乙烯齐聚催化剂研究进展

乙烯齐聚是合成直链低碳α-烯烃最先进的方法，直链低碳α-烯烃可用于生产低密度聚乙烯和高密度聚乙烯等多种精细化学品。本文综述了乙烯齐聚催化体系的研究进展，重点介绍了镍、锆、钛催化剂的组成以及反应时间、反应温度、溶剂、助催化剂等因素对乙烯齐聚活性和选择性的影响，并讨论了典型镍的催化机理。     

柳钢新建氧化球团工程的设计特点

介绍了柳钢新建120万t／a链篦机-回转窑氧化球团工程的主要设计特点。该工程是我国第一条自行设计、设备国产化和采用清洁气体能源的链篦机-回转窑生产线。它的顺利投产，标志着我国炼铁炉料生产技术有了一个新的进步。     

Effect of oxygenation on electrocatalysis of La0.6Ca0.4CoO3−x in bifunctional air electrode

A vacuum-annealed La_0.6Ca_0.4CoO_3−x was consecutively oxygenated in air at temperatures decreasing from 800 to 100 °C, and its electrocatalytic activities for oxygen reduction and evolution were then measured as a function of the oxygenation temperature. The valence of Co cation, changing between +2 and +3, was found susceptible to annealing either in vacuum or air. The catalytic activities initially decrease monotonically as the oxygenation temperature was decreased from 800 to 300 °C, as a result of increasing oxygen content, and then rise abruptly with the oxygen reduction activity reaching a maximum at 200 °C and the oxidation activity at 150 °C. X-ray photoelectron spectroscopy analysis indicated that the enhancements by the low-temperature oxygenation involved increased OH coverage and less charged cations at surface. The results clearly reveal the importance of the post-calcination annealing process for optimizing the performance of La_0.6Ca_0.4CoO_3−x in air electrode applications.     

Influence of iron oxide pigments on the properties of concrete interlocking blocks

Concrete interlocking blocks (CIBs) are utilized in a variety of commercial, municipal, and industrial applications. Superior engineering properties, low maintenance, ease of placement and removal, reuse of original blocks, aesthetic appeal, and immediate availability are the primary reasons for choosing concrete block pavement over other paving surfaces. It is a common practice to pigment building materials, such as mortar, concrete pavers, concrete roof tiles, and prefabricated concrete products; CIBs are colored using iron oxide pigments. This article presents experimental results detailing the properties of CIBs dyed with pigments. The results of these experiments are as follows: Because the particles of iron oxide pigments are finer than those of brown iron oxide, interlocking blocks mixed with the former acquired higher color strength than with the latter. Additional analysis determined a definite relationship between the flexural strength and the absorption ratio of pigment-dyed blocks; the correlation coefficient (R²) of interlocking blocks at 91 days was .90. It is suggested that if iron oxide pigments are to be used to color CIBs, the pigment-to-cement ratio should be below 4%.     

用CMOS工艺实现VSR光电集成接收机的途径

介绍了10Gbit／s速率的甚短距离光传输系统VSR(Very Short Reach)中的接收机。分析了几种有希望用于VSR系统的CMOS工艺兼容的光电探测器。提出用CMOS电路实现VSR光电集成(OEIC)接收机的可能性和实现方法。     

Mixed oxide supported hydrodesulfurization catalysts—a review

Support effects form important aspect of hydrodesulfurization (HDS) studies and mixed oxide supports received maximum attention in the last two decades. This review will focus attention on studies on mixed oxide supported Mo and W catalysts. For convenience of discussion, these are divided into Al₂O₃ containing mixed oxide supports, TiO₂ containing mixed oxide supports, ZrO₂ containing mixed oxide supports and other mixed oxide supports containing all the rest. TiO₂ containing mixed oxides received maximum attention, especially TiO₂–Al₂O₃ supported catalysts. A brief discussion about their prospects for application to ultradeep desulfurization is also included. An overview of the available literature with emphasis on research carried out in our laboratory form the contents of this publication.     

