全文获取类型
收费全文 | 1519篇 |
免费 | 42篇 |
国内免费 | 15篇 |
专业分类
综合类 | 29篇 |
化学工业 | 435篇 |
金属工艺 | 21篇 |
机械仪表 | 167篇 |
建筑科学 | 72篇 |
矿业工程 | 8篇 |
能源动力 | 37篇 |
轻工业 | 202篇 |
水利工程 | 2篇 |
石油天然气 | 63篇 |
无线电 | 109篇 |
一般工业技术 | 266篇 |
冶金工业 | 46篇 |
原子能技术 | 48篇 |
自动化技术 | 71篇 |
出版年
2024年 | 1篇 |
2023年 | 14篇 |
2022年 | 23篇 |
2021年 | 33篇 |
2020年 | 18篇 |
2019年 | 18篇 |
2018年 | 19篇 |
2017年 | 37篇 |
2016年 | 35篇 |
2015年 | 37篇 |
2014年 | 64篇 |
2013年 | 77篇 |
2012年 | 104篇 |
2011年 | 152篇 |
2010年 | 98篇 |
2009年 | 119篇 |
2008年 | 96篇 |
2007年 | 110篇 |
2006年 | 81篇 |
2005年 | 73篇 |
2004年 | 52篇 |
2003年 | 65篇 |
2002年 | 34篇 |
2001年 | 27篇 |
2000年 | 32篇 |
1999年 | 34篇 |
1998年 | 28篇 |
1997年 | 12篇 |
1996年 | 11篇 |
1995年 | 14篇 |
1994年 | 11篇 |
1993年 | 7篇 |
1992年 | 7篇 |
1991年 | 7篇 |
1990年 | 7篇 |
1989年 | 3篇 |
1988年 | 2篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1984年 | 2篇 |
1983年 | 5篇 |
1982年 | 1篇 |
1981年 | 1篇 |
排序方式: 共有1576条查询结果,搜索用时 15 毫秒
21.
Huili Chen Yanbo Wu Yunfei Cheng Hong Yang Fuyou Li Pin Yang Chunhui Huang 《Inorganic chemistry communications》2007,10(12):1413-1415
Spectroscopic studies revealed that the compound [N,N′-di(quinoline-2-methylene) -1,2-phenylenediimine] (1) exhibited a rather high selectivity toward Zn2+ over other metal ions, even Cd2+. In acetonitrile, the red shift of fluorescent emission from 396 nm to 426 nm upon zinc binding is due to the formation of a 1:1 metal/ligand complex. 相似文献
22.
为了分析测定茶叶中铅的含量,采用硝酸、高氯酸混合酸消解茶叶试样,氢化物发生-原子荧光光谱法测定铅,探讨了仪器条件及氢化物发生的最佳实验条件。方法的检出限为0.021 ng/mL,相对标准偏差为3.12%和3.69%,线性方程为y=52.724x+104.094,相关系数R2=0.9992。 相似文献
23.
Ya-Ping Sun Robert D. Miller R. Sooriyakumaran Josef Michl 《Journal of Inorganic and Organometallic Polymers》1991,1(1):3-35
A comprehensive study of the electronic absorption and emission spectra and the fluorescence quantum yield and lifetime of seven poly(di-n-alkylsilane)s and of three isotopically labelled poly(di-n-hexylsilane)s in hydrocarbon solution at room temperature is reported. Also reported are fluorescence polarization and carbon tetrachloride quenching of fluorescence of poly(di-n-hexylsilane). The observed fluorescence spectra, quantum yield, and polarization depend on the selected excitation energy in a very characteristic fashion, whereas the fluorescence lifetime does not; however, it depends on the selected emission energy. These characteristic dependencies are qualitatively accounted for by the previously proposed segment distribution model if one assumes that the photophysical behavior at higher excitation energies is strongly affected by the presence of a low-lying weakly allowed state in short-segment chromophores and the behavior at lower excitation energies is dictated by the selective excitation of emitting long-segment chromophores. 相似文献
24.
通过自由基胶束共聚法制备了N-苄基-N-n-十六烷基丙烯酰胺/丙烯酰胺/丙烯酸钠三元共聚两亲聚合物-P(AM/BHAM/NaA),并优化了合成方案。该聚合物具有临界聚集浓度(CAC),当该两亲聚合物质量浓度高于700mg/L时,P(AM/BHAM/NaA)在水溶液中形成聚集体,并随着聚合物质量浓度的增加聚集体的流体力学半径增加,表观黏度也随之增加。P(AM/BHAM/NaA)具有良好的原油乳化能力,研究了不同质量浓度的两亲聚合物对原油乳化性能。结果表明,随着两亲聚合物质量浓度的升高,在水溶液中形成聚集体的体积增大,空间网络结构增大,乳化能力升高。 相似文献
25.
Sohei Sato Hironori Hondoh Satoru Ueno 《Journal of the American Oil Chemists' Society》2021,98(3):269-280
Fat bloom in chocolate is a substantial problem that affects its sensory properties, such as texture and appearance. This phenomenon is because of diffuse light reflection on a roughened surface of chocolate, caused by structural changes of fat crystals subjected to various temperature conditions. The purpose of this study is to characterize the fat bloom formed through gradual two-step cooling after exposure to temperatures (35–37 °C) slightly above the cocoa butter Form βV melting point (33.8 °C). To clarify the fat bloom formation process, the structural changes in cocoa butter and on the chocolate surface, at the dynamic thermal condition for bloom formation, was investigated using X-ray diffraction (XRD), fluorescence light microscopy, and scanning electron microscopy (SEM). The results revealed that an entirely light brown fat bloom occurred, even in the absence of the Form βVI or other polymorphic transformation. Microscopic observation showed that the light brown appearance was because of the porous structure on the chocolate surface. This porous structure was formed by liquid oil moving inside of chocolate from the surface. The formation of a coarse network and the subsequent de-oiling, because of movement of unsolidified liquid fat into the chocolate, appeared to be the main causes of bloom formation. Therefore, a coarsened fat network and oil movement besides the conventional principles of polymorphic transformation of cocoa butter should be considered. 相似文献
26.
