应急电源的设计与应用

介绍了工厂应急电源系统的设计,提出了应急负荷分批启动的概念及控制方式,对提高应急电源的可靠性提出了建议。     

The influence of operating parameters on the performance and emissions of a DI diesel engine using methanol-blended-diesel fuel

In this study, the effects of injection pressure and timing on the performance and emission characteristics of a DI diesel engine using methanol (5%, 10% and 15%) blended-diesel fuel were investigated. The tests were conducted on three different injection pressures (180, 200 and 220 bar) and timings (15°, 20°, and 25° CA BTDC) at 20 Nm engine load and 2200 rpm. The results indicated that brake specific fuel consumption (BSFC), brake specific energy consumption (BSEC), and nitrogen oxides (NO_x) emissions increased as brake thermal efficiency (BTE), smoke opacity, carbon monoxide (CO) and total unburned hydrocarbon (THC) decreased with increasing amount of methanol in the fuel mixture. The best results were achieved for BSFC, BSEC and BTE at the original injection pressure and timing. For the all test fuels, the increasing injection pressure and timing caused to decrease in the smoke opacity, CO, THC emissions while NO_x emissions increase.     

Experimental investigation of Gasoline-Like Fuel obtained from waste lubrication oil on engine performance and exhaust emission

Experimental investigation on engine performance and exhaust emission of a gasoline engine fueled by Gasoline-Like Fuel (GLF) was performed in this study. The GLF was obtained from waste lubrication oil (WLO) using the pyrolitic distillation method. Firstly, the WLO collected in a tank was particulates removed by a refining process. The refined lubrication oil samples were taken into a reactor and blended with calcium oxide (CaO) 2, 4, 6, 8, and 10 wt.% to remove sulphur in the oil. The blended samples were heated in the reactor and then distilled to decrease sulphur and to produce fuel samples. Distillation tests and characteristics of the produced fuel such as density, flash point and lower heating value were examined. The experimental results indicated that the CaO at 2 wt.% had the highest effect on decreasing the amount of sulphur content in the lubrication oil. Fuels produced using 2 wt.% CaO were separated into two parts which were light fuel with 20 wt.% and heavy fuel with 60 wt.% of the total WLO. Remaining of the WLO is about 20 wt.%, which is rejected from the reactor. The light fuel, referred to as GLF and gasoline samples are used to investigate the effect of the GLF on performance and emissions of a 1300 cm³ spark ignited engine manufactured by Fiat. The engine used in the study has specifications of four-stroke and four cylinders, water cooled, fueled with carburetor and naturally aspirated. Each cylinder has a bore of 76 mm and a stroke of 71.5 mm. The experimental results showed that the GLF had a positive effect on brake power, brake thermal efficiency, mean effective pressure and specific fuel consumption. The GLF also raised CO emission and exhaust temperature, but it decreased hydrocarbon (HC) in the exhaust.     

An investigation of the effects of spray angle and injection strategy on dimethyl ether (DME) combustion and exhaust emission characteristics in a common-rail diesel engine

An experimental investigation was performed on the effects of spray angle and injection strategies (single and multiple) on the combustion characteristics, concentrations of exhaust emissions, and the particle size distribution in a direct-injection (DI) compression ignition engine fueled with dimethyl ether (DME) fuel. In this study, two types of narrow spray angle injectors (θ_spray = 70° and 60°) were examined and its results were compared with the results of conventional spray angle (θ_spray = 156°). In addition, to investigate the optimal operating conditions, early single-injection and multiple-injection strategies were employed to reduce cylinder wall-wetting of the injected fuels and to promote the ignition of premixed charge. The engine test was performed at 1400 rpm, and the injection timings were varied from TDC to BTDC 40° of the crank angle.The experimental results showed that the combustion pressure from single combustion for narrow-angle injectors (θ_spray = 70° and 60°) is increased, as compared to the results of the wide-angle injector (θ_spray = 156°) with advanced injection timing of BTDC 35°. In addition, two peaks of the rate of heat release (ROHR) are generated by the combustion of air-fuel premixed mixtures. DME combustion for all test injectors indicated low levels of soot emissions at all injection timings. The NO_x emissions for narrow-angle injectors simultaneously increased in proportion to the advance in injection timing up to BTDC 25°, whereas BTDC 20° for the wide-angle injector. For multiple injections, the combustion pressure and ROHR of the first injection with narrow-angle injectors are combusted more actively, and the ignition delay of the second injected fuel is shorter than with the wide-angle injector. However, the second combustion pressure and ROHR were lower than during the first injection, and combustion durations are prolonged, as compared to the wide-angle injector. With advanced timing of the first injection, narrow-angle injectors with multiple injections could achieve low NO_x levels and soot levels similar to single-injection cases.     

