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31.
32.
Immobilization of new Mn(salen) complex over MCM-41 and its activity in asymmetric epoxidation of styrene 总被引:3,自引:0,他引:3
New tetradentate chelates of bis-Schiff bases were synthesized and then these chiral salen ligands were immobilized over mesoporous
MCM-41 by using the ion-exchange method. The efficiency of the chiral catalyst was examined in the asymmetric epoxidation
of styrene. Chiral Mn(salen) complexes immobilized onto mesoporous MCM-41 were stable during the reaction without any leaching
and exhibited relatively high enantioselectivity for epoxidation as compared with homogeneous complexes.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
33.
Griselda A. Eimer Liliana B. Pierella Gustavo A. Monti Oscar A. Anunziata 《Catalysis Letters》2002,78(1-4):65-75
A novel route in the synthesis of Al-MCM-41 and Al-MCM-48, using tetraethoxysilane (TEOS) and sodium aluminate (NaAlO2) as Si and Al source has been obtained. The effect of surfactant nature and the synthesis conditions such as surfactant/Si ratio and hydrothermal treatment time on the formed mesostructure regularity has been studied. Different methods of template removal have also been evaluated. The samples were characterized by X-ray diffraction, nitrogen physisorption, FT-IR, and solid-state MAS NMR spectroscopy. 相似文献
34.
对MCM-41沸石的结构、合成方法、模板剂、催化方面的应用及合成原料进行了综述。 相似文献
35.
A series of Cr incorporated, and Cr and Ti co-incorporated MCM-41 photocatalysts were synthesized by hydrothermal method. X-ray diffraction (XRD), UV–vis diffuse reflectance spectra (UV–vis), Fourier transform infrared spectroscopy (FTIR), X-ray fluorescence analysis (XRF), N2 adsorption–desorption isotherms and Raman spectra were used to investigate the effects of the incorporated elements on the structure of MCM-41. The experimental results for photocatalytic water splitting under visible light irradiation (λ > 430 nm) demonstrated that the photocatalytic activities of Cr-MCM-41 and Cr-Ti-MCM-41 catalysts for hydrogen production decreased with an increase in the amount of Cr incorporated. Compared with the Cr-MCM-41 which had the same amount of incorporated Cr, the Cr-Ti-MCM-41 exhibited much higher hydrogen evolution activities. 相似文献
36.
Light cycle oil (LCO), a by-product of the fluid catalytic cracking (FCC) process in a petroleum refinery, can be used as a blendstock for the production of diesel and jet fuels. Regulatory and operational issues result in need for new and more active catalysts for the deep hydrodesulfurization (HDS) of diesel feedstocks, such as LCO. This paper reports the activity of a mesoporous molecular sieve MCM-41-supported Co-Mo catalyst in comparison to a commercial γ-alumina (Al2O3)-supported Co-Mo catalyst for the desulfurization of a LCO with a sulfur content of 2.19 wt.%. The HDS of dibenzothiophene, 4-methyldibenzothiophene, and 4,6-dimethyldibenzothiophene—polyaromatic sulfur compounds present in LCO—and their relative reactivities in terms of conversion were examined as a function of time on stream in a fixed-bed flow reactor. The MCM-41-supported catalyst demonstrates consistently higher activity for the HDS of the refractory dibenzothiophenic sulfur compounds, particularly 4,6-dimethyldibenzothiophene. The presence of a large concentration of aromatics in LCO appears to inhibit the HDS of the substituted dibenzothiophenes. 相似文献
37.
K. R. Kloetstra H. W. Zandbergen M. A. van Koten H. van Bekkum 《Catalysis Letters》1995,33(1-2):145-156
Thermoporometry, a calorimetric procedure, is applied for measuring the pore size distribution, pore volume and surface area of mesoporous MCM-41 molecular sieves using water as the adsorbate. A series of MCM-41 materials with various pore diameters was synthesized and subjected to the new method. The results are compared with nitrogen physisorption. Both methods are complementary, whereby the former provides also information about the pore shape. MCM-41 materials with pores wider than 50 Å also allow the use of benzene as the adsorbate in thermoporometry. 相似文献
38.
I. V. Kozhevnikov A. Sinnema R. J. J. Jansen K. Pamin H. van Bekkum 《Catalysis Letters》1994,30(1-4):241-252
New solid acid catalysts, consisting of heteropoly acid (HPA) H3PW12O40 (PW) supported on a mesoporous pure-silica molecular sieve MCM-41, have been prepared and characterized by nitrogen physisorption, X-ray diffraction, FT-IR, and31P magic angle spinning NMR. The PW/MCM-41 compositions with PW loadings from 10 to 50 wt% have 30 Å uniformly-sized mesopores. HPA retains the Keggin structure on the MCM-41 surface and forms finely dispersed HPA species. No HPA crystal phase is developed even at HPA loadings as high as 50 wt%. PW/MCM-41 exhibits higher catalytic activity than H2SO4 or bulk PW in liquid-phase alkylation of 4-t-butylphenol (TBP) by isobutene and styrene. In the alkylation of TBP by styrene, PW/MCM-41 shows a size selectivity compared to bulk PW and PW/SiO2, providing higher yields of a 2-(1-phenylethyl)-4-t-butylphenol, at the expense of the more bulky 2,6-bis-(1-phenylethyl)-4-t-butylphenol. The PW/MCM-41 compositions, having strong acid sites and a regular mesoporous system, are promising catalysts for the acid-type conversion and formation of organic compounds of large molecular size. 相似文献
39.
针对井下人员定位系统中身份码发射器的实际情况,选择通信射频芯片cc1000及主控制器ATmega88V作为硬件设计的主体,并提出了一种基于RFID技术的身份码发射器的硬件设计方案.为井下人员定位系统的整体设计提供了一种设计参考. 相似文献
40.
The effect of surface finish and annealing treatment on the oxidation behavior of Ti-48Al-8Cr-2Ag (molar fraction, %) alloy
was investigated at 900 and 1 000 °C, respectively in air. Thermal gravimetric analysis (TGA) was conducted for the characterization
of oxidation kinetics. The microstructures of oxide scales were studied by scanning electron microscopy (SEM) and transmission
election microscopy (TEM) techniques. Unfavorable effect of the annealing treatment on the oxidation behavior of the coating
was also investigated. The results indicate that the oxidation behavior of the alloy is influenced by surface finish and annealing
treatment. The oxidation rate of ground sample is lower than that of the polished alloy at 1 000 °C in air. The former forms
a scale of merely Al2O3, and the latter forms a scale of the mixture of Al2O3 and TiO2. Annealing can improve the formation of TiO2.
Foundation item: Project(2007430028) supported by the Science and Technique Foundation of Henan Educational Committee, China 相似文献