Treatment of High Nitrate-Containing Wastewaters by Sequential Heterotrophic and Autotrophic Denitrification

The treatment performance of sequential heterotrophic and autotrophic denitrification process was evaluated using synthetic wastewaters containing high nitrate concentrations. The effluents from two sequentially connected reactors, for heterotrophic denitrification and sulfur-based autotrophic denitrification, were analyzed for more than 200 days. Experimental results indicated that higher than 95% of the nitrate removal could be achieved with volumetric nitrate loading rates of 2.16, 3.24, and 4.32 kg/m3?d. The maximum denitrification rates, with 1,000 mgN/l influent nitrate concentrations, for the heterotrophic and sulfur-packed autotrophic reactors, were found to be 2.47 and 3.61 kg/m3?d, respectively. A sequential heterotrophic and autotrophic denitrification process is considered a good alternative for the sole autotrophic denitrification process, providing excellent nitrate removal, especially for nitrate-rich wastewaters with very low organic contents.     

Improved Anaerobic Process Efficiency Using Mesophilic and Thermophilic Elutriated Phased Treatment

An innovative anaerobic digestion elutriated phased treatment (ADEPT) has been evaluated at mesophilic (M-ADEPT) (35°C) and thermophilic (T-ADEPT) (55°C) temperatures in which the organic loading rate (OLR) was increased until reactor failure (pH<5.5). Single-stage continuously stirred tank reactors (CSTRs) at both temperatures were also operated as controls (M-CSTR for 35°C and T-CSTR for 55°C). The T-CSTR failed at an OLR of 7.4 g volatile solid (VS)/L?day and the M-CSTR at an OLR of 10 g VS/L?day while the M-ADEPT continued until an OLR of 18 g VS/L?day and the T-ADEPT reached an OLR of 24 g VS/L?day before system failure. The T-CSTR produced the poorest effluent quality as manifested by high propionate concentrations (1,500–2,500 mg/L) while both M-ADEPT and T-ADEPT produced much better quality of effluent with propionate concentrations below 100 mg/L. Thus it appears that the T-ADEPT design may solve effluent quality problems associated with normally high propionate concentrations produced during thermophilic anaerobic digestion. Superior effluent quality, reduced reactor volume requirements, more stable methanogenesis due to the extended solids retention time, and uncoupling of the methanogen wasting from the refractory sludge wasting process resulted in stable and efficient processing at both temperatures for the innovative ADEPT design. Because the higher amounts of volatile fatty acids produced in the acid elutriation phase of the ADEPT system can be a favorable carbon source for biological nutrient removal in wastewater treatment plants, this positive aspect should be considered in future applications of the ADEPT system.     

设施栽培条件下土壤养分及有机质组成变化趋势的研究

以黄泛平原壤质潮土不同年限的设施栽培土壤为研究对象,探讨了设施栽培条件对土壤养分及土壤有机质组成的影响。结果表明,设施栽培土壤碱解氮、速效磷、速效钾、盐分含量均明显高于大田,其含量主要取决于施用化学肥料的种类和数量,随栽培年限的增加而增加;土壤有机质、腐殖酸、胡敏酸含量随种植年限有升高趋势;HA/FA与栽培年限显著相关,表示设施栽培条件下,土壤熟化程度随有机肥料的逐年施用而有所提高,但HA/FA变化幅度不大,这可能与设施栽培形成的高温高湿条件及施用有机肥料中难分解物质的含量有关。     

昆虫病毒在害虫生物防治中的应用

利用昆虫病毒防治害虫是生物防治的一种有效方法。主要针对昆虫病毒的作用机制、后效作用以及重组昆虫病毒和昆虫病毒感染增效物质等方面进行了阐述。     

松花江水环境质量评价模糊可变集合工程方法

为对松花江哈尔滨江段的水质进行科学准确的评价,首先证明该江段水环境质量评价物元分析法关联函数基本公式的错误,然后在工程可变模糊集理论的基础上,提出以相对差异函数表示的模糊可变集合工程方法,对该江段水环境质量进行评价.通过实例,将结果与物元分析法进行比较,验证模型与方法的合理性.同时分析物元分析法对松花江哈尔滨江段的水质评价成果的逻辑错误,指出物元分析法不能用于水环境质量评价等领域.     