Enhanced activity and stability of Pt/C fuel cell anodes by the modification with ruthenium-oxide nanosheets

Ruthenium-oxide nanosheet (RuO₂ns) crystallites with thickness less than 1 nm were prepared via chemical exfoliation of a layered potassium ruthenate and deposited onto carbon supported platinum (Pt/C) as a potential co-catalyst for fuel cell anode catalysts. The electrocatalytic activity towards carbon monoxide and methanol oxidation was studied at various temperatures for different RuO₂ns loadings. An increase in electrocatalytic activity was evidenced at temperatures above 40 °C, while little enhancement in activity was observed at room temperature. The RuO₂ns modified Pt/C catalyst with composition of RuO₂:Pt = 0.5:1 (molar ratio) exhibited the highest methanol oxidation activity. CO-stripping voltammetry revealed that RuO₂ns promotes oxidation of adsorbed CO on Pt. In addition to the enhanced initial activity, the RuO₂ns modified Pt/C catalyst exhibited improved stability compared to pristine Pt/C against consecutive potential cycling tests.     

Influence of sputtering power on oxygen reduction reaction activity of zirconium oxides prepared by radio frequency reactive sputtering

Zirconium oxides (ZrO_2−x) have been investigated as new cathodes for direct methanol fuel cells without platinum. ZrO_2−x films were prepared using a radio frequency (RF) magnetron sputtering at RF powers from 75 to 175 W. The influence of the RF power on the catalytic activity for the oxygen reduction reaction (ORR) and properties of the ZrO_2−x films were examined. The ORR activity of the ZrO_2−x catalyst increased with the RF power in the range we studied. The onset potential for ORR over ZrO_2−x deposited at 175 W was 0.88 V vs RHE. In addition, the relationship between the ORR activity and the composition, crystallinity, electric conductivity, as well as the ionization potential has been investigated. The zirconium oxide with an oxygen defected state and the higher electric conductivity showed the higher ORR activity, and the electrocatalytic activity for ORR increased with the decreasing in the ionization potential of the ZrO_2−x catalyst.     

A comparison of La0.75Sr0.25Cr0.5Mn0.5O3−δ and Ni impregnated porous YSZ anodes fabricated in two different ways for SOFCs

In this paper, La_0.75Sr_0.25Cr_0.5Mn_0.5O_3−δ (LSCrM) and Ni impregnated porous yttria-stabilized zirconia (YSZ) anodes have been fabricated in two different ways. The testing results demonstrated the excellent performance of the anode made by infiltrating a mixture of LSCrM and Ni(NO₃)₂ solutions into porous YSZ matrix. After reduction of the anode with hydrogen, an inner nano-network structure with mixed ionic-electronic conducting path has been formed within and between these added particles. A single cell with the anode at 800 °C exhibited the maximum power densities of 1151 and 704 mW cm⁻² when dry H₂ and CH₄ were used as the fuels, respectively; under the same conditions, the cell performances for LSCrM and Ni impregnated YSZ anode separately were 810 and 508 mW cm⁻². A cavity model was proposed to simulate the impregnating process and the loading was calculated. No carbon deposition was detected in the anode, even with the presence of Ni, after operation in dry CH₄ for about 6 h under open-circuit condition.     

