复杂环境中天线辐射方向图的分析

采用一致性几何绕射理论(UTD)研究了电大尺寸复杂平台中天线的辐射特性。以点源模型分析了天线受周围电磁环境影响后的辐射方向图,与自由空间方向图的对比说明了受影响后天线辐射特性的变化。与低频算法相比,本文算法有计算速度快、占用内存量很少的优点,可应用于工程中类似平台的多天线系统干扰分析。     

钽掺杂的钌基厚膜电阻导电相和玻璃相颗粒尺寸效应的研究

本文报道了钽掺杂钌基厚膜电阻制备过程中导电相和玻璃相颗粒尺寸效应的实验研究结果。当导电相和玻璃相颗粒尺寸分别达到25和50nm时,电阻阻值和电阻温度系数也随之发生显著变化,并尝试根据厚膜电阻导电机理对其产生的原因进行定性的分析。     

一种用于导电油墨的特种铜粉制备研究

特种导电油墨是全印制电路技术开发与应用的关键之一。本文报道了利用硫酸铜、碳酸钠、抗坏血酸等为原料,通过固相反应获得纳米非球形铜粉方法。通过SEM、EDS分析表明,获得的产物为一种柱状的高纯铜粉,直径大约500nm,可以作为全印制电路技术用高性能特种油墨的开发。     

Study of the anticorrosive properties of polypyrrole/polyaniline bilayer via electrochemical techniques

In this work, using electrochemical techniques the authors investigated the protective properties of a polypyrrole/polyaniline bilayer as a conductive polymer. A polypyrrole/polyaniline bilayer was deposited on carbon steel substrate by potentiostatic method. The electric capacitance and resistance of the films were monitored with the immersion time in a corrosive solution to investigate the water permeability of the films. Polypyrrole/polyaniline bilayer has a relatively low permeability and good catalytic behavior in passivation of carbon steel in longer periods. The results show that the bilayer has a better anticorrosive behavior compared to homopolymers (polypyrrole and polyaniline).     

Self-sensing piezoresistive cement composite loaded with carbon black particles

Strain sensors can be embedded in civil engineering infrastructures to perform real-time service life monitoring. Here, the sensing capability of piezoresistive cement-based composites loaded with carbon black (CB) particles is investigated. Several composite mixtures, with a CB filler loading up to 10% of binder mass, were mechanically tested under cyclic uniaxial compression, registering variations in electrical resistance as a function of deformation. The results show a reversible piezoresistive behaviour and a quasi-linear relation between the fractional change in resistivity and the compressive strain, in particular for those compositions with higher amount of CB. Gage factors of 30 and 24 were found for compositions containing 7 and 10% of binder mass, respectively. These findings suggest that the CB-cement composites may be a promising active material to monitor compressive strain in civil infrastructures such as concrete bridges and roadways.     

Synthesis and conductivity of heptadecatungstovanadodiphosphoric heteropoly acid with Dawson structure

A new solid high-proton conductor, heptadecatungstovanadodiphosphoric heteropoly acid H₇P₂W₁₇VO₆₂·28H₂O with Dawson structure was synthesized by the stepwise acidification and the stepwise addition of element solutions. The optimal proportion of component compounds in the synthesis reaction was given. The product was characterized by chemical analysis, potentiometric titration, IR, UV, XRD, ³¹P NMR, TG-DTA and electrochemical impedance spectroscopy (EIS). The results indicate that H₇P₂W₁₇VO₆₂·28H₂O possesses the Dawson structure. EIS measurements show a high conductivity (3.10 × 10⁻² S cm⁻¹ at 26 °C and 75% relative humidity), with an activation energy of 32.23 kJ mol⁻¹ for proton conduction. The mechanism of proton conduction for this heteropoly acid is Vehicle mechanism.     

Simplified Impedance Model for Adhesively Bonded Piezo-Impedance Transducers

The electromechanical impedance technique employs surface-bonded lead zirconate titanate piezoelectric ceramic patches as impedance transducers for structural health monitoring and nondestructive evaluation. The patches are bonded to the monitored structures using finitely thick adhesive bond layer, which introduces shear lag effect, thus invariably influencing the electromechanical admittance signatures. This paper presents a new simplified impedance model to incorporate shear lag effect into electromechanical admittance formulations, both one-dimensional and two-dimensional. This provides a closed-form analytical solution of the inverse problem, i.e. to derive the true structural impedance from the measured conductance and susceptance signatures, thus an improvement over the existing models. The influence of various parameters (associated with the bond layer) on admittance signatures is investigated using the proposed model and the results compared with existing models. The results show that the new model, which is far simpler than the existing models, models the shear lag phenomenon reasonably well besides providing direct solution of a complex inverse problem.     

Strain sensing behavior of electrically conductive fibers under large deformation

Electrically conductive fiber/yarn/fabric is one of the promising materials as flexible conductive sensors because of their sensitivity to strain, temperature and humidity. Aiming at developing of effective flexible sensors, this study investigates experimentally the strain sensing behavior of PPy (polypyrrole)-coated Lycra fibers, showing that the electrically resistance of the conductive fibers changes with the deformation of fibers. The variation in electrically resistance is mainly related to the micro-cracks appearing on the fiber surface during deformation. Then, the effects of the characteristic parameters of the micro-cracks are studied statistically by means of image processing functions in MATLAB, and the governing parameters are determined. Based on the results, a model is built to describe the variation of electrical resistance by the parameters of the micro-cracks. The analytical results are compared with the experimental results, showing an acceptable agreement.     

Light-colored compound conductive coatings based on CuI: Effect of volume fraction of CuI on morphology and electrical conductivity

A novel family of compound conductive coating has been designed and developed using Cu(I)I (cuprous iodide) as electrical conducting material. A carefully designed polyurethane matrix material allowed incorporation of large volume fraction of CuI, much above its critical volume concentration, while maintaining good film integrity. Electrical conductivity of a series of such coatings has been studied using dielectric spectroscopy, as a function of volume fraction of CuI and temperature. The light-colored (white–beige colored) coatings having electrical conductivity of the order of up to 10⁻³–10⁻² S cm⁻¹ have been demonstrated. Scanning electron microscopy (SEM) has been used to characterize bulk coating microstructures. The result of this study provides useful insight for fabrication of compound conductive coatings based on CuI.