粗磨矿在金炭浸工艺中的应用

炭浸提金工艺通常对磨矿细度要求较高（-200目90％），在夏家店金矿设计生产中，根据矿石性质，大胆采用了粗磨矿下炭浸提金，经实践证明完全达到了设计指标，大大降低了投资及生产成本。     

铀矿加压碱浸的研究与应用

本文阐述了加压碱浸过程中影响铀浸出率的主要因素,系统地介绍了792矿小型试验、扩大试验的研究情况和所提供的工艺流程及工业生产结果。     

新疆某铀矿淡化少试剂地浸关键技术和工艺参数现场试验研究

为解决新疆某铀矿床地浸生产中的因地下水矿化度高而容易产生化学堵塞问题,在室内研究基础上,进行淡化少试剂现场浸出试验,得出该工艺的关键技术和最佳参数。结果表明,淡化技术、氧化技术、酸化技术、加助溶剂技术是本工艺的关键技术。控制地下水矿化度小于4g/L、溶解氧浓度250~350mg/L、溶液pH值小于6.9、HCO-3浓度为600mg/L左右为淡化少试剂工艺最佳技术参数。该工艺技术将会对同类铀矿地浸具有参考意义。     

Acid leaching and rheological behaviour of a siliceous goethitic nickel laterite ore: Influence of particle size and temperature

This study investigates the isothermal, batch, H₂SO₄ acid leaching behaviour of siliceous goethitic (SG) nickel (Ni) laterite ore and its links to pulp rheology. Specifically, the effect of feed ore particle size (−0.2 vs −2.0 mm), leaching temperature (70 vs 95 °C) and pulp rheology on Ni and pay metal, cobalt (Co) extraction kinetics and yield was studied for 4 h on 40 wt.% solid dispersions at pH 1. The leaching behaviour was distinctly incongruent, reflecting the disproportionate proliferation of major gangue mineral’s constituent elements (e.g., Fe, Al, Mg, Na, Si) alongside Ni and Co in the pregnant leach solution. At 70 °C, Ni/Co extraction rates were notably lower (<20%) in contrast with 95 °C where a significant increase in Ni/Co extraction to 78/77% and 74/77%, respectively, for the −0.2 and −2.0 mm feeds occurred. The slurries displayed a non-Newtonian, shear thinning Bingham plastic rheological behaviour of which the viscosity and shear yield stress increased markedly in the course of 4 h leaching. The pulp viscosity and shear yield stress were greater at lower temperature than at higher temperature and they were also greater in slurries with finer than coarser feed particles. The dynamic pulp rheology, however, had no marked effect on the overall Ni/Co extraction rates. Whilst the feed ore particle size had no remarkable impact on overall Ni/Co extraction, it led to noticeably higher acid consumption and enhanced slurry rheology in the finer sized ore. The mechanism of leaching the SG ore followed a two-stage, first order chemical reaction-controlled shrinking core model, the kinetics of which gave higher rate constants and lower activation energies for the release of Ni, Co, Fe and Mg in the first stage. A faster leaching process involving more reactive minerals during the first 30 min is envisaged to be followed by leaching of the more refractory minerals.     

蛇纹石酸浸提镁残渣制备硅酸锂及其性能研究

以蛇纹石酸浸提镁残渣为硅源,碳酸锂为锂源,通过高温固相反应合成了硅酸锂高温固碳材料,探究了煅烧时间、气氛以及物料配比对合成材料高温固碳性能的影响。采用热重-差热综合热分析仪(TG-DTG)研究了蛇纹石酸浸提镁残渣型硅酸锂的CO2吸收性能,并通过扫描电子显微镜(SEM)与X射线衍射仪(XRD)对合成材料的微观形貌与结构特征进行了表征。结果表明:蛇纹石酸浸提镁残渣型硅酸锂具有较好的CO2吸收性能,吸收量可达26.66%;与市售Si O2为硅源相比,蛇纹石酸浸提镁残渣型硅酸锂材料煅烧合成时间缩短,高温固碳性能更优。     

某高结合率土质氧化铜矿石强化浸出试验研究

对云南某黏土质氧化铜矿进行了浸出试验研究,试验结合不同粒级矿石的可浸性能差异,对矿石进行分级强化浸出。+0.074mm添加强化浸出剂ED-1搅拌浸出,-0.074mm加温80℃搅拌浸出。通过搅拌浸出条件试验,确定最佳浸出参数,最佳条件下铜综合浸出率81.93%,吨铜综合酸耗13.86t,铜浸出率较现有常温浸出工艺有了大幅提升。     

