowefficiency ,highconsumptionofenergy ,strictrequirementforequip ment,andlowoperationflexibility ,etc .,anditishardtoradicallylowerenergyconsumptionbysimplyimprovingiron basedcatalystsproper… 相似文献
224.
采用燃烧合成技术制备了相对密度为90%左右的TiB2—40Cu-8Ni金属陶瓷复合材料。为进一步提高复合材料的力学性能,首先研究了TiB2—40Cu金属一陶瓷高温压缩弹塑性变形行为,证明了高陶瓷体积分数下金属陶瓷在高温环境中具有一定的塑性行为;然后分别在1200℃、1250℃、1300℃温度下对复合材料进行二次热压,详细研究了TiB2—40Cu-8Ni复合材料液一固两相区间的变形行为、组织特征及力学性能的变化。结果表明:经过二次热压后,材料的相对密度和抗弯强度有了较大幅度的提高,在1300℃时,材料的相对密度提高了5%,抗弯强度达到608MPa。复合材料中TiB2颗粒的形貌也发生了改变,大部分由原来的等轴状转变为长棒状,同时根据TiB2晶体结构特征,分析了复合材料中TiB2的生长机制。 相似文献
225.
将稀土固体超强酸与微波辐射技术相结合研究蔗糖酯的合成,考察了微波辐射功率、反应时间、催化剂、乳化剂对反应的影响。结果表明,当辐射功率为390W、反应时问为20min时,稀土固体超强酸Gd^3+(Y^3+)-SO4^2-/ZrO2对合成蔗糖酯的催化活性优于常规催化剂无水碳酸钾。并且微波辐射使反应时间从传统减压加热4~8h缩短到常压反应20min。 相似文献
226.
227.
Achim Müller Olga Heim M. Panneerselvam Monika Willert-Porada 《Materials Research Bulletin》2005,40(12):2153-2169
A modified microwave-assisted polyol method was applied to prepare nanoparticulate ceramic powders of different oxides, i.e. Gd2O3, AlO(OH) (boehmite) and TiO2. Due to the good dielectric properties of the utilised solvents, such as ethylene glycol, diethylene glycol and 1,4 butanediol, a significant decrease in reaction time was achieved under microwave heating. In the case of AlO(OH) and Gd2O3, <5 nm primary particle size were obtained. Boehmite was found to be intercalated with the solvent. The general applicability of the process is shown and the advantages in terms of properties and processibility are described. The powders thus prepared were investigated using X-ray diffractometry, electron microscopy and physisorption. 相似文献
228.
C. Lpez-Mata M.E. Nicho Hailin Hu G. Cadenas-Pliego E. García-Hernndez 《Thin solid films》2005,490(2):189-195
Poly3-octylthiophene (P3OT) was synthesized by direct oxidation of 3-octylthiophene using FeCl3 as oxidant/catalyst. It was observed that the purity of FeCl3 affected the molecular weight and polydisparity as well as the degree of regioregularity of the polymer, measured by size exclusion chromatography and by 1H nuclear magnetic resonance, respectively. Optical absorption properties of the P3OT films were analyzed as a function of solution concentration, the type of the substrates and the mole percentage of the doping agent. Morphology study with atomic force microscopy indicates that the surface roughness and the cluster size of the polymeric films are influenced by the P3OT solution concentration and the percentage molarity of ferric chloride. FeCl3 doped P3OT films show enlarged clusters compared with the pristine one due to the introduction of FeCl3 molecules in the original P3OT chains, a phenomenon observed in electrochemically doped heterocyclic conducting polymers reported in the literature. 相似文献
229.
Pb(Zr0.4Ti0.6)O3 [PZT(40/60)] thin films were deposited onto LaNiO3 (LNO) coated Si substrates by sol-gel technique. Three kinds of gases, air, O2 and N2, were used as the annealing ambient. The effect of the annealing ambient on their structure and ferroelectric properties was investigated. The results showed that both the films annealed in air and O2 were the complete perovskite phase with (1 0 0) preferential orientation, while those annealed in N2 were random orientation including some pyrochlore phases. As compared with the air ambient, either too much O2 or too much N2 was detrimental to the ferroelectric properties of PZT films. The difference in structure and ferroelectric properties was mainly associated with the intermediate phases and the concentration of domain pinning centers in the films. 相似文献
230.
Yu Qiu 《Materials Research Bulletin》2005,40(5):794-799
Novel blue-emitting cyanuric acid-melamine complexes CAx·M1−x (x = 0.8-0.9) have been prepared by a simple two-step procedure from urea. Relatively strong and pure blue-light emission with a maximum at 470 nm was observed from these complexes. These complexes are very promising light-emitting materials due to their good thermal stability. 相似文献