全文获取类型
收费全文 | 18643篇 |
免费 | 378篇 |
国内免费 | 380篇 |
专业分类
电工技术 | 177篇 |
技术理论 | 1篇 |
综合类 | 439篇 |
化学工业 | 5574篇 |
金属工艺 | 963篇 |
机械仪表 | 760篇 |
建筑科学 | 465篇 |
矿业工程 | 208篇 |
能源动力 | 1488篇 |
轻工业 | 1207篇 |
水利工程 | 89篇 |
石油天然气 | 815篇 |
武器工业 | 137篇 |
无线电 | 1000篇 |
一般工业技术 | 4148篇 |
冶金工业 | 391篇 |
原子能技术 | 523篇 |
自动化技术 | 1016篇 |
出版年
2024年 | 13篇 |
2023年 | 190篇 |
2022年 | 273篇 |
2021年 | 368篇 |
2020年 | 353篇 |
2019年 | 376篇 |
2018年 | 348篇 |
2017年 | 389篇 |
2016年 | 401篇 |
2015年 | 375篇 |
2014年 | 860篇 |
2013年 | 1024篇 |
2012年 | 874篇 |
2011年 | 1676篇 |
2010年 | 1128篇 |
2009年 | 1263篇 |
2008年 | 1058篇 |
2007年 | 1044篇 |
2006年 | 972篇 |
2005年 | 852篇 |
2004年 | 759篇 |
2003年 | 697篇 |
2002年 | 630篇 |
2001年 | 432篇 |
2000年 | 438篇 |
1999年 | 378篇 |
1998年 | 345篇 |
1997年 | 323篇 |
1996年 | 280篇 |
1995年 | 285篇 |
1994年 | 214篇 |
1993年 | 157篇 |
1992年 | 113篇 |
1991年 | 91篇 |
1990年 | 76篇 |
1989年 | 68篇 |
1988年 | 55篇 |
1987年 | 38篇 |
1986年 | 34篇 |
1985年 | 26篇 |
1984年 | 25篇 |
1983年 | 27篇 |
1982年 | 17篇 |
1981年 | 17篇 |
1980年 | 14篇 |
1979年 | 10篇 |
1978年 | 2篇 |
1977年 | 5篇 |
1975年 | 4篇 |
1959年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 31 毫秒
51.
Gibbs energies of formation of CoF2 and MnF2 have been measured in the temperature range from 700 to 1100 K using Al2O3-dispersed CaF2 solid electrolyte and Ni+NiF2 as the reference electrode. The dispersed solid electrolyte has higher conductivity than pure CaF2 thus permitting accurate measurements at lower temperatures. However, to prevent reaction between Al2O3 in the solid electrolyte and NiF2 (or CoF2) at the electrode, the dispersed solid electrolyte was coated with pure CaF2, thus creating a composite structure. The free energies of formation of CoF2 and MnF2 are (± 1700) J mol−1; {fx37-1} The third law analysis gives the enthalpy of formation of solid CoF2 as ΔH° (298·15 K) = −672·69 (± 0·1) kJ mol−1, which compares with a value of −671·5 (± 4) kJ mol−1 given in Janaf tables. For solid MnF2, ΔH°(298·15 K) = − 854·97 (± 0·13) kJ mol−1, which is significantly different from a value of −803·3 kJ mol−1 given in the compilation by Barinet al. 相似文献
52.
A new supported liquid membrane (SLM) system was prepared for the selective transport of bismuth ions from the aqueous feed into the aqueous permeate phase. The support of the SLM was a thin porous polypropylene or polyvinylidene fluoride membrane impregnated with diisooctyldithiophosphinic acid (Cyanex 301) as mobile carrier in 4‐chloroacetophenon as organic solvent. Cyanex 301 acts as a highly selective carrier for the uphill transport of bismuth ions through the SLM. In the presence of HNO3 as a metal ion acceptor in the strip solution, the transport of bismuth ions into the strip side reached 70 % of the initial feed concentration after 3.5 hours. The selectivity and efficiency of bismuth transport from aqueous solutions containing different mixtures of cations were investigated. In the presence of P2O72– ions as suitable masking agent in the feed solution, the interfering effects of other cations were completely eliminated. The selective transport of bismuth through SLM is superior to liquid‐liquid extraction or through bulk liquid membranes. This is due to the high efficiency. The SLM reduces the solvent requirements, combines extraction and stripping operations in a single process and allows the use of highly selective extractants. The system may be applied to samples containing very low bismuth concentrations. 相似文献
53.
本文评价了塑料闪烁片用作软β核素探测器时的计数效率、β谱、本底谱和康普顿电子谱的特征。文中强调:采用胶合光导剂构成的系统是一种新型探测器(软β核素内部样品塑料闪烁探测器)。本文提出内部样品固体探测器、胶合光导剂和胶合闪烁光导剂的新概念。 相似文献
54.
