尿素生产中尿液的不稳定流动对尿素一分塔的影响

介绍了水溶液全循环法尿素生产系统中,一分塔的精馏段由泡罩塔盘改为规整填料后出现的一系列问题,针对尿液的不稳定流动造成一分塔规整填料严重腐蚀的原因,进行分析并提出整改和预防措施。     

A SIMPLE METHOD FOR STUDYING THE KINETICS OF GAS-SOLID REACTIONS IN A FLUIDIZED BED REACTOR

A methodology for studying the kinetics of gas-solid reactions in a fluidized bed reactor is presented. This procedure is based on the analysis of the response of the system (flue gases) when batches of solids of different weight are added to the reactor. The method has been applied to the study of limestone particle calcination. The calcination rate constants obtained are in good agreement with those found in the literature. The method offers the advantage of simplicity and avoids the use of model assumptions or empirical correlations.     

MATHEMATICAL MODELING OF THROUGH-HOLE-PLATING IN ELECTROCHEMICAL MICROFABRICATION II. AXISYMMETRIC TWO-DIMENSIONAL CONVECTIVE MASS TRANSFER

Axisymmetrical, two dimensional mass transfer in a tube and a through-hole was studied. The elliptic convective-diffusion equation was solved numerically by taking into account both the axial and radial diffusion in the entrance region of an infinite tube. The whole mass-transfer region in a tube of finite length was also studied by dividing the domain into several regions according to different mass-transfer mechanisms. A similar analysis is then conducted for a through-hole geometry by assuming a modified Hagen-Poiseuille fluid pattern. Results show that mass-transfer rate in a through-hole is larger than that in a tube by approximately 10%. This is due primarily to faster fluid flow within the concentration boundary layer in a through-hole.     

Flow regime, hydrodynamics, floc size distribution and sludge properties in activated sludge bubble column, air-lift and aerated stirred reactors

This paper presents a comparative study how reactor configuration, sludge loading and air flowrate affect flow regimes, hydrodynamics, floc size distribution and sludge solids-liquid separation properties. Three reactor configurations were studied in bench scale activated sludge bubble column reactor (BCR), air-lift reactor (ALR) and aerated stirred reactor (ASR). The ASR demonstrated the highest capacity of gas holdup and resistance, and homogeneity in flow regimes and shearing forces, resulting in producing large numbers of small and compact flocs. The fluid dynamics in the ALR created regularly directed recirculation forces to enhance the gas holdup and sludge flocculation. The BCR distributed a high turbulent flow regime and non-homogeneity in gas holdup and mixing, and generated large numbers of larger and looser flocs. The sludge size distributions, compressibility and settleability were significantly influenced by the reactor configurations associated with the flow regimes and hydrodynamics.     

药用中间体苯丙酮含量的气相色谱/质谱分析

苯丙酮是合成利胆药苯丙醇的重要中间体。本文建立了用气相色谱 /质谱法 (GC/MS)测定苯丙酮含量的方法。组分的定性依靠GC/MS联用技术和NIST谱库标准质谱图对照分析。以苯乙酮为内标 ,苯丙酮含量在 1.0× 10 -5～ 2 .0× 10 -4g/mL范围内呈线性 ,线性相关系数r =0 .994 9,苯丙酮最低检测浓度为 1.0× 10 -8g/mL。该法操作简便、快速 ,结果准确可靠 ,且具有很好的实用价值     

塑料充模流动粘性模型研究

对多种塑料在不同温度下的剪切速率一稳态剪切粘度数据进行Cross粘性模型参数拟合，得到了表征材料粘度的模型参数(B，Tb，τ^*，n)。其拟合效果良好，能较准确地描述塑料熔体在一定剪切速率和温度范围内的粘流特性，为工程计算和塑料熔体模流分析提供了数据支持。结果表明，该方法有较广泛的适用性。     

容器设计中搅拌装置的轴向力分析

搅拌装置在化工厂中应用很广，在磷肥、钛白粉装置中（15kt/a)使用较多，仅钛白粉装置中就大约有40－50台，如增稠结晶器，中和槽等，搅拌操作所涉及的因素极为复杂，浆叶形式的选择，从力学的观点来说，迄今研究不够，本文就搅拌装置产生的轴向力问题进行了初步研究。     

LOCAL EQUILIBRIUM THEORY FOR THE DYNAMICS OF NONISOTHERMAL MIXED GAS ADSORPTION OF HIGH-CONCENTRATION COMPONENTS

A local equilibrium theory for nonisothermal gas adsorption is developed which accounts for variations in interstitial gas velocity induced by adsorption. Also presented are expressions describing the entropy admissibility criterion. A solution is developed for a Riemann's problem involving adiabatic gas-phase adsorption where there is no inert diluent and where Langmuir isotherms apply.     

A reactive extension of the OpenMusic visual programming language

Objectives: OpenMusic (OM) is a domain-specific visual programming language designed for computer-aided music composition. This language based on Common Lisp allows composers to develop functional processes generating or transforming musical data, and to execute them locally by demand-driven evaluations. As most historical computer-aided composition environments, OM relies on a transformational declarative paradigm, which is hard to conciliate with reactive data-flow (an evaluation scheme more adequate to the development of interactive systems). We propose to link these two evaluation paradigms in the same and consistent visual programming framework.Methods: We establish a denotational semantics of the visual language, which gives account for its demand-driven evaluation mechanism and the incremental construction of programs. We then extend this semantics to enable reactive computations in the functional graphs.Results: The resulting language merges data-driven executions with the existing demand-driven mechanism. A conservative implementation is proposed.Conclusions: We show that the incremental construction of programs and their data-driven and demand-driven evaluations can be smoothly integrated in the visual programming workflow. This integration allows for the propagation of changes in the programs, and the evaluation of graphically designed functional expressions as a response to external events, a first step in bridging the gap between computer-assisted composition environments and real-time musical systems.     

低雷诺数气液交叉流装置研究（I）——孔流液柱流动特性数值模拟

针对低雷诺数的气液交叉流气体净化过程,提出有效避免二次雾沫夹带的液柱流体力学条件。数值模拟结果表明,液柱表面随着离开孔口的距离而变化,采用公式Lb／d=2．84We^0.694能有效预测液柱的断裂行为。