Single-Atom Metal Sites Anchored Hydrogen-Bonded Organic Frameworks for Superior “Two-In-One” Photocatalytic Reaction

Photoredox catalysis is a green solution for organics transformation and CO₂ conversion into valuable fuels, meeting the challenges of sustainable energy and environmental concerns. However, the regulation of single-atomic active sites in organic framework not only influences the photoredox performance, but also limits the understanding of the relationship for photocatalytic selective organic conversion with CO₂ valorization into one reaction system. As a prototype, different single-atomic metal (M) sites (M²⁺ = Fe²⁺, Co²⁺, Ni²⁺, Cu²⁺, and Zn²⁺) in hydrogen-bonded organic frameworks (M-HOF) backbone with bridging structure of metal-nitrogen are constructed by a typical “two-in-one” strategy for superior photocatalytic C N coupling reactions integrated with CO₂ valorization. Remarkably, Zn-HOF achieves 100% conversion of benzylamine oxidative coupling reactions, 91% selectivity of N-benzylidenebenzylamine and CO₂ conversion in one photoredox cycle. From X-ray absorption fine structure analysis and density functional theory calculations, the superior photocatalytic performance is attributed to synergic effect of atomically dispersed metal sites and HOF host, decreasing the reaction energy barriers, enhancing CO₂ adsorption and forming benzylcarbamic acid intermediate to promote the redox recycle. This work not only affords the rational design strategy of single-atom active sites in functional HOF, but also facilitates the fundamental insights upon the mechanism of versatile photoredox coupling reaction systems.     

考虑电网阻抗耦合的模块化多电平换流器交直流侧阻抗通用计算方法

以模块化多电平换流器(modular multilevel converter,MMC)为技术路线的柔性直流输电技术在风电接入、电网异步互联等领域迅速发展。MMC的阻抗建模是分析柔性直流输电系统振荡起源的重要依据。文中分析MMC在交、直流侧激励下的谐波传递机制,建立一种适用于交、直流侧阻抗计算的通用方法。对一次系统频域建模关联了MMC所连接的交、直流侧网络阻抗,并考虑包含解耦双同步参考坐标系锁相环及负序内环控制在内的全部控制模块。通过求解线性方程组对MMC阻抗进行计算,并在PSCAD/EMTDC环境中对双端背靠背MMC系统在多种工况下1～5kHz频段内进行扫频,验证该方法的准确性,并详细分析网络阻抗耦合、控制链路延时、功率等级、负序内环和外环控制等因素对MMC阻抗的影响。     

Plasmon enhancement for Vernier coupled single-mode lasing from ZnO/Pt hybrid microcavities

It is essential to develop a single mode operation and improve the performance of lasing in order to ensure practical applicability of microlasers and nanolasers.In this paper,two hexagonal microteeth with varied nanoscaled air-gaps of a ZnO microcomb are used to construct coupled whispering-gallery cavities.This is done to achieve a stable single mode lasing based on Vernier effect without requiring any complicated or sophisticated manipulation to achieve positioning with nanoscale precision.Optical gain and the corresponding ultraviolet lasing performance were improved greatly through coupling with localized surface plasmons of Pt nanoparticles.The ZnO/Pt hybrid microcavities achieved a seven-fold enhancement of intensity of single mode lasing with higher sidemode suppression ratio and lower threshold.The mechanism that led to this enhancement has been described in detail.     

氧化镧/聚丙烯防X射线复合纤维的制备及性能表征

先采用熔融纺丝方法制备了不同氧化镧含量的氧化镧/聚丙烯复合纤维,然后采用对二甲苯在相同处理时间(1 h)不同温度(105~109℃)下溶解复合纤维中的部分聚丙烯基体以提高纤维中氧化镧含量,并对处理过后的纤维进行扫描电镜、X射线屏蔽性能等测试。此外,采用硅烷偶联剂改性氧化镧,通过熔融纺丝法制备了表面活性氧化镧/聚丙烯复合纤维,并对其作了差示扫描量热分析、扫描电镜、力学测试等性能表征。实验结果表明,随未改性氧化镧添加量增加,纤维力学性能下降,玻璃化转变温度向低温方向移动,纤维热稳定提高;有机改性可改善氧化镧在聚丙烯中的分散,提高纤维的力学性能,纤维玻璃化转变温度较纯聚丙烯纤维升高;用对二甲苯在107℃处理1h所获取的复合纤维中氧化镧含量最高,X射线屏蔽性能最优。     