Nikos Antonopoulos Patrick Linke Antonis Kokossis 《Chemical Engineering Communications》2005,192(10):1258-1271
This article presents a GRID framework for distributed computations in the chemical process industries. We advocate a generic agent-based GRID environment in which chemical processes can be represented, simulated, and optimized as a set of autonomous, collaborative software agents. The framework features numerous advantages in terms of scalability, software reuse, security, and distributed resource discovery and utilization. It is a novel example of how advanced distributed techniques and paradigms can be elegantly applied in the area of chemical engineering to support distributed computations and discovery functions in chemical process engineering. A prototype implementation of the proposed framework for chemical process design is presented to illustrate the concepts. 相似文献
55.
A novel milk-like Cu-thiourea colloid has been synthesized. Nanocrystalline quaternary copper sulfide Cu2FeSnS4 was obtained through the Cu-thiourea colloidal precursor cooperative conversion route at low temperature. The samples were characterized by means of X-ray powder diffraction, transmission electron microscopy, scanning electron microscopy, inductively coupled plasma atomic emission spectroscopy, and X-ray energy dispersive spectroscopy techniques. The reaction details and features were described and discussed. 相似文献
56.
Thin layers of ceria were deposited on the surface of mica platelets in solution. The reaction of such particles with hydrogen sulfide yields a red colored special effect pigment. The ceria layer reacts with H2S to produce a variety of sulfide and oxysulfide phases. The reaction path discovered in situ by time and temperature resolved X-ray diffraction is CeO2→CeS2→C-Ce2S3→Ce10S14O. The reaction itself is extremely variable depending on gas flow, heating rates and decomposition atmospheres. Effects on the thin film are recorded by scanning electron microscopy (SEM) and revealed a destruction of the layer once red Ce10S14O was formed. The product layer then reveals the typical nonwetting behaviour of a liquid on a surface. 相似文献
57.
K Madhusudan Reddy Sunkara V Manorama R.D.K Misra 《Materials Research Bulletin》2004,39(10):1491-1498
A comparative study of gas sensing behavior of nanocrystalline nickel ferrite synthesized by micro-emulsion and hydrothermal method to liquefied petroleum gas (LPG) is presented. Nanocrystalline nickel ferrite synthesized by hydrothermal method indicated higher electrical conductivity and gas sensitivity at low operating temperature compared to nanocrystalline nickel ferrite synthesized by reverse micelle technique. This difference in the gas sensing behavior can be attributed to the presence of more oxygen vacancies (i.e. non-stoichiometry) in the hydrothermally synthesized nickel ferrite. Incorporation of palladium had a catalytic effect and the operating temperature was significantly reduced in both the samples. The higher operating temperature of the reverse micelle nickel ferrite material makes the sensor response speed faster (∼10 s) compared to the hydrothermally synthesized material (∼1 min). 相似文献
58.
The thick film of Zn-Sb-O was prepared by coating the paste of nanoparticles mixture (Sb2O3:ZnO=1:3) on the alumina substrate, followed by sintering at 500-900 °C for 2 h in air. The electrical resistance and gas-sensing properties to benzene, alcohol and acetone of Zn-Sb-O films were found to be dependent on the change of phase structure caused by sintering temperature. 相似文献
59.
We investigated liquid crystallization of liquid crystalline polyester BB-5 during isothermal annealing by digital high-fidelity microscope and light scattering. A liquid crystalline spherical domain having a radius of micrometers appeared by annealing at around 180 °C. The domain grew dendritically in all directions. Neighboring liquid crystalline regions coalesced and then interconnected. The interconnected structure changed to a co-continuous two-phase structure with increasing ordering of the liquid crystalline phase, and the interface between the liquid crystalline phase and the isotropic phase became smoother over time. Liquid crystallization stopped before volume filling the whole space, and the liquid crystalline phase and isotropic phase coexisted. The liquid crystalline region became narrower with an increase in the temperature of the liquid crystallization. Such structural development is different from the liquid-liquid phase separation via spinodal decomposition, and it may be attributed to the segregation of non-liquid crystallizable low molecular weight molecules from the growth front by fractionation of the molecular weight distribution during the liquid crystallization in terms of the instability of the diffusion-controlled interface. 相似文献
60.
Manipulation of molecular orientation alignment in MCTLCPs (main-chain thermotropic liquid crystalline polymers) by pure shear at nano scale has been investigated for the first time using molecular dynamics (MD) simulation. Results indicate that high planar shear induces long-range uniform orientation ordering (liquid crystalline phase) of initially randomly orientated molecules of MCTLCP fluid confined in a nanochannel, which is confirmed by analyzing the orientation order parameter and the snapshots of MCTLCP liquid in a nanochannel under different shear rates. Insights into the origin of the phase transition phenomena are given at molecular level through investigating the thermodynamic density distribution of MCTLCP molecules in the nanochannel, suggesting that the energy shift due to a radical jump of system density affects both the magnitude and the orientation of the molecular ordering. Simulation results also show that there is a critical shear rate for transforming isotropic phase into liquid crystalline phase. The critical shear rate is dependent on the temperature of the MCTLCP system. Findings in this paper may present useful information for processing TLCP molecules at nano scale and the understanding of nanoflow. 相似文献