低浓去污预氧化过程中因科镍690合金我因科镍600合金的电化学 …

介绍了低浓去污预氧化过程中两种蒸汽发生器材料因科镍６９０合金及因科镍６００合金（下面简称６９０合金及６００合金）在不同邓氧化剂中脱膜效果（以铬的释放曲线表征）实验、腐蚀电位迁移测试和极化曲线测试。结果表明,６００合金在碱性高锰酸钾（ＡＰ）中的脱膜效果好于酸性高锰酸钾（ＮＰ）中,而６９０合金则在（ＮＰ）中的脱膜效果好于ＡＰ中。并且在ＮＰ中,随着硝酸浓度的增加,６００合金的腐蚀电位向正方向移动,６９０     

Efficient and novel Sb2S3 based solar cells with chitosan/poly(ethylene glycol)/electrolyte blend

We present here a novel solar cell made of ITO/composite p‐doped Sb₂S₃ + P3HT + PANI+TiO₂/amorphous Sb₂S₃ + P3HT + PANI + TiO₂/n‐doped Sb₂S₃ + P3HT + PANI + TiO₂/solid carrier/aluminum as counter electrode. With spraying technique, the layers were deposited and the thickness of films was 1 μm. A new solid carrier of electrolyte was a blend consisted of chitosan (low MW), polyethylene glycol and electrolyte. X‐ray diffraction was recorded to confirm the amorphous nature of the blend. Information about the surface appearance and roughness of a solid carrier dry and soaked in the electrolyte was given by atomic force microscopy. The solar cell was examined at very low and low light intensity (5% and 35% of sun, respectively), and at standard test conditions (100% of sun) using different light sources. The whole cell surface was 7.5 cm² while the illuminated part was 3 cm². Obtained results expressed for the illuminated surface showed the highest efficiency of 23.1% at 5% of sun while the efficiency of the cell was 2.9% at 35% of sun and only 0.75% at intensity of 100% of sun.     

600MW亚临界空冷机组汽轮机高调门摆动问题的分析及解决方案

本文针对国内两台处于电网末端的600 MW亚临界空冷机组,在顺序阀方式下运行至高调门第三阀与第四阀重叠区域附近阀位时,出现的高调门高频摆动问题进行分析研究。最终,通过对机组实际运行参数和DEH控制逻辑的分析,发现了阀门摆动的根本原因,并采用配汽优化技术较好的解决了这一问题。这对提高目前国内占主流的600 MW级别机组的顺序阀运行方式下的安全性、经济性以及一次调频等调节性能具有一定的借鉴意义。     

火电机组蒸汽冷却器运行热经济性分析研究

以引进型600MW机组热力系统为研究对象,运用等效焓降法,对蒸汽冷却器的运行热经济性进行了定量分析,结果表明,蒸汽冷却器连接位置不同,其经济效果也不同,对现行机组的优化改造提出了建议,为进一步提高机组效率提供了一定的理论依据。     

PEG200增塑改性ACNs/MMT/PHBH纳米复合包装膜

目的 制备聚乙二醇(PEG200)-乙酰化纤维素纳米晶体/蒙脱土/聚3-羟基丁酸酯-co-3-羟基己酸酯(PHBH)纳米复合包装膜,探究PEG200对三元纳米复合材料(ACNs/MMT/PHBH)性能的影响,以获得柔韧性、分散性等性能优良的纳米复合包装膜,增加复合包装膜在包装上的可应用性.方法 通过溶液共混法制备不同比例的PEG200-ACNs/MMT/PHBH纳米复合包装膜,应用扫描电镜、傅里叶红外光谱、偏光显微镜、热重分析、差式扫描量热仪、拉伸测试仪和透氧透湿测试仪,对复合膜的断面形貌、热稳定性、晶体形貌、力学性能和阻隔性能进行分析表征.结果 扫描电镜显示,加入适量的PEG200后,纳米颗粒上具有包覆作用,使得填料与PHBH基质间的相容性得到进一步改善.力学测试结果表明,PEG200的加入使复合包装膜的韧性有一定程度的提高,当PEG200的质量分数为6％时,与未添加PEG200的包装膜相比,其断裂伸长率增加了29.9％.阻隔性能测试结果显示,当PEG200的质量分数为4％时,复合膜的阻隔性能最佳,水蒸气透过率和氧气透过率分别为26.48 g/(m2·d)和28.46 cm3/(m2·d).结论 实验结果表明,加入少量的PEG200能够改善纳米粒子与PHBH之间的相容性,提高ACNs/MMT/PHBH纳米复合材料的韧性和阻氧阻湿性能.     

