N-甲基乙酰氧基乙酰苯胺的液谱分析

本文研究了高效液相色谱测定N－甲基乙酰氧基乙酰苯胺的方法。采用Hypersil C18柱，以甲醇：水＝60：40（V／V）为流动相。该方法的变异系数为0．43％，回收率为98．9％－100．6％。     

Using ontology-based text classification to assist Job Hazard Analysis

The dangers of the construction industry due to the risk of fatal hazards, such as falling from extreme heights, being struck by heavy equipment or materials, and the possibility of electrocution, are well known. The concept of Job Hazard Analysis is commonly used to mitigate and control these occupational hazards. This technique analyzes the major tasks in a construction activity, identifies all potential task-related hazards, and suggests safe approaches to reduce or avoid each of these hazards. In this paper, the authors explore the possibility of leveraging existing construction safety resources to assist JHA, aiming to reduce the level of human effort required. Specifically, the authors apply ontology-based text classification (TC) to match safe approaches identified in existing resources with unsafe scenarios. These safe approaches can serve as initial references and enrich the solution space when performing JHA. Various document modification strategies are applied to existing resources in order to achieve superior TC effectiveness. The end result of this research is a construction safety domain ontology and its underlying knowledge base. A user scenario is also discussed to demonstrate how the ontology supports JHA in practice.     

乙烯装置长周期运行安全风险分析与对策

分析了中国石化茂名石化公司化工事业部乙烯装置长周期运行的安全风险,讨论了风险控制措施。结果表明:乙烯装置连续运行6年,其安全风险属于可容许风险。     

Modified Indigo Method For Gaseous And Aqueous Ozone Analyses

The indigo method developed by Bader and Hoigné for aqueous ozone analysis was modified to allow for both gaseous and aqueous ozone determination. Gas or water samples were extracted with a gas-tight syringe containing a known volume of indigo reagent. The modified procedure provided a more consistent basis for gaseous and aqueous ozone determination allowing for more accurate ozone mass balance calculations. Direct gaseous ozone UV absorbance with molar absorptivity of 3,000 M^?1cm^?1 at 258 nm was used as primary standard to determine the molar absorptivity of the indigo reagent. The molar absorptivity of indigo reagent, assuming a 1:1 stoichiometric ratio for the reaction between indigo and ozone, was determined to be 23,150 ± 80 M^?1cm^?1, or approximately 16 percent higher than that of 20,000 M^?1cm^?1 suggested by Bader and Hoigné. An independently calibrated membrane-electrode ozone monitor showed good correlation with indigo method results using the molar absorptivity value determined in this study. The apparent molar absorptivity of aqueous ozone at the wavelength of 258 nm measured by the modified indigo method increased from 2,400 to 3,600 M^?1cm^?1 in the investigated ozone concentration range of 0.4 to 11.0 mg/L. This variation might have been caused by the inherent interference of unidentified ozone byproducts, which presence was supported with scanning spectra in the wavelength range of 200 to 300 nm.     

3-溴-4-氟苯甲醛的气相色谱分析方法

采用气相色谱法,氢火焰离子化检测器,选用3%OV-17填充柱,正十三烷为内标,气化室和检测器温度为180℃,柱温120℃,对3溴4氟苯甲醛进行定量测定。该方法简单、快速、准确、适用,标准偏差0.26%,变异系数0.27%,平均回收率100.1%。     

高效液相色谱法在农药残留分析中的应用

介绍了高效液相色谱法在农药残留分析中的应用,列举了一些杀虫剂、除草剂、杀菌剂的分析方法,指出了高效液相色谱法在农药残留分析中发展方向。     

基于差异半监督学习的相关理论分析

基于差异的半监督学习属于半监督学习和集成学习的结合,是近年来机器学习领域的研究热点.但相关的理论研究较缺乏,且都未考虑存在分布噪声的情况.文中首先针对基于差异的半监督学习的特点,定义一种分类噪声和分布噪声的混合噪声(HCAD).其次给出算法在HCAD噪声下的可能近似正确(PAC)理论分析及其应用实例.最后基于投票边缘函数,推导出在HCAD噪声下多分类器系统的泛化误差上界,并给出相关证明.文中开展的理论研究可用于设计基于差异的半监督学习算法及评估算法的泛化能力,具有广阔的应用前景.     

2D12型往复式压缩机气阀故障诊断的时频分析方法

分析了 2D12型往复式压缩机气阀的工作过程 ,针对气阀工作特点提取吸气阀与排气阀均关闭时刻的压缩阶段的局域声音信号 ,应用广义双线性时频法诊断气阀故障 ,给出了正常气阀和故障气阀的时频分析图     

—Review Paper—Current State-Of-The-Art Measurements Of Ozone In The Gas Phase And In Solution

This paper is a critical review and summary of the analytical procedures currently used by operating water utilities to control ozone treatment processes, considering disinfection as well as the many oxidative applications of ozone in water treatment applications. The role of common interferences in the various methods is described.

In operating U S., Canadian, European, and Japanese water treatment plants currently employing ozone as a primary disinfectant, ozone nearly always is followed by the addition of small quantities of chlorine, chlorine dioxide, or chloramine to provide the residual in the distribution system and to act as a secondary disinfectant. Clearly, the analytical procedures used must distinguish between the various species. This review critically presents these various factors and their implication with respect to “true values” of ozone determined under widely varying conditions.     

Internal fracture of notched epoxy resins

The brittle fracture of round-notched epoxy resin bars subjected to plane strain bending has been studied at varying strain rates. Observations of fracture processes and surface morphologies revealed that the internal crack was nucleated at the plastic-elastic boundary when the plastic deformation zone at the notch root reached a certain size. A slip-line field theory allows calculation of the stress components at the plastic-elastic boundary from a knowledge of the location of the internal crack. An analysis of the data concluded that the triaxial stress level ahead of the plastic zone was raised by plastic constraints to an ideal fracture stress which is considerably larger than that of glassy thermoplastics.