Characterization of NOM and THM formation potential in eutrophic reservoir water

Resin adsorption technique with XAD-8 and XAD-4 was used to characterize the raw water from Erlong reservoir in Jilin province of China. The NOM chemical composition sequences of four organic fractions in the raw water,from high to low,are fulvic acid (FA) fraction,hydrophilic non-acid (HPINA) fraction,hydrophilic acid (HPIA) fraction,and humic acid (HA) fraction. Experimental results show that FA is the main precursor of THMFP among the four organic fractions. However,HA or hydrophobic acid exhibits the highest chlorination activity in forming THMs. It is also found that the value of FI/DOC or SUVA and the specific THMFP have better positive correlation. It is implied that certain source water has unique nature of NOM and DBPs.     

五氯酚在厌氧生物体系中的降解及反馈作用

为探讨厌氧系统降解五氯酚(PCP)能力及PCP对厌氧系统的毒性影响,采用UASB反应器进行了PCP模拟污水连续流试验,考察了不同PCP浓度及负荷条件下系统对PCP和COD的降解去除规律,揭示了PCP对系统产酸相和产甲烷相影响状况.结果表明,在进水PCP含量从无到开始加入、PCP浓度提高以及PCP负荷提高3个冲击变化阶段,厌氧系统对PCP和COD的去除率均表现出先迅速降低后缓慢升高的变化趋势,运行稳定后PCP和COD的去除率分别达91.2%和83.5%以上.PCP对厌氧系统中微生物种群产生影响,使系统产酸菌由丁酸型菌群为主逐渐演替为丙酸型菌群为主,PCP对系统产甲烷菌活性产生明显抑制,甲烷产量由PCP加入前的12.1L/d降低至加入后的2.5L/d.     

色谱顶空法测活度系数及对三元极性体系液液平衡预测

用气相色谱顶空分析法测定 18组部分互溶三元极性体系在完全互溶区的 3个组分活度系数 ,由此拟合出 U NIQU AC过量自由焓模型参数 ,再用 U NIQUAC方程预测液液平衡。这一方法曾很好地用在水-正烷烃 -醇体系。将此法拓展到含醇、酮、酯 ,醚、卤烷烃和水等多种极性组分的三元体系液液平衡的预测 ,其结果与文献的液液平衡数据比较 ,平均均方根误差 1.4 1% ,表明本法对含极性组分的体系仍然可行     

Thermodynamic reassessment of the Cd−Zn system

The Cd−Zn system has been thermodynamically reassessed with the CALPHAD method by combining more recent experimental data, in particular the activities of zinc in the liquid phase. A good agreement is obtained between the calculated and experimental thermodynamic parameters as well asphase boundaries.     

含B2O3渣系的热力学计算模型

根据炉渣结构的共存理论和相图，推导了ＣａＯＢ２Ｏ３和ＦｅＯＦｅ２Ｏ３Ｂ２Ｏ３渣系的热力学计算模型。结果表明：（１）理论计算的ＣａＯＢ２Ｏ３渣系的作用浓度ＮＣａＯ及ＮＢ２Ｏ３与实测的活度ａＣａＯ及ａＢ２Ｏ３一致；（２）理论计算的ＦｅＯＦｅ２Ｏ３Ｂ２Ｏ３渣系的氧化能力ＮＦｅｔＯ与实测的炉渣ＦｅｔＯ的活度值相符合。这说明本文提出的热力学计算模型是合理的。     

继电保护定值管理系统设计

基于工作流技术分析了定值单管理业务过程,利用UML活动图对定值单管理工作流程建模,在BEA Weblogic Integration支持下实现了定值单工作流系统,给出了与定值整定计算软件、配电AM/FM/GIS进行系统集成的方案.系统的实施实现了定值生产管理流程化、自动化和多部门协同.     

电子学档在计算机基础课程教学中的应用

对大学计算机基础课程教学活动中引入电子学档来辅助教学,从而构建一种基于电子学档的信息化教学活动进行了探讨。并以《网页设计基础》课程的教学活动为案例,分析了在计算机基础课程教学中引入电子学档的可行性、必要性。最后,使用平均数差异显著性T检验来测量两组学生的学习情况,对使用电子学档提高学生的学习效率进行了量化评价。     

Shape design of cerium oxide nanoparticles for enhancement of enzyme mimetic activity in therapeutic applications

Cerium oxide nanoparticles (CONPs), widely used in catalytic applications owing to their robust redox reaction, are now being considered in therapeutic applications based on their enzyme mimetic properties such as catalase and super oxide dismutase (SOD) mimetic activities. In therapeutic applications, the emerging demand for CONPs with low cytotoxicity, high cost efficiency, and high enzyme mimetic capability necessitates the exploration of alternative synthesis and effective material design. This study presents a room temperature aqueous synthesis for low-cost production of shape-selective CONPs without potentially harmful organic substances, and additionally, investigates cell viability and catalase and SOD mimetic activities. This synthesis, at room temperature, produced CONPs with particular planes: {111}/{100} nanopolyhedra, {100} nano/submicron cubes, and {111}/{100} nanorods that grew in [110] longitudinal direction. Enzymatic activity assays indicated that nanopolyhedra with a high concentration of Ce⁴⁺ ions promoted catalase mimetic activity, while nanocubes and nanorods with high Ce³⁺ ion concentrations enhanced SOD mimetic activity. This is the first study indicating that shape and facet configuration design of CONPs, coupled with the retention of dominant, specific Ce valence states, potentiates enzyme mimetic activities. These findings may be utilized for CONP design aimed at enhancing enzyme mimetic activities in therapeutic applications.

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Unpowered Knee Exoskeleton Reduces Quadriceps Activity during Cycling

Cycling is an eco-friendly method of transport and recreation. With the intent of reducing the energy cost of cycling without providing an additional energy source, we have proposed the use of a torsion spring for knee-extension support. We developed an exoskeleton prototype using a crossing four-bar mechanism as a knee joint with an embedded torsion spring. This study evaluates the passive knee exoskeleton using constant-power cycling tests performed by eight healthy male participants. We recorded the surface electromyography over the rectus femoris muscles of both legs, while the participants cycled at 200 and 225 W on a trainer with the developed wheel-accelerating system. We then analyzed these data in time–frequency via a continuous wavelet transform. At the same cycling speed and leg cadence, the median power spectral frequency of the electromyography increases with cycling load. At the same cycling load, the median power spectral frequency decreases when cycling with the exoskeleton. Quadriceps activity can be relieved despite the exoskeleton consuming no electrical energy and not delivering net-positive mechanical work. This fundamental can be applied to the further development of wearable devices for cycling assistance.     

基于DSP的矿井光纤直放系统的设计

根据煤矿井下巷道狭长、拐点多、分支多的特点,针对井下环境中移动通信系统通话质量差、可靠性低等问题,提出了一种基于DSP的矿井光纤直放系统的设计方案,详细介绍了系统基于DSP的自动监控单元和FIR数字滤波器的设计及语音激活技术在直放系统中的应用。该光纤直放系统解决了井下广域范围移动通信问题,采用DSP对系统实施自动监控,为系统稳定运行提供了可靠保障;数字滤波器的引入、话音激活技术的应用使井下通信系统性能更稳定、话音质量更好、抗干扰性更强,为矿井移动通信的最佳实现奠定基础。