Morphology Transformation Pathway of Block Copolymer-Directed Cooperative Self-Assembly of ZnO Hybrid Films Monitored In Situ during Slot-Die Coating

Cooperative self-assembly (co-assembly) of diblock copolymers (DBCs) and inorganic precursors that takes inspiration from the rich phase separation behavior of DBCs can enable the realization of a broad spectrum of functional nanostructures with the desired sizes. In a DBC assisted sol–gel chemistry approach with polystyrene-block-poly(ethylene oxide) and ZnO, hybrid films are formed with slot-die coating. Pure DBC films are printed as control. In situ grazing-incidence small-angle X-ray scattering measurements are performed to investigate the self-assembly and co-assembly process during the film formation. Combining complementary ex situ characterizations, several distinct regimes are differentiated to describe the morphological transformations from the initially solvent-dispersed to the ultimately solidified films. The comparison of the assembly pathway evidences that the key step in the establishment of the pure DBC film is the coalescence of spherical micelles toward cylindrical domains. Due to the presence of the phase-selective precursor, the formation of cylindrical aggregates in the solution is crucial for the structural development of the hybrid film. The pre-existing cylinders in the ink impede the domain growth of the hybrid film during the subsequent drying process. The precursor reduces the degree of order, prevents crystallization of the PEO block, and introduces additional length scales in the hybrid films.     

受激布里渊散射(SBS)中的三类介质

介绍了目前使用的三类受激布里渊散射介质的化学结构及其SBS性能．并且分析了受激布里渊散射对介质的要求，     

切换通信拓扑条件下的无人机集群构型变换控制

研究了在切换通信拓扑条件下的无人机集群构型变换控制问题。基于一致性控制理论,对具有2阶积分特性的无人机集群设计了构型变换控制协议,为使无人机集群能够实现特定构型变换并保持特定速度,在控制协议中引入编队参考向量。给出了在通信拓扑切换情况下无人机集群实现特定构型变换并保持特定速度的充分必要条件。在通信拓扑图保持连通的条件下,利用Lyapunov稳定性理论证明了无人机集群系统稳定性,并利用代数黎卡提方程理论给出了控制协议中参数矩阵的设计方法。数值仿真结果验证了所设计的控制协议有效性。     

基于对潜防御航母编队反潜舰阵位配置模型

基于航母编队对潜防御建立反潜舰阵位配置模型,需要立足于拖曳线列阵声纳使用和航母编队作战特点。 针对拖曳线列阵声纳使用,提出相邻反潜舰最小间距确定方法和弥补盲区措施;针对反潜舰在航渡和综合作战区中 承担的任务,运用解析法建立反潜舰阵位配置模型。在此基础上,通过设定合理参数进行仿真分析验证模型。结果 表明,该模型能为航母编队反潜舰阵位配置提供理论参考。     

掩护攻击下从弹的导航与制导方法

针对全导式多弹头在确保射击精度与弹头密集分布条件下的作战需求,提出了一种数值导航计算和相对制导的方法。基于零视加速度理论,在自由段采用数值导航计算方法,有效地消除了惯性导航系统加速度计漂移误差对导航精度的影响,减小了弹头落点偏差。以摄动制导理论为基础,研究了从弹伴随主弹飞行的相对制导方法,设计了满足落点约束的姿态控制方程和制导关机方程,将从弹和主弹分离时刻的状态参数作为标准关机量,实时计算分离后从弹的关机量并与标准关机量进行对比,满足相对距离条件则实施关机。仿真表明:通过数值导航与相对制导方法能有效实现全导式多弹头的伴随飞行,并以较高精度命中目标,从弹掩护主弹攻击的效果较好。     

GAP基自修复粘结剂的制备及性能

为了延长粘结剂的储存寿命,采用一步法将具有可自修复性能的双硫官能团引入叠氮粘结剂中,首次合成了具有自修复性能的聚叠氮缩水甘油醚(GAP)基自修复粘结剂。通过傅里叶红外光谱(FTIR)、X射线衍射(XRD)和光学显微镜对其结构和表面形貌进行表征,在此基础上,通过自修复前后拉伸强度的变化,考察了不同自修复温度和不同自修复时间下的自修复效率。结果显示:合成的GAP基自修复粘结剂具有聚氨酯结构,60℃下24 h后表面裂纹基本愈合完全。提高自修复温度和延长自修复时间,均有助于提高体系的自修复效率。同时随着交联剂质量分数的增加,自修复效率先提高后降低,其中交联剂质量分数为8%的配方,自修复效率可达98.2%,相对于自修复效率为61.7%的对比样,表明双硫官能团的引入能够提高体系的自修复效率。     

A highly luminescent organic crystal with the well-balanced charge transport property: The role of cyano-substitution in the terminal phenyl unit of distyrylbenzene

1,4-bis(2-cyano styryl)benzene (2-CSB) crystal with cyano substituent groups introduced to the terminal phenyl rings of distyrylbenzene (DSB) has been prepared and its luminescence efficiency could be as high as ∼55%. Based on the analyses of cyclic voltammetry and crystal structure, cyano substituents not only lower the LUMO level but also result in a change of the packing mode from the herringbone arrangement to the face-to-face slipped π stacking motif. Then field-effect transistors (FETs) based on high-quality 2-CSB crystals grown by the physical vapor transport method have been fabricated and the highest hole and electron mobilities were measured as 0.66 and 0.29 cm²/Vs, which enhanced the corresponding values of DSB crystal by up to one and two orders of magnitude, respectively. 2-CSB crystal simultaneously combined the high luminescence and the well-balanced mobility is expected to be of interest for the fundamental research of organic light-emitting devices.     

Crack formation in metallized single crystal silicon substrates

Ball bonding of metallized silicon substrates has been simulated by microindentation, with a hemispherical diamond indentor, of (100) silicon wafers that contained aluminum film layers. The indentation loads varied up to 35N and the thickest aluminum film, composed of four layers, was 100 × 10^-6 m. The radial cracks in the silicon, beneath the aluminum film, were measured as a function of indentation load and aluminum film thickness, and compared to that of unmetallized silicon. The crack lengths have been used to determine the fracture toughness,K _c = 24.4 ± 4.9 MPam^0.5, which is twice the value obtained by Vickers indentation experiments. A model describing the relationship between the film thickness versus the radial crack length is presented.     

基于GPRS的车队管理系统传输协议

GPRS(通用分组无线电业务)由于其流量计费、高速传输等特点,正越来越广泛地用于车载监控、电力抄表、气象监测等行业的远程数据传输。它支持TCP/IP协议体系,然而用户面对可选的UDP(用户数据报协议)与TCP(传输控制协议),没有明确的选择标准。文中主要将这两种协议进行对比,从可靠性、适用性、资费等方面讨论了在GPRS网络上,两种数据传输协议在车队管理系统中的适用性。     

无人水面艇在信息战中的应用

通过对无人水面艇历史和现状的介绍,以及对信息战概念的理解,提出了无人水面艇信息作战的思想。对无人水面艇在信息战中的应用做出了分析和展望,认为无人水面艇在信息战中将扮演重要角色。