Ultra-fine pitch palladium-coated copper wire bonding: Effect of bonding parameters

Copper (Cu) wire bonding has become a mainstream IC assembly solution due to its significant cost savings over gold wire. However, concerns on corrosion susceptibility and package reliability have driven the industry to develop alternative materials. In recent years, palladium-coated copper (PdCu) wire has become widely used as it is believed to improve reliability. In this paper, we experimented with 0.6 ml PdCu and bare Cu wires. Palladium distribution and grain structure of the PdCu Free Air Ball (FAB) were investigated. It was observed that Electronic Flame Off (EFO) current and the cover gas type have a significant effect on palladium distribution in the FAB. The FAB hardness was measured and correlated to palladium distribution and grain structure. First bond process responses were characterized. The impact of palladium on wire bondability and wire bond intermetallic using a high temperature storage test was studied.     

机械合金化制备表面涂层的力学响应机制数值模拟

以机械合金化法制备金属表面功能涂层这一新型工艺为主要实验背景,通过有限元数值模拟研究在球磨制备涂层的过程中,涂层与基体的界面形貌形成及演变过程,讨论不同工艺参数对界面形貌的影响,进而分析球磨的工艺参数对涂层的制备效果、涂层与基体结合性能的影响。研究不同的球磨参数下,基体材料的残余应力分布和等效塑性应变分布,分析其对基体材料力学性能的影响,并且对该力学响应过程中的热效应进行了数值分析。     

HMDS预处理系统

讲述了HMDS预处理工艺过程,HMDS预处理系统的优越性及该系统的工作原理与结构。     

激光熔覆镍包纳米氧化铝

进行了2Cr13不锈钢表面激光熔覆镍包纳米氧化铝的实验。使用扫描电子显微镜(SEM)、X射线衍射仪(XRD)、X射线能量色散谱仪(EDAX)、显微硬度仪等设备检测了涂层表面、横截面的显微组织和涂层的硬度、耐磨损等性能,分析了加入纳米氧化铝粒子后对涂层组织和性能的影响。研究结果表明,激光熔覆可获得致密的Fe-Ni(Cr)合金和Al2O3粒子复合涂层。其中,纳米氧化铝粒子弥散分布在微细合金晶粒之间,并与合金晶粒一起形成了胞状树枝晶结构。纳米氧化铝粒子的加入增加了基质金属的成核率,起到了细晶强化以及弥散强化的作用,使得复合涂层的机械性能大幅度提高。复合涂层的平均硬度为700HV0.2,比基体提高了1.5倍,耐磨损性能比淬火态基体提高了1.25倍。     

Water-Surface-Mediated Precise Patterning of Organic Single-Crystalline Films via Double-Blade Coating for High-Performance Organic Transistors

Application-oriented growth of patterned organic semiconductor (OSC) thin films with a single domain is a nonnegotiable requirement for the manufacturing of high-performance organic electronic devices. However, the prevalent selective-wetting patterning method remains a challenge in controlling the density of nucleation events in microscale spaces, resulting in thin films with high grain boundary density and no preferential orientation spherulites. Herein, a simple double-blade-coating printing technique using a combination of wetting-patterned substrates to produce an array of highly crystalline OSC thin films is developed. Specifically, the approach confines the OSC crystallization on a molecular-flat water surface in specific areas, enabling a significant reduction in the number of nuclei. Consequently, patterned 2,7-dioctyl[1]benzothieno[3,2-b] benzothiophene (C₈-BTBT) thin films comprising single-crystal domains are achieved with an exceptionally high yield of 62.5%. The organic field-effect transistor array developed from such patterns of C₈-BTBT single-crystalline films exhibits an excellent average mobility of 11.5 cm² V⁻¹ s⁻¹ which is 12.5-fold higher compared to that of the reference sample fabricated via conventional single-blade coating. It is believed that this approach can be widely applied to other soluble organic materials, thereby opening up opportunities for fabricating multicomponent integrated electronics.     

