超高相对分子质量聚乙烯注射成型技术

分析了超高相对分子质量聚乙烯(PE-UHMW)的流变性能和独特的口模流动特性以及PE-UHMW注射成型所存在的难点,据此研制出PE-UHMW专用注塑机(螺杆直径45 mm,长径比20),介绍了该机的性能和特点。初步讨论了PE-UHMW注射成型的配方及工艺参数如成型温度、注射压力和注射速度等对注射成型制品表观质量的影响。采用该机,以一模双腔模具成功地制得不同相对分子质量(相对分子质量从2．5×106到4×106以上)的试样, 其力学性能测试结果优良;同时还探讨了PE-UHMW注射成型制品的应用和市场前景。     

Biocomposites Made from Short Abaca Fiber and Biodegradable Polyesters

Natural fiber‐reinforced biodegradable polyester composites were prepared from biodegradable polyesters and surface‐untreated or ‐treated abaca fibers (length ca. 5 mm) by melt mixing and subsequent injection molding. Poly(butylene succinate)(PBS), polyestercarbonate (PEC)/poly(lactic acid)(PLA) blend, and PLA were used as biodegradable polyesters. Esterifications using acetic anhydride and butyric anhydride, alkali treatment, and cyanoethylation were performed as surface treatments on the fiber. The flexural moduli of all the fiber‐reinforced composites increased with fiber content. The effect of the surface treatment on the flexural modulus of the fiber‐reinforced composites was not so pronounced. The flexural strength of PBS composites increased with fiber content, and esterification of the fiber by butyric anhydride gave the best result. For the PEC/PLA composites, flexural strength increased slightly with increased fiber content (0–20 wt.‐%) in the case of using untreated fiber, while it increased considerably in the case of using the fiber esterified by butyric anhydride. For the PLA composite, flexural strength did not increase with the fiber reinforcement. The result of soil‐burial tests showed that the composites using untreated fiber have a higher weight loss than both the neat resin and the composites made using acetylated fiber.

Flexural modulus of PBS composites as a function of fiber content.     

聚四氟乙烯的加工成型技术

综述聚四氟乙烯（PTFE）的性能特点，以及不同品种PTFE（悬浮聚合PTFE、乳液聚合PTFE和PTFE分散乳液）成型制品所适用的成型工艺。介绍PTFE的模压成型，等压成型，挤压成型，流延成型，热真空成型、热压成型、热吹塑成型及缠绕成型等技术。     

不饱和聚酯片状模塑料力学性能的研究

研究了玻纤布、短切玻纤及碳酸钙对不饱和聚酯片状模塑料力学性能的影响,实验发现:玻纤布增强不饱和聚酯片状模塑料的力学性能比短切玻纤好,随着玻纤含量的增加,不饱和聚酯片状模塑料的拉伸强度先增加,达到一极大值之后减少。碳酸钙填充不饱和聚酯片状模塑料,随着碳酸钙含量的增加,不饱和聚酯片状模塑料的拉伸强度明显降低,弯曲强度增加。     

PE-UHMW挤出中空吹塑设备与工艺的研究

改型设计了改性超高相对分子质量聚乙烯的挤出中空吹塑设备，设计采用了专用的挤出螺杆、机筒、模头和模具，并研究改进了吹塑工艺及生产方法，从而克服了超高相对分子质量聚乙烯的加工难点，得到了合格的吹塑制品。     

塑料注射成型新技术——微孔发泡技术的应用

主要介绍微孔发泡技术的工艺过程、应用特性及加工条件、气体条件对微孔发泡过程的影响     

塑料注射成型新工艺

简要介绍了气体（水）辅助注射、模具滑动注射、熔芯注射、受控低压注射、注射－压缩、剪切控制取向注射、推－拉注射、层状注射、微孔发泡注射等注塑料工艺的原理，特点及应用前景，说明塑料注射成型工艺的发展趋势主要以节能，节约原材料，提高成型效率，改进制品性能，提高其附加值为前提。     

精密注塑件的生产稳定性探讨

针对精密注塑件的生产,介绍了设计,成型精密注塑件的基本要求,探讨了原材料,注塑机,电压,环境温湿度及模具积垢等因素对生产精密注塑件稳定性的影响,研究了评估工艺参数敏感性的试验方法和获得稳定工艺的手段;说明了统计过程控制（SPC）的基本原理,以及如何利用控制图和工序能力指数CP,CPK来评估,预测工序能力,确保工序确定性。     

Effect of crystallization and interface formation mechanism on mechanical properties of film‐insert injection‐molded poly(propylene) (PP) film/PP substrate

A previous study has shown that the adhesion between the film and substrate of film‐insert injection‐molded poly(propylene) (PP) film/PP substrate was evident with the increases in barrel temperature and injection holding pressure. In this second part of the research work, the crystallinity at the interfacial region (i.e., region between the film and the injected substrate) was extensively studied using FTIR imaging, polarized light microscopy, and DSC in an attempt to determine the level of influence that crystallinity has on the interface and bulk mechanical properties. Consequently, a more thorough and clearer picture of the influence of the inserted film on the interfacial crystallinity and subsequently the substrate mechanical properties, such as peel strength and impact strength, has been revealed. The initial proposition that crystallinity could enhance film–substrate interfacial bonding has been confirmed, judging from the higher peel strength with increasing crystallinity at the interfacial region. Nevertheless, the change in crystallinity was not only confined to the interfacial region. With the film acting as heat‐transfer inhibitor between the injected resin and the mold wall, the total crystal structure of the substrate was substantially altered, which subsequently affected the bulk mechanical properties. The lower impact strength of film‐insert injection‐molded samples compared to that of samples without film inserts provided evidence of how the film could impart inferior properties to the substrate. The difference in cooling rate between the substrate and film might also cause other defects such as warpage and/or residual stress build‐up within the product. © 2005 Wiley Periodicals, Inc. J Appl Polym Sci 98: 294–301, 2005     

流变参数对顺序共注成型芯层熔体最大填充量的影响

基于Hele-Shaw模型，采用有限元数值模拟技术，系统研究了壳层熔体流变指数和零切黏度对顺序共注成型芯层熔体最大填充量的影响规律，并基于流变学理论揭示了其影响机理，最终提出了顺序共注成型芯层熔体最大填充量与壳层熔体流变指数和零切黏度经验关系方程。