Proton Nuclear Magnetic Resonance-Based Method for the Quantification of Epoxidized Methyl Oleate

Epoxidized methyl esters (EMO) with their high oxirane ring reactivity, acts as a raw material in the synthesis of various industrial chemicals including polymers, stabilizers, plasticizers, glycols, polyols, carbonyl compounds, biolubricants etc. EMO has been generally quantified by the gas chromatography (GC) and high-performance liquid chromatography (HPLC) techniques. Taking into the account of the limitations of these techniques, two qHNMR-based equations have been proposed for the quantification of EMO in the mixture of EMO and methylesters (MO). The validity of the proposed method was determined using standard mixtures of MO and EMO having different molar concentrations. The developed equations have been applied on the samples of EMO prepared from oleic acid in two-step process viz., esterification followed by epoxidation. The qHNMR-based EMO quantification showed acceptable agreement with the results obtained from HPLC analysis.     

An International Collaborative Study on Trypsin Inhibitor Assay for Legumes,Cereals, and Related Products

For determining trypsin inhibitor activity (TIA) in soy products, the American Oil Chemists' Society (AOCS) Method Ba 12-75 has been used. It measures differences in absorbance at 410 nm of bovine trypsin activity toward a synthetic substrate (Nα-benzoyl-DL-arginine-p-nitroanilide) in the absence and presence of an inhibitor. Recently, a significantly improved method was developed (JAOCS, 2019, 96:635–645), featuring 5 mL of total assay volume, enzyme-last sequence, and single inhibitor level in duplicate. It is proposed as the AOCS Method Ba 12a-2020. As a part of the AOCS method approval process, a collaborative study involving 12 international laboratories was conducted to evaluate the performance of the proposed method. The study involved measuring TIA in 10 selected test samples plus a blind duplicate. They included soybeans, pulses, cereals, and their processed products (flours, concentrates, and isolates). After rigorous statistical treatment of the data, only three outliers were removed from the data of two samples. Repeatability relative standard deviations (RSDr) for the 11 samples ranged from 0.99% to 5.52%. Reproducibility RSD (RSD_R) ranged from 7.07% to 22.92%, with seven samples having RSD_R around 10% or less. The remaining four samples had very low TIA, and their RSD_R values ranged from 13.34% to 22.92%. The study has demonstrated reliable performance of the proposed AOCS method. Several collaborators carried out additional experiments addressing some aspects of the method, leading to further refinements. The proposed method is undergoing evaluation by the AOCS Uniform Methods Committee for adoption as an Official Method for measuring TIA in various legume and grain products.     

低碳钢焊缝的应力腐蚀和酸腐蚀

通过恒载荷实验研究了16MnR钢焊缝区在40％NaOH,110℃溶液中的应力腐蚀破裂行为，同时研究了酸洗对腐蚀断裂的作用。结果表明，根据极化曲线确定－980mV/SCE作为应力腐蚀敏感电位是合理的，在此电位下，16MnR焊缝区在40％NaOH,110℃溶液中仅用2天就出现了应力腐蚀裂纹，酸洗会引起裂纹加深加宽，导致断裂，可以从消除应力和选择合适的缓蚀剂两方面来防止氧化铝厂单管预热器破裂失效。     

宝钢No.3高炉炉壳孔洞应力弹性分析

针对高炉炉壳各种复杂的开发及受力情况，结合宝钢No．3高炉炉壳开孔实例，建立相应的四种数学模型，利用美国ALGOR计算软件中的SSAPO计算模块，作有限元应力计算并进行孔洞弹性应力分析的讨论，以判断高炉开孔的安全可靠性。     

薄板坯连铸工艺液芯压下的有限元分析

简要介绍世界几种主要薄板坯连铸工艺。着重叙述应用大型通用商业软件MSC.MARC。模拟液芯压下时铸坯的变形，确定最佳压下方案的有限元分析，液芯压下应该在结晶器出口处及二冷区扇形段开始部分进行，这样能减小铸坯的应变。     

基于磁性传感器信息融合的油管损伤在线检测技术

建立适用于油管损伤检测的磁性传感器信息融合模型，并将信息融合模型分为四级。在此基础上，提出了磁性传感器信息融合方法，分别完成局部损伤及其严重程度的分类、壁厚损伤的定性判别和壁厚损伤检测数据的融合估计。结果表明，基于磁性传感器信息融合的油管损伤在线检测系统有效地提高了多源信息的利用程度，具有较高的准确性、可靠性和稳健性。     

数字化油管井口无损检测系统

根据电磁无损检测原理研制了数字化油管井口无损检测系统。分析了不同类型缺陷的漏磁场分布特征，布置不同方向的检测元件测值不同的缺陷信息，结合井口检测的要求，设计了检测装置，并给出了现场采集的信号波形，试验表明，该系统能满足现场使用要求。     

穿孔顶头使用寿命浅析

分析了顶头的各种失效形式及产生的原因,提出了提高顶头使用寿命的措施。即应根据顶头的具体工作条件,制定合理的热处理工艺;采用复合处理工艺,解决好顶头单纯氧化处理热强性不高的问题等。     

我国油井管生产的回顾和展望

扼要介绍了油井管的品种、用途。分阶段介绍了我国油井管的生产发展过程以及我国钻杆的生产发展情况,指出根据油井勘探开发发展趋势,各生产厂应重点开发高难、特殊品种油井管。     

中厚板轧制边部不均匀变形机理的探讨

通过分析宽中厚板轧制过程中的边部不均匀变形，探讨了其影响因素及大宽度板“切边纵裂”的产生原因，提出了解决问题的具体办法。