In-Flight Synthesis of Core–Shell Mg/Si–SiOx Particles with Greatly Reduced Ignition Temperature

Magnesium is a promising candidate as a solid fuel for energetic applications, however, the diffusion-controlled oxidation mechanism impedes its reaction with an oxidizer, often resulting in diminished performance. In this study, non-thermal plasma processing is implemented to modify the surface of magnesium nanoparticles with silicon in-flight, in the gas-phase to enhance the rate of interfacial reactions and tune the ignition pathways. Allowing the silicon coating to partially oxidize provides direct contact between the fuel and oxidizer, resulting in a nanostructured thermite system at the single particle level. The proximal distance between oxidizer and fuel directly impacts the ignition temperature and, therefore, the combustion kinetics. An intermetallic reaction occurs within the magnesium/silicon system to supplement the heating of the magnesium fuel to initiate its reaction with the oxidizer, resulting in highly reduced ignition thresholds. The ignition temperature is lowered significantly from ≈740 °C for magnesium particles with a native oxide layer to ≈520 °C for particles coated via the in-flight plasma process.     

镁合金微弧氧化膜表面层与致密层界面组织的研究

研究镁合金微弧氧化膜的表面层与致密层界面处的组织形态。在磷酸盐碱性电解液(5～20g/LNaH2PO4,1～5g/LNaOH,5～8g/LKF,0.5～2g/LNa3C6H5O7,0.5～2g/LEDTA)中,以AZ91镁合金为基体制备出微弧氧化陶瓷薄膜,制备时采用恒电流控制模式,电流密度为10～30A/dm2。采用透射电镜(TEM)和扫描电镜(SEM)研究氧化薄膜界面及附近区域的微观结构。结果表明:微弧氧化膜的表面层靠近表面层与致密层界面处的组织以微晶和纳米晶为主,含有少量非晶态物质;微弧氧化膜的表面层与致密层界面处的组织以非晶态物质为主;微弧氧化膜的致密层靠近表面层与致密层界面处的组织为混晶组织,主要为MgO晶粒,少量为MgAlO4晶粒,并含有少量非晶态物质。     

压电陶瓷银层附着力及其影响因素

通过瓷件表面粗糙度、瓷件的清洗方式、烧渗银温度和曲线等工艺过程的试验,研究了压电陶瓷银层附着力的影响因素。结果表明主要影响因素是瓷件表面粗糙度、清洁度以及银层烧结温度和曲线。在实际应用中,如果用天然石榴石金刚砂W40微粉细磨瓷件表面,再采用超声波清洗及煅烧,然后在780℃左右烧渗银,可使附着力达到最大,约1800N/cm2。     

钛合金表面激光熔覆Ti C复合涂层的设计

钛合金具有比强度高、耐腐蚀性能好等优点, 但其硬度低、耐磨性能差, 限制了它在航空工程摩擦构件和生物医学工程上的应用。研究自行设计了3种预涂粉层的成分, 采用HL-5000型横流CO2激光加工机在TC4钛合金表面相应地制备了TiC+Ti、 TiC+Ti+ F102和TiC+ F102 3种熔覆层。通过SEM, EDAX, XRD, HXD-1000TMC型显微硬度计, HT-600型高温摩擦磨损试验机, 分析了熔覆层的显微组织、成分、物相, 测试了激光熔覆层的显微硬度和滑动摩擦磨损性能。结果表明: (TiC+Ti+ F102)和(TiC+ F102)熔覆层有可能用于航空结构材料;而(TiC+Ti)熔覆层有希望用于生物医学功能材料, 但仍需作进一步的研究。     

1.06μm高功率激光反射膜

为提高反射膜的抗激光强度,对ZrO_2-SiO_2多层介质膜的制造工艺进行了深入的研究。已制备出高反射膜和激光输出膜在λ_0=1.064μm处,激光脉宽为1.2ms的单脉冲激光照射下,能承受的能量密度为160J/cm~2;在重复频率为20次/s的激光照射下,能承受的功率密度为1.5kW/cm~2,承受打激光脉冲300万次膜层不损坏,并通过了16kW/cm~2承受激光脉冲7.2万次的超负荷试验。