高压蒸汽管道保温研究

计算了不同管径和保温厚度下蒸汽管道输送高压蒸汽的热损失和温度降。结果表明:保温厚度越大,蒸汽的热损失越小、温度降越小;保温材料导热系数与蒸汽的热损失呈正比;环境温度越高,蒸汽的热损失越小;环境风速对热损失的影响不大。同时研究了保温材料选择和保温结构对节能的影响。     

Energetic surface heterogeneity of nanocrystalline TiO<Subscript>2</Subscript> films for dye-sensitized solar cells

Dye sensitized solar cells (DSSCs) have been receiving significant attention because they have many advantages compared to conventional organic solar cells. It has been known that the photovoltaic characteristics of DSSC are highly dependent on the adsorption properties of dyes on TiO₂ films. To analyze the surface heterogeneity of TiO₂ surfaces, single-phase anatase nanocrystallite titanium films were prepared by sol-gel method using the hydrolysis reaction of titanium tetraisopropoxide under acidic condition and characterized by XRD, FE-SEM and BET analysis. The adsorption energy distribution functions were calculated by the generalized nonlinear regularization method. It was found that the shape and the intensity of the adsorption energy distribution curve determined were highly related with the physical properties (i.e., geometrical heterogeneity) and chemical characteristics (i.e., energetic heterogeneity) of nanocrystalline TiO₂ for DSSC.     

Protoporphyrin-modified gold surfaces for the selective monitoring of catecholamines

Protoporphyrin IX (PPIX) was immobilized on Au surfaces for the electrochemical oxidation of dopamine (DA) and epinephrine (EP). Two procedures for the immobilization were employed. One class of modified electrodes was prepared by immobilizing the PPIX into polypyrrole (PPy) films synthesized by anodic electropolymerization. The other procedure involved the immobilization of PPIX on an electrode modified by a 11-mercaptoundecanoic acid (MUA) self-assembled monolayer (SAM). The modified surfaces were characterized by cyclic voltammetry (CV).The efficiency of these modified surfaces for the electrochemical oxidation of DA and EP was investigated and compared. The peak potential for the oxidation of each analyte at the different electrode surfaces was determined by square-wave voltammetry (SWV).The dependence of the sensitivity of the electrodes for the detection of the catecholamines on the applied potential was also measured. The SAM-based electrodes showed better selectivity for detecting DA in the potential range between 0.2 and 0.4 V versus Pt (QRE). However, higher sensitivity and linearity were observed for the film-based electrodes.     

多孔介质微波加热厚度的确定

简述了微波加热的机理，以湿木材为研究对象，通过理论计算确定了微波在木材中的穿透深度。计算表明：随着木材含水率和微波工作频率的增加，微波在木材中的穿透深度减小；当用频率为915MHz和2450MHz的微波加热或干燥具有高含水率的多孔介质时，多孔介质的最大厚度应分别控制在16cm和6cm以内。     

气体分离膜综述

介绍了一种新兴的化工单元操作-气体膜分离，对膜分离器及其应用产生的效益进行了阐述，并展望了今后的发展方向。     

低苯乙烯散发不饱和聚酯树脂研究

用单官能团醇对不饱和聚酯树脂改性，合成了苯乙烯质量分数为30％和W01树脂，对W01树脂的挥发性和反应性进行了测定，研究了成膜助剂对01树脂性能的影响，并与通用型191树脂和一种亚克力板层间粘合用不饱和聚酯树脂进行了比较；指出结合成膜助剂的W01树脂进一步降低苯乙烯的散发。     

