Theoretical Prediction of Chiral 3D Hybrid Organic–Inorganic Perovskites

Hybrid organic–inorganic perovskites (HOIPs), in particular 3D HOIPs, have demonstrated remarkable properties, including ultralong charge‐carrier diffusion lengths, high dielectric constants, low trap densities, tunable absorption and emission wavelengths, strong spin–orbit coupling, and large Rashba splitting. These superior properties have generated intensive research interest in HOIPs for high‐performance optoelectronics and spintronics. Here, 3D hybrid organic–inorganic perovskites that implant chirality through introducing the chiral methylammonium cation are demonstrated. Based on structural optimization, phonon spectra, formation energy, and ab initio molecular dynamics simulations, it is found that the chirality of the chiral cations can be successfully transferred to the framework of 3D HOIPs, and the resulting 3D chiral HOIPs are both kinetically and thermodynamically stable. Combining chirality with the impressive optical, electrical, and spintronic properties of 3D perovskites, 3D chiral perovskites is of great interest in the fields of piezoelectricity, pyroelectricity, ferroelectricity, topological quantum engineering, circularly polarized optoelectronics, and spintronics.     

Single-Crystalline TiO2(B) Nanobelts with Unusual Large Exposed {100} Facets and Enhanced Li-Storage Capacity

The {100} facet of single-crystalline TiO₂(B) is an ideal platform for inserting Li ions, but it is hard to be obtained due to its high surface energy. Here, the single-crystalline TiO₂(B) nanobelts from H₂Ti₃O₇ with nearly 70% {100} facets exposed are synthesized, which significantly enhances Li-storage capacity. The first-principle calculations demonstrate an ab in-plane 2D diffusion through the exposed {100} facets. As a consequence, the nanobelts can significantly accommodate Li ions in LiTiO₂ formula with specific capacity up to 335 mAh g⁻¹, which is in good agreement with the electrochemical characterizations. Coating with conductive and protective poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), the cut-off discharge voltage is as low as 0.5 V, leading to a capacity of 160.7 mAh g⁻¹ after 1500 cycles with a retention rate of 66% at 1C. This work provides a practical strategy to increase the Li-ion capacity and cycle stability by tailoring the crystal orientation and nanostructures.     

"通信原理"课程教学改革探索

针对我院省重点专业“电子信息工程”的必修主干专业基础课程。“通信原理”教学中存在的不利于培养和提高学生分析问题、解决问题的能力的因素，从课程的教学内容、教学手段等方面论述了课程改革的基本构想，并对课程的实践环节——设计性实验的改革进行了探讨。     

Minimum spanning trees made easier via multi-objective optimization

Many real-world problems are multi-objective optimization problems and evolutionary algorithms are quite successful on such problems. Since the task is to compute or approximate the Pareto front, multi-objective optimization problems are considered as more difficult than single-objective problems. One should not forget that the fitness vector with respect to more than one objective contains more information that in principle can direct the search of evolutionary algorithms. Therefore, it is possible that a single-objective problem can be solved more efficiently via a generalized multi-objective model of the problem. That this is indeed the case is proved by investigating the computation of minimum spanning trees.This work was supported by the Deutsche Forschungsgemeinschaft (DFG) as part of the Collaborative Research Center Computational Intelligence (SFB 531) and by the German-Israeli Foundation (GIF) in the project Robustness Aspects of Algorithms.     

长庆油田苏平1井固井技术研究与应用

苏平l井完井方式运用了技术套管一次上返、悬挂尾管和筛管技术。该井技术套管段井眼大、裸眼段长，加上大斜度、小间隙的尾管段．对水泥浆体系的性能要求较高。总结分析了长庆天然气水平井苏平l井的固井技术问题，介绍了苏平l井的井身结构与地层性质。通过研究．确定采用低失水GSJ水泥浆体系。该体系成功地应用在三次工程建井过程中，解决了长裸眼、大灰量、大斜度、尾管小间隙等固井技术问题。固井质量达到工程要求。     

Hybrid Approach for Addressing Uncertainty in Risk Assessments

Parameter uncertainty is a major aspect of the model-based estimation of the risk of human exposure to pollutants. The Monte Carlo method, which applies probability theory to address model parameter uncertainty, relies on a statistical representation of available information. In recent years, other uncertainty theories have been proposed as alternative approaches to address model parameter uncertainty in situations where available information is insufficient to identify statistically representative probability distributions, due in particular to data scarcity. The simplest such theory is possibility theory, which uses so-called fuzzy numbers to represent model parameter uncertainty. In practice, it may occur that certain model parameters can be reasonably represented by probability distributions, because there are sufficient data available to substantiate such distributions by statistical analysis, while others are better represented by fuzzy numbers (due to data scarcity). The question then arises as to how these two modes of representation of model parameter uncertainty can be combined for the purpose of estimating the risk of exposure. This paper proposes an approach (termed a hybrid approach) which combines Monte Carlo random sampling of probability distribution functions with fuzzy calculus. The approach is applied to a real case of estimation of human exposure, via vegetable consumption, to cadmium present in the surficial soils of an industrial site located in the north of France. The application illustrates the potential of the proposed approach, which allows the uncertainty affecting model parameters to be represented in a way that is consistent with the information at hand. Also, because the hybrid approach takes advantage of the “rich” information provided by probability distributions, while retaining the conservative character of fuzzy calculus, it is believed to hold value in terms of a “reasonable” application of the precautionary principle.     

Kinetic Studies of the Thermal Decomposition of C60H2 in Solution

Thermal decomposition of C₆₀H₂ in C₆D₄Cl₂ solution at 236°C for 2 hours was shown to produce hydrogen as a product, the hydrogen production was successfully followed by NMR. In order to further explore the rule of thermal decomposition of C₆₀H₂, the dynamics of decomposition reaction was studied and the results showed this decomposition reaction accorded with first order reaction dynamical equation. The experiment temperature was ranged separately in 459K, 455K, 451K, and 446K.     

建筑制图标准中图形符号适宜性、区分性的研究

应用线段长短、间距大小视觉反应的量化规律，提出设计图形符号大小的原则——既更使其大小满足“长”“短”“大”“小”的心理要求，又要互相之间在大小上有区分性。根据图形组织的相似、接近、连续三原则提出设计图形符号形状的原则——图形符号之间尽量减少相似、接近、连续，以保证较好的区分性。通过分析发现，现行建筑制图标准中的图形符号绝大部分在大小和形状具有适宜性、区分性。     

MOSFET亚阈特性分析与低温按比例缩小理论的研究

器件尺寸按比例缩小是实现超大规模集成电路的有效途径，但寄生和二级效应却将器件限在一定的水平，本文在对比分析常温与低温下小尺寸器件效应的基础上，重点研究了ＭＯＳ器件亚阈特性对器件性能及按比例缩小的影响，并根据低温工作的特点，提出了ＭＯＳ器件一种低温按比例缩小规则，该原则对低温器的优化设计，从而更大程度在提高电路与系统性能具有重要的指导意义。