The ability to manipulate the intracellular environment within living cells and to monitor the cytosolic chemical changes which occur during cell stimulation has lead to major advances in our understanding of how cells read and respond to their environment. Perhaps the most powerful suite of techniques for achieving these dual objectives is based on the use of light (photons). Because cells are 'transparent', light has been used to both interrogate and manipulate the chemistry inside living cells, exploiting technical advances in both the physical and biochemical sciences. However, cells are neither transparent nor homogeneous with respect to their optical properties. The interface between light and the living cell cytoplasm thus represent an important, yet largely ignored, interface. There has been no review of the optical properties of cytoplasm and little discussion about how the optical properties of living cytoplasm influence the outcome of such measurements and manipulations. In this short review, we discuss the importance of understanding the optical properties of cytoplasm for such techniques and how imperfections in experimental interpretation can arise. 相似文献
27.
Kathiravan Vaiyapuri Thangavel Subramani Ashok Kumar Rajamani Muthu Lakshmi Thangavel Satheesh Kumar Ganesan Selvarajan Palanisamy Kumaresavanji Malaivelusamy 《电子科技学刊:英文版》2022,20(4):345-355
Single crystals of L-alanine cadmium iodide (LACI) were grown by the slow evaporation technique at room temperature. A single-crystal X-ray diffraction (SXRD) model was used to evaluate the crystal structure of the as-grown LACI crystal. The energy dispersive X-ray (EDX) analysis and ultraviolet-visible-near infrared (UV-vis-NIR) transmittance studies were carried out, and the results reveal the presence of elements in the title compound. From the transmittance data, the optical bandgap as a function of photon energy was estimated, and the different optical constants were calculated. A fluorescence study was performed for the LACI crystal. Thermogravimetric and differential thermal analyses have also been studied to investigate the thermal property of the LACI crystal. The efficiency of the second harmonic generation (SHG) of the title crystal was investigated. The magnetic and electrical properties were estimated by the vibrating sample magnetometer (VSM) analysis and impedance study, respectively. 相似文献
28.
《Current Opinion in Solid State & Materials Science》2017,21(1):35-42
Ever since the discovery of fullerenes in 1985, nanocarbon has demonstrated a wide range of applications in various areas of science and engineering. Compared with metal, oxide, and semiconductor nanoparticles, the carbon-based nanomaterials have distinct advantages in both biotechnological and biomedical applications due to their inherent biocompatibility. Fluorescent nanodiamond (FND) joined the nanocarbon family in 2005. It was initially developed as a contrast agent for bioimaging because it can emit bright red photoluminescence from negatively charged nitrogen-vacancy centers built in the diamond matrix. A notable application of this technology is to study the cytoplasmic dynamics of living cells by tracking single bioconjugated FNDs in intracellular medium. This article provides a critical review on recent advances and developments of such single particle tracking (SPT) research. It summarizes SPT and related studies of FNDs in cells (such as cancer cell lines) and organisms (including zebrafish embryos, fruit fly embryos, whole nematodes, and mice) using assorted imaging techniques. 相似文献
29.
Xia Yu Derrick Yong Huiyu Zhang Hao Li Ying Zhang Chi Chiu Chan Ho-Pui Ho Hairong Liu Deming LiuAuthor vitae 《Sensors and actuators. B, Chemical》2011,160(1):196
We report excitation of surface plasmon in a gold-coated side-polished D-shape microstructure optical fiber (MOF). As the leaky evanescent field from the fiber core becomes highly localized by the plasmon wave, its intensity also gets amplified significantly. Here we demonstrate an efficient use of this intensified field as excitation in fluorescence spectroscopy. The so-called plasmonic enhanced fluorescence emission from Rhodamine B has been investigated experimentally. First, plasmonic effect alone was found to provide an immediate fluorescence enhancement factor of two. Second, experimental results show a good agreement with theoretical modeling. Strong evanescent field generation and surface enhancement with simple metallic coating makes this fiber based device a good candidate for compact fluorescence spectroscopy. 相似文献
30.
Ajit Kumar MahapatraAuthor Vitae Giridhari HazraAuthor VitaeNirmal Kumar DasAuthor Vitae Shyamaprosad GoswamiAuthor Vitae 《Sensors and actuators. B, Chemical》2011,156(1):456-462
A new triphenylamine-based fluorogenic probe bearing an indolylmethane unit (R1) was developed as a fluorescent chemosensor with high selectivity toward Cu2+ over other cations tested. The new probe R1 only sensed Cu2+ among heavy and transition metal (HTM) ions in CH3CN/H2O (70/30, v/v) solution. The capture of Cu2+ by the receptor resulted in deprotonation of the secondary amine conjugated to the triphenylamine, so that the electron-donation ability of the “N” atom would be greatly enhanced; thus sensor showed a 250 nm change in the new absorption band (from 291 nm to 541 nm) and a large colorimetric response, it also exhibited the large decrease in fluorescence intensity at 378 nm and affinity to Cu2+ over other cations such as Hg2+, Fe3+, Pb2+, Zn2+, Cd2+, Ni2+, Co2+ and Mn2+ make this compound a useful chemosensor for Cu2+ detection in CH3CN/H2O (70/30, v/v) mixture. The probe R1 (c = 1.0 × 10−6 M) displayed significant fluorescence change and colorimetric change upon addition of Cu2+ among the metal ions examined. 相似文献