ICP-AES法测定钢样中钨和铌元素的含量

介绍ICP-AES法测定钢样中钨和铌的方法,并研究该方法的最佳工作条件。通过对样品的分析试验、回收试验及精密度试验,证明该方法准确度高,与化学法相比,缩短试验周期。     

Cl_2/H_2 ICP刻蚀优化及其在1.55μm DFB激光器制作中的应用

采用特别设计的InGaAsP/InP多量子阱结构(MQW),研究了Cl2/H2电感耦合等离子体(ICP)刻蚀损伤,优化了低损伤ICP刻蚀的关键工艺参数,得到了一种低损伤、形貌良好的Bragg光栅的制作方法。结合优化的InP材料金属有机物化学气相沉积(MOCVD)外延生长工艺,制作出1.55μm分布反馈(DFB)激光器,端面镀膜前其阈值电流和斜率效率分别为15mA和0.3mW/mA,边模抑制比大于45dB。寿命加速老化实验结果显示,该器件40℃的中值寿命超过2×106h,表明了本文ICP光栅刻蚀工艺的可靠性。     

InSb的电感耦合等离子体刻蚀技术研究

随着InSb红外焦平面探测器的发展,焦平面阵列规模越来越大,像元面积越来越小.湿法刻蚀因其各向同性的特点,导致像元钻蚀严重,越来越难满足大规格InSb焦平面器件的要求.研究了以Ar/CH4/H2作为刻蚀气体,利用电感耦合等离子体(ICP)刻蚀大规格InSb晶片的初步研究结果,研究不同RF功率、腔体压力和Ar的含量对刻蚀速率、表面形貌的影响及InSb表面残留聚合物的去除方法.     

利用Ni纳米岛模板制备半极性晶面GaN纳米柱

报道了在GaN表面以Ni纳米岛结构作为模板,利用电感耦合等离子(ICP)刻蚀制备GaN纳米柱的研究结果。原子力显微镜(AFM)测试结果表明,金属Ni薄膜在快速热退火(RTA)作用下形成了平均直径和高度大约分别为325 nm和70 nm的纳米岛状结构。通过电子扫描显微镜(SEM)照片看出,以GaN表面所形成的Ni纳米岛作为模板图形,通过控制ICP刻蚀时间,在一定的刻蚀时间内(2 min)获得有序的并拥有半极性晶面的GaN纳米柱阵列。这种新颖的半极性GaN纳米柱作为氮化物量子阱或者超晶格结构的生长模板,可以有效减小甚至消除极化效应,提高光电子器件的效率和性能。     

GaN功率MMIC背面通孔工艺优化及可靠性分析

介绍了改进GaN功率MMIC背面通孔工艺的相关方法,并对通孔进行了可靠性方面的测试与分析。通过优化机械研磨的方法,减薄圆片至75μm左右,保持片内不均匀性在4%以内;利用ICP对基于SiC衬底的GaN功率MMIC进行了背面通孔工艺的优化,减少了孔底的柱状生成物。随后的可靠性测试测得圆片通孔的平均电阻值为6.3 mΩ,平均电感值为17.2 nH;对通孔样品在0.4 A工作电流175°C节温下进行了工作寿命试验,200 h后通孔特性无明显退化。     

Inductively coupled plasma etching for large format HgCdTe focal plane array fabrication

Inductively coupled plasma (ICP) using hydrogen-based gas chemistry has been developed to meet requirements for deep HgCdTe mesa etching and shallow CdTe passivation etching in large format HgCdTe infrared focal plane array (FPA) fabrication. Large format 2048×2048, 20-μm unit-cell short wavelength infrared (SWIR) and 2560×512, 25-μm unit-cell midwavelength infrared (MWIR) double-layer heterojunction (DLHJ) p-on-n HgCdTe FPAs fabricated using ICP processing exhibit >99% pixel operability. The HgCdTe FPAs are grown by molecular beam epitaxy (MBE) on Si substrates with suitable buffer layers. Midwavelength infrared detectors fabricated from 4-in. MBE-grown HgCdTe/Si substrates using ICP for mesa delineation and CdTe passivation etching demonstrate measured spectral characteristics, RoA product, and quantum efficiency comparable to detectors fabricated using wet chemical processes. Mechanical samples prepared to examine physical characteristics of ICP reveal plasma with high energy and low ion angle distribution, which is necessary for fine definition, high-aspect ratio mesa etching with accurate replication of photolithographic mask dimensions.     