(K0.45Na0.55)0.98Li0.02Nb0.77Ta0.18Sb0.05O3-Co0.85Cu0.15Fe2O4复合陶瓷的磁电性能研究

以压电体(K0.45Na0.55)0.98Li0.02Nb0.77Ta0.18Sb0.05O3和压磁体Co0.85Cu0.15Fe2O4为原料,通过传统的固相反应法制备了(1-x)[(K0.45Na0.55)0.98Li0.02Nb0.77Ta0.18Sb0.05O3]-xCo0.85Cu0.15Fe2O4多铁性复合陶瓷,并使用X射线衍射仪、扫描电子显微镜、压电测试仪、铁电测试仪和磁电耦合测试仪对物相、显微结构、压电、铁电、磁电耦合性能进行了分析。结果表明,复合陶瓷的相结构保持为(K0.45Na0.55)0.98Li0.02Nb0.77Ta0.18Sb0.05O3和Co0.85Cu0.15Fe2O4两种物相,但两者之间发生了轻微的化学反应。随着Co0.85Cu0.15Fe2O4压磁相含量的增加,复合陶瓷的压电系数从56pC/N减小到21pC/N,剩余极化强度略有降低。在压磁相含量为0.2时可获得4.3mV·cm-1·Oe-1的最佳磁电耦合系数。     

2D-C/SiC复合材料偏轴拉伸力学行为研究

通过对2D-C/SiC复合材料试件进行不同偏轴角度的拉伸实验,研究了偏轴角度对材料拉伸力学特性的影响。通过应变片分别测得了材料加载方向和纤维束方向上的应力-应变行为,对比分析了偏轴角度对上述应力-应变行为的影响;并结合试件断口扫描电镜照片,阐释了纤维束方向上拉伸和剪切损伤间的相互耦合效应。实验结果表明,材料的拉伸模量和强度随偏轴角度的增大出现明显下降;材料纤维束方向上的拉伸损伤和剪切损伤具有显著的相互促进作用。最后,以材料0°拉伸和45°拉伸实验数据为基础,建立了材料的偏轴拉伸应力-应变行为预测模型,模型预测结果与实验结果吻合较好。     

硅烷偶联剂表面改性玄武岩纤维增强复合材料研究进展

表面改性是增强玄武岩纤维与基体材料之间结合性能的关键。综述了硅烷偶联剂表面改性以及酸、碱刻蚀,等离子处理辅助协同硅烷偶联剂表面改性玄武岩纤维的研究进展,介绍了硅烷偶联剂表面改性玄武岩纤维在聚合物基复合材料中的应用,并对发展趋势进行了展望,同时分析了硅烷偶联剂表面改性玄武岩纤维当前存在的问题。     

磁悬浮飞轮储能系统机电耦合非线性动力学研究

针对磁悬浮飞轮储能系统的"磁悬浮飞轮-发电机"机电耦合非线性动力学特性进行研究.通过推导磁悬浮飞轮储能系统在偏心条件下的动能、势能、发电机系统的磁场能以及系统的耗散函数,由Lagrange-Maxwell方程建立磁悬浮飞轮系统和两相四极永磁发电机系统的机电耦合动力学方程.采用数值法对0.6MW磁悬浮飞轮储能系统进行了仿真分析,研究结果表明,系统机电耦合非线性方程存在稳定的与转速同频的基频和三倍频周期运动解,且基频振动幅值比三倍频振动幅值大.对于稳定的磁悬浮储能飞轮机电耦合系统,飞轮转速增大,或磁轴承系统刚度减小或阻尼增大,或磁场能(电枢反应磁场能或永磁励磁磁场能)减小,可使系统的非线性振动幅值减小.而增大磁轴承系统的刚度,或减小磁轴承系统的阻尼,或增大系统的磁场能有可能破坏机电耦合系统的稳定性,使飞轮失稳.     

车载无线电台同址干扰测试与分析

同址干扰是车载、舰载、机载无线电通信中面临的一个重要问题,针对同址干扰对复杂通信系统的影响提出了一种有效的测试和分析方法;首先对车载电台的各种天线进行了耦合度测试,从实验和仿真两方面阐述了同址干扰的严重程度,为进一步定量分析同址干扰的影响,构建了有线测试平台;在需求分析基础上,详细介绍了平台的组成,并以短波、超短波电台为对象,通过大量现场实验,深入分析了误码率,同址工作电台的频率间隔和功率之间的相互关系;研究表明,同址干扰的定量分析是设计车载通信系统,合理分配电台工作参数的关键环节。