十红滩铀矿床有机地球化学特征及与铀成矿作用

十红滩铀矿床属层间氧化带砂岩型铀矿床,赋存于中侏罗统西山窑组含煤碎屑岩中。容矿层岩石中富含有机质,有机碳、可溶有机物、酸解吸附烃在不同地球化学分带的岩石中含量大小不同,尤以氧化还原过渡带含量最高。矿石有机质母质类型为腐殖型,处于未成熟演化阶段,酸解吸附烃为煤成气型。统计计算表明:容矿层中铀和可溶有机物、酸解吸附烃含量之间具明显的相关关系。分析了有机质在砂岩型铀矿床形成过程中的作用,认为容矿层中有机质在含氧环境下分解的产物利于铀在水中的溶解和迁移,而在缺氧条件下分解的产物,构成铀沉淀的还原和吸附地球化学障,在铀的成矿过程中发挥重要的作用。     

基于最优组合赋权的地下矿山岩体质量可拓评价模型

岩体质量分级辩识是矿山工程设计、施工与支护的基础,在岩体工程应用中具有重要的意义。应用可拓学理论,以司家营铁矿超大规模地下采场的岩体工程为例,选取岩石单轴抗压强度、围岩质量指标、结构面摩擦系数、节理间距、地下水状态和完整性系数等评价指标,建立矿山岩体质量评价物元模型。基于最优组合赋权理论,提出了将层次分析法和熵值法获得的权值进行最优组合的指标权重系数的确定方法。研究结果表明：（1）计算获得了待评价岩体的工程质量特征值,实现了岩体工程分类,客观反映岩体与相邻岩体等级间的差值,为矿山岩体工程提供基础的设计参数;（2）基于最优组合赋权的权重系数,可以实现多种权重值的组合赋权,降低不同赋权间的误差,提高了质量评价的准确性;（3）评价结果与工程地质RMR法、层次分析法和熵权法评价结果一致性高,说明评价结果可靠;（4）基于离差平方和最大,使得评价结果之间的离散性高,更有利于决策。     

EES在有机朗肯循环系统热力特性仿真研究中的应用

有机朗肯循环（OrganicRankineCycle,ORC）是在传统朗肯循环中采用有机工质（~IRl13,R123等）代替水推动膨胀机做功的循环,本文根据集总参数法和能量守恒定律建立有机朗肯循环系统的数学模型,运用软件工程方程求解器（EngineeringEquationSolver,EES）进行仿真研究,得到不同工况下有机朗肯循环系统热力特性的变化规律。研究结果表明,提高系统蒸发压力、降低系统冷凝压力以及选择效率尽可能高的膨胀机,可以提高有机朗肯系统循环热效率。仿真计算结果与实验数据二者吻合较好,表明所发展的数学模型可以满足有机朗肯循环热力系统仿真的要求。     

用气相色谱法对水中有机磷农药的测定

本文采用固相萃取法预处理,然后用带有火焰光度检测器(FPD)的气相色谱仪测定有机磷农药。结果表明,该法具有简单、快速、准确的持点。     

A π-extended tetrathiafulvene derivative: Synthesis and photoluminescence properties

Solid-state emissive organic materials have received increasing attention due to their prospective applications in large-area. Here, a novel π-extended tetrathiafulvene derivative DPD with donor-π-donor structure has been newly developed to produce the prominent characteristic of aggregation-induced enhanced emission (AIEE) that exhibits higher fluorescence quantum efficiency in solid film compare to its solutions. The AIEE mechanism of DPD was studied in detail through photophysical investigations and can be dominant attributed to the formed excimer state of DPD and J-aggregates in solid state.