Acidity in upland and hill soils: Cation exchange capacity,pH and lime requirement

For 30 acid upland and hill soils, with initial pH from 3.5 to 5.8, and loss on ignition from 14% to 94%, cation exchange capacity varied with pH according to the relationship CEC = m pH+C, where m and C are characteristic of each soil. The slope m depended on loss on ignition (LOI), and is given by: m=Δ CEC/Δ=0.22 LOI+1.92. Because of these relationships, CEC measured at the natural pH of the soil (in 0.025 M MgSO₄ solution) is more relevant to field conditions than a conventional measurement at pH7. An improved method for estimating lime requirement (LR) of these soils was developed, based on the relationship found between LR and the difference in CEC (ΔCEC) between that at the natural pH of the soil and that at the target pH of 5.5: LR=1.12 ΔCEC+1.48. Lime requirement can therefore also be estimated from loss on ignition using the earlier relationships, and is given by: LR=(0.25 LOI+2.15) Δ+1.48, where Δ is the difference between the natural pH (in 0.025 M MgSO₄) and the target pH. Predictions based on this agreed well with results for a further 10 soils.     

烷基化原料预加氢工艺应用分析

由于来自催化裂化装置的烷基化原料中所含有的丁二烯在烷基化反应中可生成重质油,使产品干点上升,辛烷值下降,并使酸耗增加.针对这种状况,齐鲁石化公司研究院和胜利炼油厂联合开发了QSH-01烷基化原料预加氢催化剂及其相应的工艺技术,来脱除原料中丁二烯.笔者对该工艺技术及其应用作了阐述,并对该技术的应用前景作出分析.     

Change of characteristics of desulfurization and denitrification by combustion flue gas composition and electrode configuration under pulsed corona discharge

Laboratory-scale and parametric experiments of SO₂ and NO_x removal from the simulated combustion gas by pulsed corona discharge have been performed by changing the combustion gas composition and temperature, the electrode configuration of plasma reactor, and the polarity of high-voltage electrode. The following results are obtained: 1) the higher the concentration of H₂O and O₂, the higher the efficiency of desulfurization and denitrification at the same specific input; 2) the pulsed corona discharge with a voltage pulsewidth as short as 200 ns of negative polarity shows the possibility to attain almost 90 percent deSO_x and deNO_x efficiency at the specific discharge input of 20 J/g, which is almost the same as the specific input in the electron-beam process; 3) the deNO_x characteristics show a little temperature dependence in the range of 70 to 130°C, but the deSO_x efficiency increases rapidly in the temperature region below 100°C suggesting the thermochemical dependence of deSO_x reaction; 4) when desulfurization and denitrification proceed, the white dendritic powder deposits on the plasma reactor whose composition is identified to be 49 mol% (NH₄)₂SO₄ and 47 mol% of 2NH₄NO₃ · (NH₄)₂SO₄, and the ratio of SO₂, NO and NH₃ of the deposit is almost equal to that of supplied gas.     

转向柱管承载能力的试验研究

在分析转向柱管花键部位应力集中情况的基础上,通过对某厂生产的转向柱管扭转破坏的试验研究,得到如下结论:①转向柱管的承载能力与其外花键齿与方向盘中心内花键齿之间的非接触区长度有关,以花键端部过渡圆弧的直径大小为宜;②安装方向盘总成时所施加在安装螺母上的拧紧力矩在70N.m左右时,转向柱管的承载能力最大。     

浅谈南水北调工程中招标代理机构的自身建设

在市场经济条件下,随着水利工程建设市场的不断规范和完善,招标代理机构如何在市场竞争中开展招标代理业务,其自身建设就显得尤为重要。现结合南水北调工程实际,提出了招标代理机构应从法律意识、诚实信用、专业特长、激励机制和沟通协调等5个方面加强自身建设,以便能在南水北调工程建设中更好地发挥作用。     

TRVs and fault clearing stresses in extra-high-voltage radial networks

To cope with the high rate of increase of power demand in the main industrialized districts in Japan, 550-kV transmission systems covering the districts have been reinforced, with most of the main power plants connected directly to these systems. Through 550-/300-kV substations, the majority of power to the districts is supplied by 300-kV systems. To limit the excess short-circuit capacity in the 300-kV systems, they tend to be reconstructed as so-called radial networks. In radial networks with high short-circuit capacity and relatively small number of transmission lines connected to the substation busbars, the rate of rise of TRV can be far higher than standard value. This paper analyzes the transient recovery voltages (TRV) in such extra-high-voltage radial networks in Japan, together with the relevant stresses to circuit-breakers during fault clearings. Future system conditions have also been introduced. As the typical rate of rise of the TRV values, more than twice that of today's standard ones are probable.     

渤中28－1（BZ28－1）油田N6H水平井动态分析

本文以渤中２８－１（ＢＺ２８－１）油田Ｎ６Ｈ水平井为例，从多方面对该井的动态和产能变化进行了系统分析，所用的方法对水平井动态分析有一定的指导意义。     

Zeolite synthesis from paper sludge ash with addition of diatomite

BACKGROUND: This study aimed to investigate the synthesis of zeolites from paper sludge ash (PSA) with added diatomite to remove both NH₄⁺ and PO₄^3? for water purification. The PSA had low Si and significant Ca contents. Four types of diatomite: white (T‐W) and brown (T‐B) from deposits of marine origin in Takanosu, and white (S‐W) and gray (S‐G) from lacustrine deposits in Shonai, were added to NaOH solution to increase the Si content and thereby synthesize zeolites with high cation exchange capacity (CEC). RESULTS: The order of the amounts of Si extracted from the diatomite to the alkali solution was S‐W > T‐W = T‐B > S‐G, which correlates with the amorphous SiO₂ content of diatomite. The original ash without addition of diatomite yielded hydroxysodalite with CEC of about 1.0 mmol g^?1. For all samples, the addition of diatomite to the solution yielded zeolite‐P with a higher CEC, but the addition of excess Si inhibited the synthesis of zeolite‐P, and the CEC of the product was low. A product with high CEC including zeolite‐P was obtained in a solution with around 500 mmol L^?1 of Si concentration, and had the ability to remove both NH₄⁺ and PO₄^3?. CONCLUSION: Diatomite has the potential for used as an additive for the synthesis of high CEC zeolite from PSA. The product with zeolite‐P exhibited relatively high CEC, capacity for NH₄⁺ uptake, and the ability to remove PO₄^3? by precipitation, which is preferable for water purification applications. Copyright © 2008 Society of Chemical Industry     

Effect of mineral matter on coal self-heating rate

Adiabatic self-heating tests have been conducted on subbituminous coal cores from the same seam profile, which cover a mineral matter content range of 11.2-71.1%. In all cases the heat release rate does not conform to an Arrhenius kinetic model, but can best be described by a third order polynomial. Assessment of the theoretical heat sink effect of the mineral matter in each of the tests reveals that the coal is less reactive than predicted using a simple energy conservation equation. There is an additional effect of the mineral matter in these cases that cannot be explained by heat sink alone. The disseminated mineral matter in the coal is therefore inhibiting the oxidation reaction due to physicochemical effects.     

世界乙烯工业及其进展

阐述了世界乙烯产能需求现状，近扑扩能增产预测，乙烯原料分析以及乙烯生产的技术进展。