Inhibition effect of a synthesized N, N＇-bis（2-hydroxybenzaldehyde）- 1, 3-propandiimine on corrosion of mild steel in HC1

The corrosion inhibition of mild steel in 1 mol/L HCl by N, N′-bis (2-hydroxybenzaldehyde)-1, 3-propandiimine (2-HBP) has been investigated by using potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and chronoamperometry measurements. The experimental results suggest that this compound is an excellent corrosion inhibitor for mild steel and the inhibition efficiency increases with the increase in inhibitor concentration. Polarization curves reveal that this organic compound is a mixed type inhibitor. The effect of temperature on the corrosion behavior of mild steel with the addition of the Schiff base was studied in the temperature range from 25℃ to 65℃. The experimentally obtained adsorption isotherms follow the Langmuir equation. Activation and thermodynamic adsorption parameters such as E a , ΔH, ΔS, K ads and ΔG ads were calculated by the corrosion currents at different temperatures and using the adsorption isotherm. The morphology of mild steel surface in the absence and presence of 2-HBP was examined by atomic force microscope (AFM) images.     

三唑类化合物分子结构与防治小麦锈病活性关系的研究

本文用多元线性回归分析、逐步线性回归分析、主成分回归分析和偏最小二乘分析方法研究了三唑类化合物结构与防治小麦锈病活性的关系，并建立了构效关系式。对该系列化合物结构的变化对其生物性的影响作了一定的探讨。提出了设计高活性化合物的可能结构要求，并将研究结果用于实际化合物的设计中，取得了初步结果。     

活性污泥生物吸附性能的研究

探讨了活性污泥生物吸附作用的影响因素。吸附性能随温度升高而降低,在20~30min之间,可达到吸附平衡,且温度越高,达到吸附平衡的时间越长;活性污泥对悬浮性有机物的吸附性能高于对溶解性和胶体性有机物的吸附;对高浓度污水吸附性能高于低浓度污水的吸附性能;抑制剂对污泥的吸附作用有影响。     

机械合金化制备超细、纳米晶CuCr触头材料的探讨

分析探讨了机械合金化工艺制备超细、纳米晶CuCr材料中的晶粒尺寸、氧含量和材料密度控制等主要问题，提出了一种低成本制备高性能CuCr触头材料的新思路，即添加高性能晶粒长大抑制剂 普通真空烧结工艺。     

基于抑制弧Petri网的离散事件系统的监控理论综述

利用Petri网的抑制弧实现离散事件系统的监控是离散事件系统监控理论的一个新进展。对抑制弧Petri网作了简单的介绍，并给出了该监控理论的基本原理．详细地回顾和总结了该理论的四种方法，即：结合自动机的字符串避免方法、抑制弧方法、基于抑制弧的状态避免控制器方法以及加权抑制弧方法，分别分析了这几种方法各自的利弊。最后对其可能的发展作了展望。     

纳米晶WC-10Co复合粉末烧结行为的研究

本文研究了机械合金化制备的纳米晶WC 10Co复合粉末的真空烧结特征 ,分析了孔隙度、显微硬度随绕结时间延长和烧结温度升高的变化规律 ,考察了一种新型抑制剂的作用。结果表明 :在 132 5℃ / 15min的烧结条件下 ,样品的相对密度达到了 98%以上 ;烧结样品的显微硬度随着烧结时间的延长和烧结温度的升高先增加后降低 ,并且在 132 5℃ / 15min的条件下其硬度为 2 2 95MPa ;新型抑制剂A既有利于晶粒长大的控制 ,同时又有利于材料致密化的进行 ,显著地提高了合金的性能。     

硫化铜与含钴黄铁矿低碱度分离新工艺研究

针对海南某铜钴硫矿床,通过对其进行工艺矿物学研究查清其有用矿物的赋存状态和嵌布特征,并依此确定其最终的选矿工艺流程和药剂制度。研究表明,原矿中的钴矿物主要以晶格取代的形式赋存于黄铁矿和毒砂之中,试验针对其工艺矿物学特性采用铜钴硫混合浮选流程,混合精矿再分离得到铜精矿和硫精矿,其中钴矿物大部分进入硫精矿之中,实现了对有价金属最大限度的回收。铜硫分离使用石灰+SH组合抑制剂,SH可部分替代石灰实现在较低碱度条件下对黄铁矿的抑制作用。     

硫氢化钠常压合成巯基乙酸钠影响因素研究

巯基乙酸钠是辉钼矿选矿中代替氰化物抑制铜矿物的理想药剂,合成巯基乙酸钠的方法有多种,其中硫氢化钠一步法合成文献报道较少,本文在单因素试验的基础上,用P lackett-Burm an试验法对一步法合成巯基乙酸钠的影响因素显著性进行了分析,确定了硫氢化钠常压合成巯基乙酸钠的主要影响因素,从而达到筛选的目的,避免在后期的优化试验中由于因子数太多或部分因子不显著而浪费试验资源。     

Inhibition of La-Fe-Co-Si compound corrosion in distilled water by sodium molybdate and disodium hydrogen phosphate

A comparative study of Na2MoO4·2H2O and Na2HPO4·12H2O as inhibitors for magnetic refrigeration material La-Fe-Co-Si compound corrosion in distilled water at room temperature was carried out.Moreover,the inhibiting behavior of the mixture of Na2MoO4·2H2O and Na2HPO4·12H2O was investigated.Potentiodynamic polarization curves and electrochemical impedance spectroscopy (EIS) measurements were applied to study the corrosion behavior of the compound in the absence or presence of different concentrations of these inhibitors under the same experimental conditions.The study revealed that the mixture of 3.0×10–3 kg/L Na2MoO4·2H2O and 5.0×10–3 kg/L Na2HPO4·12H2O was the best inhibitor reaching the value of inhibition efficiency (ε%) up to 93.9%.Polarization curves showed that the studied compounds acted as anodic inhibitors.The potential of zero charge (PZC) of La-Fe-Co-Si compound was determined in distilled water in the absence of the studied inhibitors.Corrosion inhibition mechanisms for inhibitors were proposed in this work.     

滨海地区地下混凝土结构防腐设计

通过了解氯离子对混凝土的腐蚀及破坏机理,介绍滨海地区一工程中地下混凝土结构防腐做法及相关混凝土耐久性设计措施。