中国石化2004年乙烯生产述评

在对中国石化集团公司2004年乙烯生产运行情况进行简要回顾与分析的基础上,提出2005年工作重点及其具体措施。     

中国石油2004年乙烯业务概述

回顾了中国石油所属乙烯装置2004年的生产情况,总结生产管理、技术进步及改造发展工作。介绍了2005年的工作目标和任务。     

Electrochemical insertion of sodium into hard carbons

The electrochemical insertion of sodium ions into different types of hard carbons was achieved in electrolytes composed of ethylene carbonate as the solvent and NaClO₄ as the salt. For all the materials studied the sodium uptake increases when the carbon highest heat treatment temperature (HTT) decreases. PAN-based carbon fibres appear to be suitable structures to allow significant sodium insertion. Thus, T650 ex-PAN fibres lead to a reversible capacity close to 209 mAh g⁻¹. In that case, sodium insertion occurs in two main ways: one is the adsorption on the single graphene layers and the other is the concomitant insertion into the porosity that occurs below 0.1 V versus Na⁺/Na. This second mechanism, which is indicated by a low-voltage plateau on the electrochemical curves, allows significant insertion. The compared electrochemical study of two saccharose-coke samples corresponding to different regions of Dahn's classification underlines the importance of the carbon precursor and of the manufacture process. The reversible capacity is equal to 184 mAh g⁻¹ for the sample heat treated at 800 °C which presents a high hydrogen content whereas it is close to 145 mAh g⁻¹ for the one characterized by a HTT of about 1500 °C and a low hydrogen content. The best electrochemical performances are obtained for pyrolyzed cellulose carbons. Indeed, the reversible capacity is about 279 mAh g⁻¹. Outgassing these carbons at 950 °C results in such a decrease of the reversible capacity down to 145 mAh g⁻¹. That can be related either to the thermal elimination of heteroelements or to modifications of the pore size distribution. Consequently, the most suitable hard carbon material for anodic applications in rechargeable sodium-ion batteries should both present a high residual hydrogen content and a significant microporosity.     

催化热裂解工艺机遇及影响因素

分析了催化热裂解过程的反应机理及乙烯和丙烯形成的反应，乙烯和丙均可通过热裂解和催化裂解生成，讨论了影响乙烯，丙烯产率的因素：与USY和REY相比，使用ZSM－5催化剂能够提高乙烯，丙烯产率，磷改性ZRP－1经碱土金属改性后，可进一步提高乙烯和丙烯的产率，提高反应温度和降低剂油比，能够提高热裂解和催化裂解的比例，有利于乙烯产率的提高；增强蒸汽量能够减少焦炭产率，提高乙烯和丙烯产率。     

乙烯的综合利用

乙烯是重要的有机化工原料，它广泛应用于树脂、纤维、有机化学品等领域，主要用于合成聚乙烯、乙苯、环氧乙烷、二氯乙烷、α-烯烃、直链伯醇、醋酸乙烯酯、乙醇、乙酸等。本文系统全面地论述了以乙烯为原料合成下游产品的技术路线及其最新技术进展，并详细介绍了乙烯下游产品的应用情况和发展趋势。     

燕化660 kt/a乙烯冷区设备布置

主要介绍了大型乙烯改扩建的冷区设备布置的主要特点，分析了设备布置的思路，及与土建等各专业的关系，强调了设备布置方案利旧的方法。     

辽化裂解装置技术改造

辽阳石化烯烃厂裂解装置于2001年检修期间，完全采用国内技术，完成了120kt/a乙烯装置扩能改造工作，介绍了装置改造的主要内容和特点，生产运行和考核情况，以及扩能改造存在的问题和解决措施。     

减粘塔减粘技术在乙烯装置上的应用

分析了传统的急冷油减粘方法的不足之处,阐述了减粘塔减粘的原理,并结合减粘塔的工艺特殊性,列举了具体的设计改进、工艺调整以及安全运行防堵措施。介绍了中国石化扬子石油化工股份有限公司烯烃厂1#、2#乙烯装置减粘塔运行情况与效果,并针对遗留问题,提出了改造方案。     

科学管理确保乙烯装置长周期稳定运行

针对乙烯装置长周期运行面临的问题，中国石油独山子石化分公司乙烯厂采用科学的管理手段和技术进步措施，确保装置长周期运行。     

Electrochemical characteristics of phase-separated polymer electrolyte based on poly(vinylidene fluoride-co-hexafluoropropane) and ethylene carbonate

A polymer electrolyte based on microporous poly(vinylidene fluoride-co-hexafluoropropane) (PVdF-HFP) film was studied for use in lithium ion batteries. The microporous PVdF-HFP (Kynar 2801) matrix was prepared from a cast of homogeneous mixture of PVdF-HFP and solvents such as ethylene carbonate (EC), dimethyl carbonate (DMC), and ethyl methyl carbonate (EMC). After evaporation of DMC and EMC, a sold film of the PVdF-HFP and the EC mixture was obtained. EC-rich phase started its formation in the PVdF-HFP/EC film at EC content of about 60 wt.% based on the total weight of PVdF-HFP and EC. The formation of the new phase resulted in the abrupt increase of the porosity of the PVdF-HFP matrix from 32 to 62%. The ionic conductivity of the film soaked in 1 M LiPF₆-EC/DMC=1/1 was significantly increased from order of 10⁻⁴ S/cm to order of 10⁻³ S/cm at the EC content of 60 wt.%. Thermal and spectroscopic investigations showed that most of the EC interact with PVdF-HFP with the EC content being below 60 wt.%. MCMB/polymer electrolyte/LiCoO₂ cells employing the microporous PVdF-HFP polymer film showed stable charging/discharging characteristics at 1C rate and good rate capability.