Cl2/Ar/BCl3ICP刻蚀AlGaN的研究

感应耦合等离子体（ICP）刻蚀在AlGaN基紫外探测器台面制作中起着重要作用。在对比了ICP与RIE，ECR等干法刻蚀技术优缺点的基础上，采用Ni作为掩膜，Cl2/Ar/BCl3作为刻蚀气体，对金属有机化学气相淀积生长的n-Al0.45Ga0.55N进行了ICP刻蚀研究。刻蚀速率随着ICP直流偏压的增加而增加，刻蚀速率随着ICP功率的增加先增加较快后增加缓慢。最后结合刻蚀表面的扫描电镜（SEM）分析和俄歇电子能谱（AES）深度分析对刻蚀结果进行了讨论。分析表明，在满足刻蚀表面形貌的同时，较低的直流偏压下刻蚀速率较慢，但损伤较小，这对于制备高性能的紫外探测器是有利的。     

碲镉汞深微台面列阵干法隔离的轮廓研究

文章报道了碲镉汞（HgCdTe）深微台面列阵干法隔离的轮廓研究的初步结果。采用诱导耦合等离子体（ICP）增强反应离子刻蚀（RIE）技术获得的HgCdTe深微台面列阵,在金刚刀解理后,通过扫描电子显微镜（SEM）观察了其干法刻蚀图形的剖面轮廓。进一步研究了刻蚀时间和刻蚀槽开口宽度对刻蚀图形轮廓的影响,获得了一些有助干深微台面芯片工艺设计的实验结果。     

GaN/SiO_2刻蚀选择比的研究

在干法刻蚀GaN时使用SiO2作为掩蔽物,为了在较快的GaN刻蚀速率下获得良好的GaN/SiO2刻蚀选择比,使用电感耦合等离子刻蚀机(ICP),运用Cl2和Ar作为刻蚀气体,改变ICP功率、直流自偏压、气体总流量、气体组分等工艺条件,并讨论了这些因素对GaN/SiO2刻蚀选择比以及对GaN刻蚀速率的影响。实验结果获得了GaN在刻蚀速率为165nm/min时的GaN/SiO2选择比为8∶1。设备验收时GaN刻蚀速率为70nm/min,GaN/SiO2选择比为3.5∶1,可以应用于实际生产。     

Morphology of Inductively Coupled Plasma Processed HgCdTe Surfaces

Inductively coupled plasma (ICP) processing has become the industrial processing standard for HgCdTe and its related II–VI compounds. In this study ICP processes were developed that allow several microns of HgCdTe to be plasma etched while maintaining a low root-mean-square (RMS) roughness, and even improving the surface roughness in the case of HgCdTe-on-Si. These ICP processes are superior to older electron cyclotron resonance (ECR) plasma etches. The resulting ICP plasma processed surfaces are oxygen and carbon free, have a good reflection high-energy electron diffraction (RHEED) pattern, and have only a small amount of mercury depletion, x = 0.22 to 0.47 (where x is the ratio of Cd to␣Hg), in the first 25 ? to 30 ? of the HgCdTe. Nanofeatures of the as-grown HgCdTe are retained during the process and are believed to be indicative of the fundamental defect mechanisms in the different HgCdTe etched surfaces. Results from these experiments strongly suggest that ICP plasma processes can be used to delineate pixels, etch vias, clean surfaces, and even produce epi-ready surfaces that would allow HgCdTe to become much more manufacturable, and perhaps allow the replacement of wet processing in HgCdTe.