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91.
Flory's equation-of-state theory has been used to predict the lower critical solution temperature behaviour of polymer—polymer mixtures. The spinodal phase boundary of numbers of high molecular weight polymer mixtures have been previously simulated using this theory. In this paper a procedure for simultaneous predictions of the binodal and the spinodal curves by equating the chemical potential of each component in the mixture is presented. The method is tested for five different mixtures. The effects of the binary and pure component state parameters on the simulated curves are discussed and the simulated phase diagrams are compared with the experimental cloud point curves. It is found that in most cases the results are more consistent with the cloud point curve being closer to the spinodal curve than the binodal. 相似文献
92.
93.
Magnetic and electric fields have been used to determine the splay (k11) and bend (k33) elastic constants in a series of polymer/monomer liquid crystal solutions using the well known Freedericksz transition technique. Measurements have been carried out as a function of concentration and temperature. The polymer used was a smectogenic polysiloxane side chain liquid crystal with both cyanobiphenyl and benzoate ester side groups. The monomeric solvent was the nematogen 4-n-pentyl-4′-cyanobiphenyl. All of the solutions studied were nematogenic up to a concentration of 40% w/w. It has been shown that k11, k33 and all decrease with increasing polymer concentration and that at high enough concentrations tends to become independent of temperature. The implications of these results are discussed in terms of the performance of the most common liquid crystal display, i.e. the twisted nematic device. 相似文献
94.
Thermodynamic parameters have been determined for the interaction of methyl orange and poly(vinylpyrrolidone) in aqueous solutions containing tris, tris and hydrochloric acid, or water only. Enthalpy changes were determined by use of a flow microcalorimeter. Free energy changes were calculated from the results of equilbrium dialysis studies. The results are interpreted in terms of the behaviour of poly(vinylpyrrolidone) in these systems. Analysis of data shows that the hydrophobic interactions in the systems are in the order: tris > wateronly > tris-HC1. 相似文献
95.
The viscoelastic properties of a three-arm and a four-arm star polybutadiene with the same arm molecular weight (Ma) were studied. The zero-shear recoverable compliance (J0e) and plateau modulus (G0N) for these stars are the same. The zero-shear viscosity (η0) of the three-arm star is 20% lower than that of the four-arm star. Mixtures of the stars had J0e and G0N unchanged. A mixture of the three- and four-arm star was diluted with a low molecular weight linear polybutadiene. G0N∝ø2; J0e∝ø?1 and Me∝ø?1, as expected for dilution with a θ-solvent. 相似文献
96.
注聚井注入状况诊断方法研究 总被引:3,自引:3,他引:0
在室内试验和动态分析的基础上,对引起注聚井注入困难的原因进行了分析,提出了利用单井动态预测结果和实际注入动态曲线对比判断聚合物注入状况的方法,建立了预测注聚井注入动态的预测模型,并对数值模拟计算结果进行了分析。同时还评价了现场应用效果。通过数值模拟和实际注入动态曲线对比,可以初步判断待措施井有无近井地带堵塞,为提高注聚井压解堵措施的有效性奠定了基础。 相似文献
97.
透湿膜的透湿机理与膜的研究概况 总被引:2,自引:0,他引:2
基于透湿膜的空气除湿是一种比较新颖的空气除湿方法。本文介绍了各种膜在空气除湿领域的应用情况,结合对膜制备工艺的简要介绍,侧重对原除湿原理,亲水性的高分子纤维素膜,凝胶膜和分子筛无机膜在空气除湿领域的研究和进展进行了分析。 相似文献
98.
Dominique PinoitRobert E Prud'homme 《Polymer》2002,43(8):2321-2328
The phase behavior of ternary blends made of poly(epichlorohydrin) (PECH), poly(vinyl acetate) (PVAc) and poly(methyl methacrylate) (PMMA) has been investigated by differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (DMTA). DMTA measurements have been shown to be more sensitive than DSC for the detection of a second phase, for the determination of the composition of each phase, and the distribution of PECH in each of them. About 70% PECH was required to obtain a single narrow Tg in the ternary system, which suggests a single homogeneous phase in the limit of sensitivity of DMTA. This study also emphasizes the importance of the composition of the immiscible polymer pair (i.e. the PVAc/PMMA pair in the PECH/PVAc/PMMA system), in addition to the thermodynamic interaction parameters, for controling the phase behavior of ternary systems. 相似文献
99.
液晶杂环高聚物的合成 总被引:3,自引:0,他引:3
首次较详细地论述了聚苯撑苯并二噻唑或二咪唑(PBT或PBO或PBI)、聚苯并噻唑或恶唑(ABPPBT或ABPBO)、聚苯并二咪唑苯并菲绕啉二酮(PQ)及其衍生物的合成方法和相应的特性粘数。 相似文献
100.
Using the batch method, the retention of Ga(III) from HCl solutions by two gel‐type pyridine strong‐base anion exchangers containing 1‐methyl‐ or 1‐butyl‐4‐vinylpyridinium chloride structural units, called S1 and S2 resins, respectively, was studied. The influence of the HCl and Ga(III) concentrations as well as of the contact time between the resin and the liquid phase was investigated. The parameters, which characterize the retention process, were estimated using Langmuir and Freundlich isotherms. Both resins exhibited a higher affinity for gallium ions from a 6M HCl solution. According to Langmuir isotherms, maximum retention capacities of 44.44 and 60 mg Ga(III)/g dry resin for the S1 and S2 resins, respectively, were obtained. Freundlich isotherms provide additional proof for a higher affinity of the S2 resin for Ga(III) from HCl solutions. It is clear that the substituent length increase on N+ atoms led to an increasing affinity of the pyridine strong base anion exchangers toward Ga(III). © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 86: 3440–3444, 2002 相似文献