2008~2016年MODIS多角度大气校正气溶胶产品在中国的时空分布及变化趋势

探究全国大气气溶胶分布及变化特征,准确了解中国地区气溶胶光学特性对研究大气环境污染、应对全球气候变化是非常重要的。对2008~2016年的MODIS MAIAC气溶胶光学厚度数据在中国的适用性进行验证,并采用Mann-Kendall方法,从不同的时空尺度和气溶胶类型上分析中国地区AOD值的时空变化特征。结果表明：①验证表明C6的MAIAC反演结果在中国AERONET匹配点上表现良好,C6的MAIAC反演AOD结果适用于中国区域;②从年际尺度上看,2008~2016年AOD年均值整体呈波动下降;从季节尺度上看,AOD季节变化呈春季整体高、夏季中心高、秋冬季水平低的特点,各省AOD平均值及各省份划区AOD平均值随季节变化趋势相似。③在空间上,AOD呈东南高、西北低、高值中心聚集的特征。④中国AOD变化整体呈现出东部减少且集聚,西部增加且分散的变化特征。可进一步探究不同种类气溶胶分布和气溶胶与典型大气污染物分布关系,以期为中国环境污染治理提供更好的决策指导。     

Delineating spatial distribution and thickness of unconsolidated sand along the southwest Lake Michigan shoreline using TEM and ERT geophysical methods

Erosion and accretion of various magnitudes occur along the southwest Lake Michigan shoreline. These processes are triggered by natural events and human activities, which affect the distribution and thickness of sand on the nearshore lake bottom. Significant erosion along the Illinois coastline has highlighted the need for a large-scale means of acquiring spatially rich data to build models of sand distribution along the entire shoreline. Thus, we implemented a high-resolution airborne transient electromagnetic (TEM) method, coupled with a ground-based electrical resistivity tomography (ERT) method to determine the sand distribution and thickness along the shore from the beach to ~1 km into the lake. From Kenosha, Wisconsin, to Chicago, Illinois, we acquired 1049 line-km of TEM data, and 13.43 line-km of ERT data. Our results indicated a distinct, uneven distribution and thickness of the unconsolidated sand unit covering the southwestern Lake Michigan shoreline. The unconsolidated sand unit was found to range in thickness from 0 to ~12 m. This unconsolidated sand unit was shown to be thickest (4.5 to ~10 m) in the northern part of the study site. In southern Wisconsin and Chicago, the sand layer beneath the water column was found to be very thin, ≤1 m. We propose, based on our analysis, that lake-bed conditions and wind direction are the main factors that limit southward littoral transport. Our data suggest that the current state of the shoreline is relatively analogous to how it has always behaved; however, anthropogenic disturbance has exacerbated the natural patterns of erosion and accretion.     

翼缘纵向变厚度工型截面梁变形性能试验

为研究翼缘纵向变厚度工型截面简支梁的变形性能,对2根翼缘纵向变厚度工型截面梁与2根等厚度梁进行静力加载对比试验,同时采用有限元软件ANSYS进行数值模拟.变厚度梁翼缘材料为Q345GJC等级纵向变厚度钢板,加载方式包括单点加载和两点加载.试验结果表明:试件均发生明显的板件局部屈曲;采用翼缘纵向变厚度工型截面简支梁,不仅可以在保证承载力的情况下大大减少用钢量,而且可以获得更大的强度储备;也可以达到密实截面的变形要求,满足塑性设计要求.有限元结果与试验结果吻合良好.该试验结果可为翼缘纵向变厚度工型截面钢梁的塑性变形设计提供依据.     

固体充填开采地表沉陷数值模拟研究

应用FLAC3 D软件建立了某矿区固体充填开采的三维数值模型,结合固体充填开采等效采厚的相关概念模拟了模型的开挖以及模型在开采后的移动变形情况。使用FLAC3 D内嵌的FISH程序语言,编制了相关程序,提取出两种不同类型的地表移动观测站的沉陷数据。利用提取出的地表移动观测站沉陷数据,结合MATLAB强大的数据处理和可视化功能,对固体充填开采所产生的地表沉陷进行后处理与可视化操作。研究表明：固体充填开采可以有效控制地表沉陷,适用于村庄等建筑物下采煤的情况;运用FLAC3 D并结合MATLAB的方法可以方便、准确的进行开采沉陷的数值模拟与可视化操作。