聚氨酯软泡压陷性能的测试

介绍了软质聚氨酯泡沫塑料压陷性能的测试标准，不同厚度样品的压陷硬度测试值的差异，采用50%压缩负荷估计压陷硬度的简易测试方法，以及压陷性能测试的影响因素，并对测试聚氨酯软泡压陷性能的国家标准与国外标准的差别进行了比较。     

Hydrodynamic drag forces on two porous spheres moving along their centerline

This paper numerically evaluates the hydrodynamic drag force exerted on two highly porous spheres moving steadily along their centerline (sphere #1 and sphere #2) through a quiescent Newtonian fluid over a Reynolds number ranging from 0.1 to 40. At creeping flow limit, the drag forces exerted on both spheres were identical. At higher Reynolds numbers the drag force on sphere #1 was higher than sphere #2, revealing the shading effects produced by sphere #1 on sphere #2. At dimensionless diameter (β, =d_f/2k^0.5, d_f and k are floc diameter and interior permeability, respectively) >20, the spheres can be regarded nonporous. At β<20, the drag forces dropped. At β<2, the drag forces approached “no-spheres” limit. An increased size ratio of two spheres (d_f1/d_f2) would increase the drag force on sphere #1 and reduce that on sphere #2. At increasing β for both spheres, the drag force on sphere #2 was increased because of the more difficult advective flow through its interior, and at the same time the drag was reduced owing to the stronger wake flow produced by the denser sphere #1. The competition between these two effects leads to complicated dependence of drag force on sphere #2 on β value. These effects were minimal when β became low. Two identical spheres could move steadily along their centerline. At higher Reynolds number, the two spheres would move closer because of the incorporation of inertia force. For spheres of different diameters, the sphere # 2 would move faster than sphere #1 regardless of their size ratio and β value. This occurrence yielded efficient coagulation when two porous spheres were moving in-line.     

Relationship between chemical degradation and thickness loss of an amine-cured epoxy coating exposed to different UV environments

The relationship between chemical degradation and thickness loss of an unpigmented, non UV-stabilized, crosslinked amine-cured epoxy coating exposed to three UV conditions was investigated. Spin-coated samples having a thickness of approximately 7 μm on an Si substrate were prepared from a stochiometric mixture of a bisphenol A epoxy resin and a tetra-functional amine curing agent. Samples were exposed outdoors and to two accelerated laboratory UV environments. Chemical degradation and thickness loss were measured by transmission Fourier transform infrared spectroscopy (FTIRS) and laser scanning confocal microscopy (LSCM), respectively. In addition, surface roughness and morphological changes were measured by atomic forcemicrosocopy (AFM) and LSCM. Substantial chemical degradation, thickness loss, and morpholocal changes occurred in the exposed films, and the rate of chemical degradation was greater than that due to the thickness loss. This additional chemical loss was attributed to an inhomogeneous degradation process in which nanoscale localized depressions initiate at certain sites on the surface, which then enlarge and deepen with exposure time. The results of this study provide a better understanding of the degradation mechanism and should lead to the development of scientific-based models for predicting the service life of crosslinked amine-cured epoxy coatings. Presented at the 82nd Annual Meeting of the Federation of Societies for Coatings Technology, October 27–29, 2004, in Chicago, IL     

Experimental investigation on possibility of oxygen enrichment by using gradient magnetic fields

This paper presents a novel method that uses the interception effect of gradient magnetic field on oxygen molecules to realize enrichment. The use of two opposite magnetic poles of two magnets at a certain distance forms a magnetic space having a field intensity gradient near its borders. When air injected into the magnetic space outflows from the magnetic space via its borders, oxygen molecules in the air will experience the interception effect of the gradient magnetic field, but nitrogen molecules will outflow from the magnetic space without hindrance. Thus, continuous oxygen enrichment is realized. The enrichment degree of oxygen reaches 0.65% when the inlet and outlet air flows are 40 mL/min and 20 mL/min, respectively, and the gas temperature is 298 K and the maximal product of magnetic flux density and its gradient is 563 T²/m (the distance between two magnetic poles is 1 mm). When the gas temperature rises to 343 K, the enrichment degree drops to 0.32%; and when the maximal product of magnetic flux density and field intensity gradient drops to 101 T²/m (the distance between two magnetic poles is 4 mm), the enrichment degree drops to 0.23%. The experimental results show that there is an optimal ratio between the inlet air flow and the outlet air flow. Under the experimental conditions in this paper, the value is about 2.0. It is demonstrated that the method presented in this paper can continuously enrich oxygen and has a higher enrichment degree than other oxygen-enrichment methods using magnetic separation. Translated from Journal of Beijing University of Chemical Technology, 2006, 33(5): 62–66 [译自: 北京化工大学学报]     

Immobilization of biologically active species on PA‐6 foils treated by a dielectric barrier discharge

