水浴法加温液氧泵

1　故障现象一次 ,我们用KL -1 5型制氧制氮车开机制氮 ,给一只容积为 40升、最高工作压力为1 4 7MPa的气瓶灌充氮气 ,当气瓶充气压力升高到一定值时不再上升。反复开泵 ,压力基本不变。液氧泵停止时 ,出口压力无明显下降。经分析判断导致气瓶压力升高到一定值时不再上升的原因是由于液氧泵被冻结所致。2　排除方法首先关闭液氧泵。拧开制冷机氢气放气阀 ,使压力下降到 1 0MPa。开大放气阀 ,使二级压力保持在 0 3 5MPa左右。调整正流空气调节阀 ,调节好中部温度。关闭液氮进液氧泵阀和气氮出液氧泵阀。戴棉布手套 ,拆开液氮进口接头、…     

以外供液氮替代膨胀机的深度冷冻循环

介绍空分制氮装置采用膨胀机循环与液氮循环的两种工艺流程及能量平衡 ,示出了两种循环的实例比较。指出外供液氮可以作为冷源替代膨胀机 ,且单耗低、操作更方便 ,设备维护量更小、氮气提取率更高     

Synthesis and Properties of Photoisomerizable Derivatives of Isosorbide and Their Use in Cholesteric Filters

This paper describes the synthesis of photoisomerizable derivatives of isosorbide. These derivatives contain a stilbene or cinnamate moiety and can therefore be used as photoisomerizable chiral compounds in cholesteric liquid‐crystalline mixtures. The reflection wavelength of cholesteric layers made from these mixtures is increased by UV irradiation due to the fact that the Z‐isomers of these derivatives exhibit a lower helical twisting power than the corresponding E‐isomers. The cinnamate derivatives are very suitable for use in cholesteric color filters that find application in liquid‐crystal displays.     

Synthesis and properties of star-like wholly aromatic polyester fibers

Novel star-like wholly aromatic copolyesters having four arms based on a tetraamine star core, p- and m- hydroxybenzoic acids and 6-hydroxy-2-naphthoic acid have been successfully synthesized and spun into fibers for the investigation of the effect of the star-like structure on improving compressive properties of the fiber. The reactivity of the star core was demonstrated using a model compound with FTIR, ¹H and ¹³C NMR spectroscopy. The ¹³C NMR spectrum of the star-like terpolymer having a molar ratio of 10:1 of the monomers to star core showed a characteristic peak at around δ62 ppm which corresponds to a tetra-substituted carbon and thereby demonstrates that the star core was really incorporated into the polymer. The star-like copolyester exhibited a clear stir opalescence and liquid crystalline morphology in the temperature range of 150-280 °C. However, no transition was observed in the DSC thermogram except a clear T_g at 110 °C. The star-like terpolymer fiber, prepared from a polymer with a molar ratio of 500:1 for the monomers to imide core, was spun in the liquid crystalline state at 180 °C. Fiber structure and properties have been studied.     

A new family of ionic liquids based on the 1-alkyl-2-methyl pyrrolinium cation

Five new salts based on 1-alkyl-2-methyl pyrrolinium ion are reported, two involving the iodide ion and three involving the bis(trifluoromethanesulfonyl) amide ion. The iodide salts have melting points around 100 °C, while the amide salts have melting points around room temperature. Two of the amide salts can be easily quenched into the glassy state and exhibit glass transition temperatures around −70 °C. The 2-methyl pyrrolinium cation bears structural similarities to the aromatic imidazolium cations on one hand and the cyclic ammonium cation family based on the pyrrolidinium cation on the other. The properties of the salts reported here are compared within these two related families of salts.     

大功率速调管发射机水冷系统的设计

雷达发射机中大功率器件(如速调管)的强迫液体冷却是一种常用的冷却方式。本文根据某雷达发射机冷却系统的设计.介绍了大功率速调管发射机水冷系统的设计方法。     

液氨储罐保冷改造效果评定

作者结合实例，论述了氨罐保冷改造的设计、选材及施工，给出了改造后两年的测试结果，并对测试结果进行了分析。     

各种状态的液体通过核孔膜的规律

介绍了液体通过核孔膜规律方面取得的新认识，包括：（１）纯净液体通过核孔膜的规律；（２）核孔膜测定液体粘滞系数的各种方法；（３）各种物质溶液浓度的核孔膜测定；（４）液相混合物快速分离和化学分离；（５）流体中固体微粒对核孔膜的堵塞及其公式；（６）用核孔膜滤除液中各各斩规律。     

液体低温热导率的测试

介绍了非稳态法测试液体在低温下（－１００～５０℃）的热导率的测试原理、方法，测试了全氟三乙胺的低温热导率。为了提高测试的重复性，采用了相对比较法，并给出了测试装置及测试结果和误差分析。     

SURFACE TENSION AND BUOYANCY DRIVEN INSTABILITIES IN A LAYER OF LIQUID TIN HEATED FROM BELOW

The linear theory of Pearson (1958) and Nield (1964) is modified here to study liquid tin and include the finite thermal resistances of the bounding layers of boron nitride, copper and air (∼10^-2 torr) in the experiments of Ginde et al. (1989). The magnitude of the ΔT_c across the layer of liquid tin required for the onset of convection depends on the ratios of the thermal conductivities and thicknesses of the supporting layers of boron nitride and copper to those of the tin.

According to our theory surface tension contributes more than buoyancy to the instability observed experimentally. The critical ΔT_c observed required for the onset of convection in the layer of tin, is up to 25% lower than that predicted, which shows the layer is less stable than the theory indicates. Thus the surface of the tin was uncontaminated, or a significantly larger observed critical ΔT_c would be expected.

The boundary condition on the thermal fluctuations at the base of the supporting layer of copper does not appear to be important in these experiments. However, the thermal resistance of the boron nitride would have to be assumed to be unrealistically large to obtain agreement within experimental error with the theory.