贵州某微细粒金矿中碳质物的分选研究

微细粒金矿中碳质物在金浸出体系中具有较强的劫金能力,严重降低金的浸出率。针对贵州某微细粒金矿,在多元素分析、扫描电镜分析研究基础上,采用浮选预先分选碳质物。通过浮选药剂选择试验、粗选正交试验、扫选次数试验和精选次数试验,得出较优流程为"一次粗选、一次扫选、一次精选",较优试验条件为:磨矿细度-74μm含量占65%,粗选LC-1和松醇油用量分别为100和90 g/t,扫选药剂减半,精选不添加药剂。在该试验条件下可将矿石中有机碳含量从0.81%降低到0.38%,获得83%以上的碳尾矿产率。原矿、分选产品的浸出试验表明,分选后分别浸出的总浸出率比原矿直接浸出的金浸出率高7%以上。     

某铀矿酸法搅拌浸出工艺的优化

针对西安中核蓝天铀业有限公司某铀矿2段逆流搅拌浸出工艺运行期间出现的滤布过滤效果急剧下降,过滤时间大幅延长,生产无法持续运行,以及流程长,操作人员多等问题,进行了工艺技术攻关,优化工艺流程,改2段浸出为1段浸出,使搅拌浸出工艺的浸出率达到90.6%,生产稳定持续运行,每t矿石处理成本降低了13.27元。并将该铀矿的堆浸工艺和搅拌浸出工艺有机结合,采用粗堆细冶的工艺流程,使堆浸工艺的浸出率从76%提高到82%,提高了资源利用率。     

Ferrate(VI) oxidation of glycine and glycylglycine: Kinetics and products

Amino acids and peptides may form potentially harmful disinfection byproducts during the conventional treatment of water and wastewater. Removal of these parent compounds by the use of the environmental-friendly oxidant, ferrate(VI) (Fe^VIO₄²⁻, Fe(VI)) was assessed by studying the kinetics of the oxidation of glycine (NH₃⁺CH₂COOH, Gly) and glycylglycine (NH₃⁺CH₂CONHCH₂COOH, Gly-Gly) as a function of pH (4.0-12.4) at 25 °C. This study with Gly-Gly represents an initial investigation of oxidation of peptides by Fe(VI). Generally, the second-order rate constant (k) increased with decreased pH in the basic pH region, but this trend was reversed in the acidic pH range. Consideration of the reactivity of three oxidants (H₂FeO₄, HFeO₄⁻, and FeO₄²⁻) with three species of Gly and Gly-Gly (positive, neutral, and negative) reasonably explained the pH dependence of the rates. At pH 9.0, the molar consumption of Fe(VI) was nearly equal to that of Gly. The reaction of Fe(VI) with Gly at molar ratios of 1.0 and 2.0 ([Fe(VI)]:[Gly]) produced ammonia, carbon dioxide, and acetate. A reaction scheme is proposed which explains the formation of these products. The values of k for oxidation of iminodiacetate and nitriloacetate at pH 7.0 were also determined in order to compare oxidation of amines by Fe(VI). The calculated half-lives at neutral pH for the oxidation of primary and secondary amines were in seconds while decomposition of tertiary amines would occur in minutes. Overall, the reactivity of Fe(VI) with Gly and Gly-Gly indicates the significant potential of Fe(VI) to remove amine- and peptide-containing pollutants in water and wastewater.     

干膜与阻焊油墨对化镍金厚度的影响

感光阻焊与干膜析出物,是化镍金表面工艺金、镍缸控制寿命的原因之一,旨在改善黑焊盘缺陷。由于阻焊、干膜种类繁多,且阻焊、干膜与化镍金药水属于不同公司或厂家,鉴于配方专利等原因,单方对其相互影响原理甚至现象鲜有研究,此方面文献更是屈指可数。本文简述了"黑焊盘"发生的基本原理,并利用干膜以及不同阻焊油墨进行试验,通过测量镍金层厚度评估干膜与油墨对化镍金工艺的影响。通过机理验证试验,验证阻焊油墨析出物抑制化镍反应,而非目前业界所认知的加速反应。本实验一则为PCB厂家提供经验数据,利于生产控制;二则抛砖引玉,促进阻焊油墨、干膜、化镍金药水及PCB厂家对其进一步研究。