概率空间中的一个不等式

设｛Ｚ，（Ｗ）｝是定义在概率空间上的独立的随机变量序列，Ｚ（Ｗ）具有方差为期望Ｅ（Ｚｎ）＝０．本文证明了对任意算数序列｛ｂｎ｝及任意的存在充分大的整数Ｎ＞０使当Ｎ＇＞Ｎ″＞Ｎ时．有此不等式在随机级数研究中有重要作用．     

高透明耐冲击聚氯乙烯接枝聚合研究

研究高透明耐冲击聚氯乙烯接枝聚合工艺，讨论了加料顺序、复合分散体系以及采用聚集粒子乳液、并用碱性物质调节其ｐＨ值等对接枝聚合物性能的影响，确定了接枝聚合最佳工艺条件。     

阳离子化多元醇防塌剂的研制

室内研究和现场应用表明,聚乙烯醇类防塌剂表现出较明显的增粘负效应,可引起钻井液粘度的急剧增加,严重影响其推广应用.通过金属盐催化降解和阳离子化反应,研制出了抑制性好且增粘负效应低的阳离子化改性多元醇防塌剂.考察了阳离子化试剂、反应温度、反应时间对取代度、反应效率和产品主要性能的影响,得出了阳离子化多元醇防塌剂最佳制备条件,即：PVA与阳离子化试剂物质的量比为1：1,反应温度为50℃,反应时间为4 h,阳离子度可达0.435.     

苯乙烯与1-(2-叔丁基过氧异丙基)-3-异丙烯基苯共聚行为研究

苯乙烯与1－（2－叔丁基过氧异丙基）－3－异丙烯基苯（D120）能进行自由基共聚合反应，聚合后过氧基团以侧基的形成被保留在共聚物大分子链上，凝胶色谱分析发现，随原料单体中D120比例增加，共聚物的分子量减小，分子量分布变窄，DSC分析发现共聚物中过氧基团的分解温度随D120结构单元含量的增加而下降，但仍高于D120单体过氧基团的分解温度，苯乙烯与D120的竞聚率为：rD120=0.700,rSt=0.714。     

一种基于混沌的随机数发生器设计及其IC实现

在密码学、仿真学以及集成电路测试等许多领域 ,随机数起着重要的作用。在密码学中 ,通常要求所使用的随机数具有不可预测性。基于混沌现象 ,使用开关电容技术 ,用集成电路实现了一种硬件随机数发生器。测试结果表明 ,其产生的序列具有不可预测性 ,可以满足密码学的应用要求。     

Extremes of random fields over arbitrary domains with application to concrete rupture stresses

To find the exact probability distribution of the global maximum or minimum of a random field within a bounded domain is a pending problem even for Gaussian fields. Except for very special examples of fields, recourse must be taken to approximate reasoning or asymptotic considerations to be judged with respect to accuracy by simulations. In this paper, the problem is addressed through a functional equation that leads to the definition of a class of distribution functions that depend solely on process or field characteristics and domain quantities that can be calculated explicitly. This distribution function class is studied for Gaussian processes in earlier works by the author and it has been obtained explicitly for Gaussian fields on rectangular domains in the plane. Simulation studies show that rather good predictions are obtained for sufficiently smooth wide band Gaussian processes and fields. In this paper, the distribution function is obtained in general for Gaussian fields over arbitrary bounded domains with piecewise continuous and differentiable boundaries, and as in earlier works the distribution function is tested against empirical distribution functions obtained by simulation of sample functions of a smooth approximately Gaussian field, herein called a broken line Hino field. For completeness this particular field type is defined in appendix a and appendix b. The paper concludes with a statistical application on data for plain concrete tensile strength.     

结构-波浪-海床耦合系统中大圆筒结构的波压力响应

以沉入式大圆筒结构为对象，通过设计随机波浪水槽实验，测取了在单筒和连续筒两种结构型式、两种沉入深度和两种波谱输入下结构表面的动波压力分布。波面高度以及波压力历程均在领域进行分析。通过计算结构表面沿高程和沿环向的波压力谱及波压力传递函数，将单筒实测结果与基于线性绕射理论的解析解进行了比较，同时也详细对比了两种结构型式下的实测结果。文中汇报了在研究中获得的新发现及进行的相应分析，特别是在结构——波浪——海床动力相互作用下对波压力响应机理以及针对连续筒的研究，可为工程应用提供有价值的参考。     

Copolymerization of bromophenylmaleimide with ethyl or butyl methacrylate

N‐p‐Bromophenylmaleimide (BrPMI) does not polymerize in solution by conventional free radical mechanism. However, it readily polymerized in bulk when mixed with a free radical initiator and heated in a microwave oven for 7–8 min. Copolymerization of ethyl methacrylate or butyl methacrylate with BrPMI was conducted in dioxane. The copolymers were characterized by IR and ¹H NMR spectroscopy and gel permeation chromatography. The monomer reactivity ratios were calculated by a non‐linear least‐square analysis. Thermal analysis indicated a great improvement in thermal stability of the copolymers compared with the methacrylate homopolymers. BrPMI was also polymerized in bulk in the DSC pan, which allowed the calculation of the activation energy of its polymerization. Copyright © 2003 Society of Chemical Industry     

In-chain functionalization by alternating anionic copolymerization of styrene and 1-(4-dimethylaminophenyl)-1-phenylethylene

Anionic copolymerizations of styrene (M₁) with excess 1-(4-dimethyl-aminophenyl)-1-phenylethylene (M₂) were conducted in benzene at 25°C for 24h, using sec-butyllithium as initiator. Narrow molecular weight distribution copolymers with M?;_n = 16.1 × 10³ g/mol (M?_w/M?_n = 1.04) and 38.2 × 10³g/mol (M?_w/M?_n = 1.05), and 24 and 38 moles of M₂ per macromolecule, respectively, were characterized by size exclusion chromatography, ¹H NMR spectroscopy and DSC. The monomer reactivity ratio, r₁ = 5.6, was obtained from the copolymer composition at complete consumption of M₁, assuming that the rate constant k₂₂ =0,i.e. r₂ =0. The polymers exhibited T_g values of 128 and 119°C, respectively, which correspond to an estimated T_g = 217°C for the hypothetical homopolymer of M₂.