掺Er Al2O3光波导薄膜材料的制备及光学特性

介绍了掺ErAl2O3光波导薄膜的四种典型制备方法的研究结果。比较铒的发光环境和发光特性,分析了影响光致发光强度和寿命的条件和因素。不同工艺制得的Er∶Al2O3薄膜,膜内成分、膜的晶相、掺杂浓度等对Er3 的发光特性均有影响。退火对发光特性及材料具有改善作用。     

实时硬件系统中控制方法的研究

由于实时硬件系统的规模和复杂度不断增大，系统结构的模块化设计已成为硬件系统开发的发展趋势。研究了硬件系统中模块控制的方法和特点。结合MPEG2电视编码器中各功能模块的特点，提出了适合该硬件系统的模块控制方案，说明了控制模块的硬件设计思想和软件实现。实践证明，该方案满足系统实时性和可靠性的设计要求。     

草酸钙在硫酸软骨素自组装膜上周期沉淀的研究

利用硫酸软骨素(chondroitin sulfate，CS)在云母基底上通过浇铸法制备的自组装膜为基底，诱导草酸钙在其上的凝集生长。发现当硫酸软骨素的浓度为1．Omg／ml时在该膜体系中可形成规整的周期性草酸钙环状沉淀。这种有序的环状结构可能是耗散结构的一种具体表现形式。利用原子力显微镜(atomic forcemicroscope，AFM)和傅立叶红外光谱仪对这种结构进行了表征，实验结果显示合适浓度下形成的CS膜在一定程度上可以抑制草酸钙的凝集结晶，表明高分子基质与无机离子间强烈的相互作用对无机盐的成核结晶有显著影响，为探讨结石的形成与抑制提供了一定的实验依据。     

Synchronous Full-Scan for Asynchronous Handshake Circuits

Handshake circuits form a special class of asynchronous circuits that has enabled the industrial exploitation of the asynchronous potential such as low power, low electromagnetic emission, and increased cryptographic security. In this paper we present a test solution for handshake circuits that brings synchronous test-quality to asynchronous circuits. We add a synchronous mode of operation to handshake circuits that allows full controllability and observability during test. This technique is demonstrated on some industrial examples and gives over 99% stuck-at fault coverage, using test-pattern generators developed for synchronous circuits. The paper describes how such a full-scan mode can be achieved, including an approach to minimize the number of dummy latches in case latches are used in the data path of the handshake circuit.     

Physico-chemical characterization of hybrid polymers obtained by 2-hydroxyethyl(methacrylate) and alkoxides of zirconium

Hybrid monolithic materials were prepared through polymerisation of 2-hydroxyethyl methacrylate (HEMA) mixed with zirconium alkoxides (Zr(OBuⁿ)₄, Zr(OPrⁿ)₄ and Zr(OEt)₄), modified by acetylacetonate groups. The molar ratio HEMA/Zr varied between 1 and 4. Thermo-Gravimetry coupled with Mass Spectroscopy (TG-MS) analyses, ¹³C MAS NMR and Dynamical Mechanical Thermal Analysys (DMTA) indicated the polymeric chains were interconnected by the inorganic component.The presence of zirconium alkoxides modified substantially the poly-HEMA properties. Glass transition temperature of hybrid materials derived from butoxy and propoxy was found in the range 50-80 °C, depending on the composition. The typical swelling of p-HEMA in the water, was suppressed by the presence of zirconium compounds. After immersion in distilled water, hybrid polymers showed an initial slight weight increase, followed by a small mass loss, which increases proportionally to the length of alkoxyl group (ethoxide(propoxide(butoxide) and reaches a constant value after about 40 days. The hybrids remained always rigid and transparent. Flexural modulus and strength of about 400-900 and 4-8 MPa were measured.     

LARGE EDDY SIMULATION OF VERTICAL JET IMPINGEMENT WITH A FREE SURFACE

1. INTRODUCTION When wastewater is discharged into rivers, lakes or oceans, it usually leads to the formulation of turbulent jet with a free surface. If the ambient water depth is shallow, the jet will impinge on the water surface and the confinement of f…     

CeO2对RuO2／γ-A12O3催化剂湿式氧化降解苯酚性能的影响

采用浸渍法制备了RuO2／γ-A12O3和RuO2／CeO2／γ-A12O3催化剂，并利用XRD、SEM和XPS对催化剂进行了表征，研究了Ce的加入对RuO2／γ-A12O3催化剂表面分散性和催化剂表面元素Ru，O和Ce化学态的影响，同时考察了RuO2／γ-A12O3和RuO2／CeO2／γ-A12O3催化剂湿式氧化降解苯酚的活性，并深入探讨了Ce对RuO2／γ-A12O3催化剂的助催化作用。结果表明：Ce掺杂改性后，使催化剂表面Ru的化学态降低、表面氧空位增加，并且活性组分Ru的分散性增加，从而使RuO2／CeO2／γ-A12O3催化剂的活性提高，因此Ce起到了显著的助催化作用。     

Inhibition effect of carbon dioxide on the oxidation of hydrogen over a platinum foil catalyst

This paper investigates the catalytic ignition of the H₂/O₂/CO₂ mixture on platinum in a stagnation flow at atmospheric pressure experimentally and numerically. We measure the ignition temperatures of the gas mixtures flowing towards resistively heated platinum with various composition ratios and various diluent gases of N₂, Ar and CO₂. Compared with N₂ or Ar, the CO₂ dilution shows higher ignition temperature by about 50 K, even at the same composition ratio. The ignition temperature increase is proportional to the dilution ratio. Through the numerical simulation, it is illustrated that higher ignition temperature is caused by the adsorption of CO₂ and following dissociation on platinum surface, which was to date considered negligible in catalytic combustion.     

凝胶成型法制备加氢催化剂载体的研究与工业化生产

采用凝胶成型法制备加氢催化剂载体，并进行了工业放大试验。通过BET、NH3-TPD、H2-TPR等表征手段及实际的加氢反应性能评价对凝胶成型法制备的载体及加氢催化剂与常规方法进行对比分析，结果表明，采用凝胶成型法所制得的载体及催化剂均具有较高的孔体积和比表面积、较低的堆密度，其机械强度可满足工业要求，总酸量及中强酸酸量得到提升，催化剂活性组分与载体强结合力得到削弱，金属利用率提高，应用性能明显优于传统方法制备的加氢催化剂载体。通过该方法完成了加氢催化剂载体的工业生产，所生产的载体应用于天津院THDS-3加氢精制催化剂取得了良好的工业应用效果。     

Synthesis and luminescence of Sr2CeO4 fine particles

Fine particles of a blue emission phosphor Sr₂CeO₄ have been synthesized using a chemical co-precipitation technique, and the textual and luminescent properties were compared with the one synthesized by the conventional solid-state reaction method. Particle size and distribution of the Sr₂CeO₄ fine powder prepared by the co-precipitation process were smaller and narrower than those obtained by the samples prepared from the conventional one. The emission intensity of the fine particles was equal to that of the larger particles prepared from the solid-state reaction, on the contrary to the general tendency that emission intensity decrease with particle size reduction. Although no Ce³⁺ peaks were observed in EPR measurements, X-ray photoelectron spectra of the samples clearly elucidated the existence of Ce³⁺ only on the surface of Sr₂CeO₄.