Nitric oxide reduction and carbon monoxide oxidation over carbon-supported copper-chromium catalysts

Carbon supported copper-chromium catalysts are shown to be very active for both the reduction of nitric oxide with carbon monoxide and the oxidation of carbon monoxide with oxygen. Mixed copper-chromium oxide active phases have good activity in the simultaneous removal of nitric oxide and carbon monoxide from exhaust gases. The influence of several catalyst variables has been investigated. The activity per volume of catalyst increases with increasing loading, while the intrinsic activity shows a maximum around C/M=100−50. An optimum catalyst for nitric oxide reduction and carbon monoxide oxidation has a copper/chromium ratio of 2/1. The apparent activation energy for the carbon monoxide oxidation over carbon supported copper-chromium catalysts is 77 kJ/mol, suggesting that the Cu---O bond rupture is the rate-limiting process. The reduction of nitric oxide takes place at higher temperatures. Since all catalysts have a low selectivity for molecular nitrogen formation at lower temperatures, the dissociation of nitric oxide is probably rate determining, resulting in a slightly reduced catalyst system. In an excess of carbon monoxide the reaction is first-order in nitric oxide and zero-order in carbon monoxide. Moisture inhibits the reaction by reversible competitive adsorption, whereas carbon dioxide does not. Oxygen completely inhibits the reduction of nitric oxide due to the more rapid reoxidation of the catalytic sites compared to nitric oxide. Therefore, the reduction of nitric oxide takes place only when all oxygen has been converted and, hence, is shifted to higher temperatures. As a possible consequence, the production of nitrous oxide is reduced. Nitric oxide and molecular oxygen react preferentially with carbon monoxide, so, in an excess of oxidizing component, gasification of the carbon support occurs at higher temperatures after carbon monoxide has been completely consumed.     

脱落酸、乙烯和赤霉素对豌豆苗采后品质的影响

为了解植物生长调节剂对幼苗类蔬菜采后品质变化的影响，用脱落酸、乙烯、赤霉素处理豌豆苗（Pisum Satu-vum L.）。结果表明：脱落酸和乙烯处理加速了叶绿素、蛋白质、可溶性糖含量的下降和纤维素含量的升高。而赤霉素处理则显著延缓了叶绿素、蛋白质和可溶性糖含量的下降和纤维素含量的增加。     

The Synthesis of Sulfated Titanium Oxide Nanotubes

TiO₂ nanotubes can be prepared in gram quantities by treating anatase TiO₂ powder with concentrated NaOH solution. These TiO₂ nanotubes acquired strong acidity after being impregnated with sulfuric acid solution and calcined at 300 °C. The anatase TiO₂ powder used to prepare the nanotube did not catalyze the esterification between cyclohexanol and acetic acid, while sulfated TiO₂ nanotubes were very reactive toward the esterification reaction.     

Growth Stresses in the Oxide Scales on TiAl Alloys at 800 and 900°C

In the oxidation of TiAl alloys, the role of scale-growth stresses formed during oxidation has, thus far, been unknown. In the present paper the oxide-growth stresses were investigated by the deflection-test method in monofacial oxidation (DTMO) accompanied by acoustic-emission measurements. On unmodified surfaces the growth stresses are compressive and reach levels of around –100 MPa. At the same time, significant acoustic emission occurs indicating that even under isothermal conditions, stresses are relieved by a scale-cracking mechanism. For oxide scales on TiAl surfaces, which had been ion implanted with chlorine before oxidation, a very thin protective alumina layer is formed which, however, develops growth stresses in the range of several GPa, accompanied by intensive acoustic emission. In all stress–time curves, a dynamic situation is observed. This consists of phases of stress relief by scale microcracking and phases of stresses increase due to crack healing and further oxide growth. As a result, the level of stress as a function of oxidation time, is characterized by an oscillating course.