TWO-STEP MECHANISM IN HETEROGENEOUS CATALYSIS AND DYNAMIC ANALYSIS

Recent development of the dynamic analysis technique has made it possible to measure separately kinetic parameters of a catalytic reaction as well as to study the effect of catalyst preparation parameters. But its application is still limned to first-order reaction. This work is aimed to demonstrate in some detail that,by comparison of the reaction rate expressions with the two-step mechanism used in catalytic kinetics and dynamic analysis, these methods can be extended to non-first-order reaction, and the kinetic parameters measured by dynamic techniques are interpreted for different reaction mechanisms.     

Pb(Mg_(1+x)/3Nb_(2-x)/3)O_3铁电材料中有序-无序相变的理论研究

基于Kikuchi自洽迭代方法,利用有序-无序相变理论,并取最近邻相互作用近似,研究了Pb(Mg_((1+x)/2)Nb_((2-x)/2)O_3晶粒中在x=0.5时有序区形成的原因,提出Mg~(2+)∶Nb~(5+)=1∶1(离子数比)时,形成B位有序排列最为有利,并且弱的空间电荷场不影响这种有序排列的形成,同时给出了温度-组份的有序-无序相图。     

清洁镀铬用紫色硫酸铬

紫色硫酸铬是一种新型清洁镀铬（Cr^3 镀铬）的原料，在镀铬中显示了优良的性能，特别是镀液无需预电解处理亦能得到满意镀层这一实验结论，使清洁镀铬工艺实现工业生产又向前迈进了一步，介绍了它的制法，技术要求，物相分析及使用效果。     

The application of small angle scattering techniques to porosity characterization in carbons

Small angle scattering (SAS) techniques offer a number of advantages for the investigation of the nature and behavior of porous materials. In particular, with respect to carbons, the essentially non-intrusive nature of SAS means that along with the more traditional, pre- and post-treatment characterization of carbons, in principle, characterization can also be performed in situ during adsorption and activation processes. In the current communication, the application of the techniques of small angle X-ray (SAXS) and neutron (SANS) scattering is reviewed specifically with respect to porosity characterization in carbons. First, the basis of these techniques is presented. More recent applications of SAXS and SANS to carbon porosity are presented, and their relative attributes are contrasted, including the related technique of contrast matching with SANS to distinguish “closed” from “open” porosity, and its application to elucidation of pore development mechanisms. Applications of other related techniques, such as μSAXS and TGA/SAXS, to carbon characterization and porosity development are also discussed.     

Flow regime, hydrodynamics, floc size distribution and sludge properties in activated sludge bubble column, air-lift and aerated stirred reactors

This paper presents a comparative study how reactor configuration, sludge loading and air flowrate affect flow regimes, hydrodynamics, floc size distribution and sludge solids-liquid separation properties. Three reactor configurations were studied in bench scale activated sludge bubble column reactor (BCR), air-lift reactor (ALR) and aerated stirred reactor (ASR). The ASR demonstrated the highest capacity of gas holdup and resistance, and homogeneity in flow regimes and shearing forces, resulting in producing large numbers of small and compact flocs. The fluid dynamics in the ALR created regularly directed recirculation forces to enhance the gas holdup and sludge flocculation. The BCR distributed a high turbulent flow regime and non-homogeneity in gas holdup and mixing, and generated large numbers of larger and looser flocs. The sludge size distributions, compressibility and settleability were significantly influenced by the reactor configurations associated with the flow regimes and hydrodynamics.     

7万吨/年催化裂化装置技术改造及装置现状分析

阐述催化裂化装置５×１０４ｔ／ａＦＣＣＵ技改为７×１０４ｔ／ａＡＲＧＧ的技改内容及工艺特点，并对装置运行现状进行分析。重点就进一步提高液化气收率以及稳定、优化装置长周期、高效运行进行探讨、研究。     

污水处理厂PPP项目优选研究

如何在众多污水处理厂PPP项目中挑选出风险低、回报适宜的优质项目不仅是社会资本方关注的重点,也是推动PPP项目顺利开展的关键。从社会资本方的角度出发,建立政府能力及环境、项目特征、项目影响3个方面的较为完善的污水处理厂PPP项目评价体系,采用聚类分析法从类别内、类别间两方面综合计算专家权重,以此修正AHP法确定的指标权重,并结合TOPSIS模型对众多污水处理厂PPP项目进行比较,优选出最适宜投资的项目。通过实例验证,此方法可行、有效,且社会资本方对项目特征、政府能力及环境两方面非常重视。     

基于KPCA-PSO-SVM的径流预测研究

为提高径流预测模型的准确性与稳定性,对KPCA-PSO-SVM的径流预测方法进行了研究。在分析径流影响因素的基础上,利用核主成分分析(KPCA)法对径流影响因子进行非线性特征提取,获得主成分作为支持向量机(SVM)的输入变量,建立了径流预测SVM模型,其中模型参数通过粒子群算法(PSO)进行优化。模型建立后,以新疆伊犁河雅马渡站中长期径流预测为例进行分析。预测分析结果表明,在拟合和检验阶段模型的平均相对误差分别为0.77%和7.64%,与其他预测模型比较,基于KPCA-PSO-SVM方法建立的径流预测模型有较好的预测和泛化能力,是一种行之有效的中长期径流预测方法。     

昭通横江流域年径流预测

针对昭通横江由南到北贯穿昭通全境,水资源量丰富,但南北差异大,南部少、北部多的特点,根据流域内水文站实测年径流、大气环流指数、海温指数及其他指数等资料系列,采用多元回归分析法拟合1981—2010年径流,建立了预测模型,验证、预测分析了2011—2016年径流量。结果表明:干流控制站预测精度高于干流上段及支流代表站,水利工程建设等人类活动影响是导致出现这样结果的主要原因;多元回归分析在横江流域径流预测中具有一定的适应性,但因指标的差异及相关参数可获取性的差异,预测结果存在区域间、等级间的差别。     

既有项目法人项目盈利能力分析的简化

在评价既有项目法人项目时,根据项目实际情况,分析选取相关技术经济评价数据,避开现有资产的分析,从而达到简化盈利能力分析的目的。