In the field of biomaterials and biomedical devices, surface activation has been focused on creating functional groups capable of preferential adsorption of biologically active species (proteins, enzymes, cells, drugs, etc.). In this way an interface can be created between the synthetic material and the biological medium, with the aim of increasing the compatibility of the implant with the human organism. In our experiments a dielectric barrier discharge (DBD), in helium at atmospheric pressure, was used as the source of energy capable of creating active centers that render the functionalized surface favorable to immobilization of biological molecules. Retention of immunoglobulin (IgG) and heparin biomolecules on polyamide‐6 (PA‐6) surfaces after treatment by the DBD was analyzed by atomic force microscopy, adhesion evaluation, and measurement of the contact angle titration in order to assess this incorporation on the treated surfaces. The marked adsorption of the biomolecules on the active sites created by DBD on the exposed surfaces also was related to a complex set of processes, such as enhanced roughness, increased surface wettability, and modified distribution of cationic and anionic groups on the treated surfaces. All these factors could promote interfacial interactions between the specific groups of the biomolecules existing in the biological medium and the type of cationic and/or anionic groups present on the surface. The efficiency of the DBD treatment showed that the DBD technique is useful for preactivation of the polymer surface for immobilization of other biologically active species (such as drugs and enzymes). © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 1985–1990, 2003     

垃圾焚烧管式布风流化床的冷态实验

在床截面为300mm×300mm、床高为4. 4m的管式布风流化床实验台上,分别对宽筛分下不同颗粒粒度、不同床层高度、不同截面流速、布风的均匀性以及非平衡布风时颗粒流化特性进行实验研究,为未来垃圾衍生燃料的流化燃烧实验提供基础数据。管式布风流化床的开孔方向与夹角大小对床层压降变化影响明显,向下开孔角度越小,动能消耗越大,但床层稳定性能好。随着料层高度增加,各布风管间的布风更趋于平衡,流化的稳定与均匀性能也越好。管组压降失衡时,床层压降不平衡明显增加,波动幅度增大,不稳定性明显高于正常流化状态。     

聚合物合成及成型加工中协同学的应用

综述了协同学在聚合物领域的最新研究进展，介绍了加工制备一些聚合物合成及复合材料所显示出的协同效应，以及用协同学方法定量求解一类合成反应体系的动力学模型。提出通过改变振动力场等作用方式，在聚合物动态塑化成型加工时，协同学方法具有广阔的应用前景。     

电动汽车机电复合制动力分配策略研究

为了实现再生制动力与机械制动力在驱动轮和从动轮之间的优化分配,在保证车辆制动安全的同时提高能量回收效率,将汽车理想制动力分配I曲线与模糊算法相结合,提出一种基于模糊控制的电动汽车机电复合制动力分配策略。设计了电动汽车再生制动力分配模糊控制器,根据车辆工况与理想制动力分配I曲线,计算前后轮上分别应加载的机电复合制动力大小。建立了电动汽车制动系统动力学仿真模型,在此基础上进行仿真分析。最后利用Advisor仿真软件对该分配策略进行回收能量效率测试。结果表明,该分配策略既能保证汽车前后轮的制动力分配按照理想制动力I曲线分布,确保汽车的制动安全;又能有效地实现再生制动能量回收,提高电动汽车的续驶里程。     

Graft polymerization of vinyl acetate onto silica

The free‐radical graft polymerization of vinyl acetate onto nonporous silica particles was studied experimentally. The grafting procedure consisted of surface activation with vinyltrimethoxysilane, followed by free‐radical graft polymerization of vinyl acetate in ethyl acetate with 2,2′‐azobis(2,4‐dimethylpentanenitrile) initiator. Initial monomer concentration was varied from 10 to 40% by volume and the reaction was spanned from 50 to 70°C. The resulting grafted polymer, which was stable over a wide range of pH levels, consisted of polymer chains that are terminally and covalently bonded to the silica substrate. The experimental polymerization rate order, with respect to monomer concentration, ranged from 1.61 to 2.00, consistent with the kinetic order for the high polymerization regime. The corresponding rate order for polymer grafting varied from 1.24 to 1.43. The polymer graft yield increased with both initial monomer concentration and reaction temperature, and the polymer‐grafted surface became more hydrophobic with increasing polymer graft yield. The present study suggests that a denser grafted polymer phase of shorter chains was created upon increasing temperature. On the other hand, both polymer chain length and polymer graft density increased with initial monomer concentration. Atomic force microscopy–determined topology of the polymer‐grafted surface revealed a distribution of surface clusters and surface elevations consistent with the expected broad molecular‐weight distribution for free‐radical polymerization. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 87: 300–310, 2003     

容器设计中搅拌装置的轴向力分析

搅拌装置在化工厂中应用很广，在磷肥、钛白粉装置中（15kt/a)使用较多，仅钛白粉装置中就大约有40－50台，如增稠结晶器，中和槽等，搅拌操作所涉及的因素极为复杂，浆叶形式的选择，从力学的观点来说，迄今研究不够，本文就搅拌装置产生的轴向力问题进行了初步研究。