浅析聚乙烯装置后部造粒对粒料颜色的影响

分析了气相法生产线性低密度聚乙烯(LLDPE)装置粒料颜色变黄的原因，从工艺条件、造粒设备、添加剂等几方面提出了改进措施。     

Miscibility of oligomeric poly(dimethyl siloxanes) with long-chain unbranched alkanes: 2. Unsymmetrical cloud point curves

Previously obtained cloud point curves for mixtures of oligomeric poly(dimethyl siloxanes) (weight fraction W₁) with oligomeric polyethylenes have been supplemented by the use of samples of higher molecular weight. Initial flat regions at low-medium W₁ as well as a slight shoulder at extremely high W₁ are now considered to be due to crystallization, since the temperatures at which they occur are the melting points of the oligoethylenes. The actual cloud point curves were of an unsymmetrical dome shape, the form of which could not be simulated by using a concentration-independent interaction parameter g in the Flory-Huggins equation. However, spinodals calculated by assuming a quadratic dependence of g on composition were of the same shape as the experimental cloud point curves. The critical compositions calculated on this basis were also close to the experimental ones.     

不同螺杆组合对聚乙烯交联反应挤出的影响

从20世纪60年代到现在,在国外,反应挤出取得了相当巨大的进步,其应用相当广泛。而在国内,对于反应挤出研究得很少,最突出的表现在利用平行同向双螺杆、采用两步法的生产工艺来反应挤出聚乙烯交联料。这主要是由于影响交联质量的因素很多,如配方、生产工艺和反应挤出设备等等,而本文着重讨论挤出设备,通过对现有的挤出设备进行改进,以期得到一组最佳的螺杆组合和生产工艺条件。     

固相法低度氯化聚乙烯耐老化性能的研究

用室温对折断裂试验,研究固相法低度氯化聚乙烯老化性能,当氯含量约为7.4％时,其老化时间发生突跃,老化时间发生突跃时,氯含量与试样的氯化温度和老化温度有关.     

Stochastic defect diffusion model for relaxation effects in crystalline polyethylene

It is suggested that some relaxation processes observed in crystalline polyethylene are consequences of the diffusive motion of a particular defect called a point dislocation or twist dispiration loop along the polyethylene stems in lamellar crystals. The motion of the defect, characterized by a diffusion coefficient and a mobility, is described by solutions of the Smoluchowski diffusion equation with boundary conditions that constrain the defect to move along routes that produce experimentally observable results. The fact that passage of the defect causes both a 180° rotation of the chain and moves an extra CH₂ group in the direction of the chain axis is important to the interpretation of the data according to this model. The diffusion coefficient for a defect is estimated to be around 2 × 10^?9 cm² s^?1 at 70°C. This value is shown to be reasonable both from the viewpoint of detailed computer modelling of defect motion and contemporary ideas about scaling.     

双峰聚乙烯生产工艺及催化剂研究进展

综述了国内外双峰聚乙烯的生产方法、生产工艺及催化剂的研究开发进展，提出了发展我国双峰聚乙烯生产的一些建议。     

氯化低分子聚乙烯的应用研究

本文叙述了氯化聚乙烯的国内外发展概况。研究了低分子聚乙烯的氯化工艺路线与生产方法，测定了熔融本体氯化方法生产的氯化低分子聚乙烯性能。探讨了ＣＬＰＥ在高分子材料加工，纺织上浆等各个方面的应用。     

Adhesion and Hydrolytic Stability of the Interface Between High-Modulus Polyethylene Fibers and Acrylic Resins

The effects of oxyen plasma treatment on the surface chemistry of Spectra 1000® high modulus polyethylene fibers and on the mechanical properties of fiber-reinforced composites of the fibers in a Bis-GMA based acrylic resin have been studied. X-ray photoelectron spectroscopy and diffuse reflectance FTIR spectroscopy have been used to show that the majority of oxygen on the fiber surface exists mostly in the form of ether and/or epoxy linkages, with carbonyl-, carboxylic- and ester-containing compounds accounting for less than 10 percent of the total. While the untreated and plasma-treated fibers have similar chemical compositions, the surfaces of the plasma-treated fibers are more polar and the oxygen is chemically bonded instead of being merely physisorbed. The interfacial shear strength between the fibers and the acrylic resin is increased by a factor of 2.3 by the plasma treatment indicating the presence of a weak boundary layer on the surface of the untreated fibers. The hydrolytic stability of the composite interfaces was investigated for fibers sized with several Bis-GMA-based adhesives. Maximum stability was attained by sizing with Bis-GMA containing a peroxide catalyst or an amine accelerator. The flexural properties of composites utilizing plasma-treated and untreated fibers were compared in three-point bending. The ultimate bending loads for composites using treated fibers were much higher than those for composites with untreated fibers, but only a fraction of that for glass or Kevlar®-reinforced materials.     

利用C++Builder对处理ESCR数据方法的改进

介绍一种利用C＋＋Builder编程工具自动处理聚乙烯环境应力开裂(ESCR)试验数据的方法。此方法利用计算机简化试验数据的处理过程,消除标准试验方法中作图法所引入的人为误差,并可以大幅度缩短试验时间。     

Rheological analysis of vapor‐grown carbon nanofiber‐reinforced polyethylene composites

The melt rheological analysis of high‐density polyethylene reinforced with vapor‐grown carbon nanofibers (VGCNFs) was performed on an oscillatory rheometer. The influence of frequency, temperature, and nanofiber concentration (up to 30 wt %) on the rheological properties of composites was investigated. Specifically, the viscosity increase is accompanied by an increase in the elastic melt properties, represented by the storage modulus G′, which is much higher than the increase in the loss modulus G″. The composites and pure PE exhibit a typical shear thinning behavior as complex viscosity decreases rapidly with the increase of shearing frequency. The shear thinning behavior is much more pronounced for the composites with high fiber concentration. The rheological threshold value for this system was found to be around 10 wt % of VGCNF. The damping factor was reduced significantly by the inclusion of nanofibers into the matrix. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 93: 155–162, 2004