Power generation from a biocathode microbial fuel cell biocatalyzed by ferro/manganese-oxidizing bacteria

The abiotic cathodes usually require a catalyst such as Pt to enhance power production, increasing the cost and lowering the operational sustainability. In this paper, the performance of a biocathode microbial fuel cell biocatalyzed by ferro/manganese-oxidizing bacteria was investigated. A scanning electron microscopy with an energy-dispersive spectrometer (SEM-EDS) was used to characterize the cathode and analyze the element of cathode. The amount of ferro/manganese-oxidizing bacteria in the biocathode was examined. In batch-fed systems, the maximum open circuit voltage (OCV) was between 700 and 800 mV and the maximum cell potential difference was higher than 600 mV with an external resistance of 100 Ω. The maximum power density was 32 W m⁻³ MFC for batch-fed systems (20-40% Coulombic yield) and 28 W m⁻³ MFC for a continuous system with an acetate loading rate of 1.0 kg COD m⁻³ day⁻¹. The results of SEM-EDS clearly showed that cathode was impregnated with iron and manganese. The amount of ferro/manganese-oxidizing bacteria was (7.5-20.0) × 10⁵ MPN mL⁻¹ in the biocathode. Biocathodes alleviate the need to use noble catalysts for the reduction of oxygen, which step forward towards large-scale application of MFCs.     

Modeling liquid water transport in gas diffusion layers by topologically equivalent pore network

A topologically equivalent pore network (TEPN) model is developed for the first time to extract pore networks directly from gas diffusion layer (GDL) microstructures and thus account for all structural features of a GDL material. A generic framework of TEPN modeling is presented to design GDL structures that enable improved water management. With TEPNs used as input to a two-phase flow simulator, constitutive relations and steady-state liquid saturation profiles for carbon paper and carbon cloth are obtained and reported in this work. The results indicate a strong influence of the GDL morphology on water transport characteristics, which helps unravel the structure-performance relationship for GDLs.     

Analysis of sulfur poisoning on a PEM fuel cell electrode

The extent of irreversible deactivation of Pt towards hydrogen oxidation reaction (HOR) due to sulfur adsorption and subsequent electrochemical oxidation is quantified in a functional polymer electrolyte membrane (PEM) fuel cell. At 70 °C, sequential hydrogen sulfide (H₂S) exposure and electrochemical oxidation experiments indicate that as much as 6% of total Pt sites are deactivated per monolayer sulfur adsorption at open-circuit potential of a PEM fuel cell followed by its removal. The extent of such deactivation is much higher when the electrode is exposed to H₂S while the fuel cell is operating at a finite load, and is dependent on the local overpotential as well as the duration of exposure. Regardless of this deactivation, the H₂/O₂ polarization curves obtained on post-recovery electrodes do not show performance losses suggesting that such performance curves alone cannot be used to assess the extent of recovery due to sulfur poisoning. A concise mechanism for the adsorption and electro-oxidation of H₂S on Pt anode is presented. H₂S dissociatively adsorbs onto Pt as two different sulfur species and at intermediate oxidation potentials, undergoes electro-oxidation to sulfur and then to sulfur dioxide. This mechanism is validated by charge balances between hydrogen desorption and sulfur electro-oxidation on Pt. The ignition potential for sulfur oxidation decreases with increase in temperature, which coupled with faster electro-oxidation kinetics result in the easier removal of adsorbed sulfur at higher temperatures. Furthermore, the adsorption potential is found to influence sulfur coverage of an electrode exposed to H₂S. As an implication, the local potential of a PEM fuel cell anode exposed to H₂S contaminated fuel should be kept below the equilibrium potential for sulfur oxidation to prevent irreversible loss of Pt sites.