Tuning the Solution Self-Assembly of a Peptide-PEG (Polyethylene Glycol) Conjugate with α-Cyclodextrin

Cyclodextrins are saccharide ring molecules which act as host cavities that can encapsulate small guest molecules or thread polymer chains. We investigate the influence of alpha-cyclodextrin (αCD) on the aqueous solution self-assembly of a peptide-polymer conjugate YYKLVFF-PEG3K previously studied by our group [Castelletto et al., Polym. Chem., 2010, 1, 453–459]. This conjugate comprises a designed amyloid-forming peptide YYKLVFF that contains the KLVFF sequence from Amyloid β peptide, Aβ16-20, along with two aromatic tyrosine residues to enhance hydrophobicity, as well as polyethylene glycol PEG with molar mass 3 kg mol⁻¹. The conjugate self-assembles into β-sheet fibrils in aqueous solution. Here we show that complexation with αCD instead generates free-floating nanosheets in aqueous solution (with a β-sheet structure). The nanosheets comprise a bilayer with a hydrophobic peptide core and highly swollen PEG outer layers. The transition from fibrils to nanosheets is driven by an increase in the number of αCD molecules threaded on the PEG chains, as determined by ¹H NMR spectroscopy. These findings point to the use of cyclodextrin additives as a powerful means to tune the solution self-assembly in peptide-polymer conjugates and potentially other polymer/biomolecular hybrids.     

微生物矿化对黏土渗透性影响的试验研究

为探究矿化对黏土渗透性的影响,采用球形赖氨酸芽孢杆菌属kp-22菌诱导矿化处理黏土,测定了碳酸盐生成率,研究了矿化处理后黏土的渗透性,系统分析了渗透系数随菌液OD₆₀₀值、胶结液浓度和土中镉含量变化的规律,探讨了各因素对渗透系数的影响规律及机理,建立了考虑菌液OD₆₀₀值和胶结液浓度影响的矿化后黏土渗透系数的经验公式。结果表明:矿化后的土样中生成了碳酸盐颗粒,填充了部分土体孔隙,渗透系数最多可降低约一个数量级;随着菌液OD₆₀₀值的增大,矿化后黏土的碳酸盐生成率先升高后逐渐稳定,而土样的渗透系数先减小后趋于平稳,当菌液OD₆₀₀值大于0.9时,碳酸盐生成率和渗透系数都变化很小;随着胶结液浓度增大,碳酸盐生成率先升高后下降,而渗透系数先减小后增大,当胶结液浓度为0.8 mol/L时,黏土的渗透系数最小;随着土中镉含量的增大,矿化反应受到抑制,渗透系数逐渐增大;矿化后黏土的渗透系数与碳酸盐生成率负相关,两者满足线性关系;所建立的矿化后黏土渗透系数经验公式计算值与试验结果吻合较好。     

荆门电厂600MW超临界机组协调控制系统改进与优化

针对荆门电厂600MW超临界机组的设备特性和协调控制系统的构成、特点和难点等进行了分析;在此基础上,对协调控制、给水、汽温自动调节等控制策略进行了改进与优化,并在实际中成功应用.对同类机组控制策略设计和现场调试提供借鉴.