Investigation of formaldehyde-free wood adhesives from kraft lignin and a polyaminoamide–epichlorohydrin resin

A formaldehyde-free wood adhesive system consisting of kraft lignin and a polyaminoamide-epichlorohydrin (PAE) resin (a paper wet strength agent) has been investigated in detail. The lignin-PAE adhesives were prepared by mixing an alkaline kraft lignin solution and a PAE solution. Mixing times longer than 20 min had little impact on the shear strength of the wood composites bonded with the lignin-PAE adhesives. The shear strength of the wood composites bonded with the lignin-PAE adhesives increased and then flattened out when the press time and the press temperature increased. The shear strength and water resistance of the wood composites bonded with the lignin-PAE adhesives depended strongly on the lignin/PAE weight ratio. Of the weight ratios studied, the 3:1 lignin/PAE weight ratio resulted in the highest shear strength and the highest water resistance of the resulting wood composites. The wood composites bonded with the lignin-PAE adhesives did not delaminate and retained very high strengths even after they underwent a boiling-water test. The lignin-PAE adhesives could be stored at room temperature for two days without losing their adhesion ability. PAE was the crosslinking agent in this lignin-PAE adhesive. Possible reactions between lignin and PAE are discussed in detail.     

Geometric Factors Impacting Adhesive Lap Joint Strength and Design

Too often adhesive thickness, adherend thickness and other geometric factors are not explicitly considered in adhesive joint design. This study includes experimental and computational research exploring the means of enhancing the engineering design process for adhesive lap joints to include such effects. It clearly demon-strated that both the cleavage stresses and the shear stresses, near the bond termini, play important roles in lap 'shear' joint failure. Finite Element and Fracture Mechanics analyses were used to examine the energy release rate applied to growth of cracks in adhesive lap joints. Lap joints with similar geometries to those analyzed were designed, fabricated and tested. In a separate set of experiments the bond termini were constrained in the direction normal to the uniaxial loading. If the strength of lap shear joints is dominated by the adhesive shear strength, then constraining the lateral motion of the bond termini should have little or no effect on the overall shear strength of the adhesive joint. This work clearly demonstrates that this is not the case. If cleavage stresses are important in lap joints then constraining the bond termini, in a direction normal to the bond area, should have a commensurate effect on the overall strength of the lap joint. None of the ASTM standardized 'lap shear tests' provide any insight into this premise. This paper also presents analyses and experimental results for lap joints to which several methods of lateral constraint were applied near the bond termini. The analytical and numerical methods described and used for explaining and predicting such effects might be a useful adhesive joint design tool.     

Comparative Study of the Results of Various Experimental Tests Used for the Analysis of the Mechanical Behaviour of an Adhesive in a Bonded Joint

The use of adhesively bonded joints is often limited by a lack of reliable models able to accurately predict their behaviour in industrial applications, in which the stress distribution is often complex. The mechanical behaviour of an adhesive in a bonded joint is often heavily dependent on its stress state (i.e., the tensile–shear combinations). Thus, a large experimental database is required to accurately represent the complex behaviour of an adhesive in a bonded joint. On the one hand, the initial yield surface (initial elastic limit) often has to be described taking into account the two stress invariants, hydrostatic stress and von Mises equivalent stress, and on the other hand the non-linear behaviour of the adhesive is also quite complex to model. However, the mechanical response of adhesively bonded joints often presents quite large stress concentrations; thus, the analysis of experimental tests is made particularly difficult. Obtaining reliable experimental results makes it possible to contribute to optimization of an adhesive in a bonded joint. This paper presents comparisons between results of different experimental tests (with bulk and bonded joints), some of them are designed to greatly limit the edge effects. Results are presented for two adhesives under proportional monotonic loadings. The two adhesives have very different behaviours (a ductile adhesive and a brittle adhesive) and two different surface preparations of aluminium substrates (a mechanical preparation and a chemical preparation recommended by the adhesive manufacturer) were studied.     

Influence of the adhesive thickness and steel plate thickness on the behaviour of strengthened concrete beams

The technique of strengthening concrete structures by epoxy bonding the steel plates to the tension face of the structure has been widely used in civil engineering. In this paper, the surface preparation of the concrete and steel plates is described and then the bonding technique is discussed. The influence of the adhesive thickness and the steel plate thickness on the behaviour of strengthened concrete beam is investigated. Beams with six different thicknesses of adhesive layer and five different thicknesses of steel plate were used in this study. The measured load versus strain curves for both the steel plate and the concrete of the strengthened beam were plotted. The results indicate that the ultimate flexural strength does not increase with increasing thickness of the adhesive. The strain at the first cracks in the concrete is unchanged with increasing adhesive thickness. However, at higher loads, the strain in the plate, as well as in the concrete, increased with increasing adhesive thickness. The strain in the steel plate increased at the same rate as that in the concrete in the elastic region and then the strain in the steel plate increased at a much faster rate for the same beam. The results also indicate that the strain corresponding to the ultimate load in the steel plate decreased with increasing plate thickness. The stiffness of the beam increased with the plate thickness, especially in the higher load range.     

Modeling of cohesive failure processes in structural adhesive bonded joints

This paper presents an approach to predicting the strength of joints bonded by structural adhesives using a finite element method. The material properties of a commercial structural adhesive and the strength of single-lap joints and scarf joints of aluminum bonded by this adhesive were experimentally measured to provide input for and comparison with the finite element model. Criteria based on maximum strain and stress were used to characterize the cohesive failure within the adhesive and adherend failure observed in this study. In addition to its simplicity, the approach described in this paper is capable of analyzing the entire deformation and failure process of adhesive joints in which different fracture modes may dominate and both adhesive and adherends may undergo inelastic deformation. It was shown that the finite element predictions of the joint strength generally agreed well with the experimental measurements.     

Shear and peel stress analysis of an adhesively bonded scarf joint

The shear and peel stress distributions in a scarf joint made of two isotropic adherends with blunt adherend tips are analysed using a linear elastic analysis. The limits of the analysis with respect to adherend tip thickness have been investigated. A finite difference method is used to solve the differential equations for the shear and peel stress distributions over the joint. The boundary conditions used limit the analysis to the two adherends having the same thicknesses, lengths, and material properties. The adherends are modelled as plates with extensional and bending stiffnesses bonded together with an elastic interlayer. The stresses across the adhesive layer are assumed to be constant. The current analysis applied to cases known from the literature shows good agreement with the shear stresses but the peel stresses are overestimated.     

Silanization of adhesively bonded aluminum alloy AA6060 with γ-glycidoxypropyltrimethoxysilane. II. Stability in degrading environments

Alkaline etched aluminum alloy AA6060 treated with of γ-glycidoxypropyltrimethoxysilane was investigated. The stability of the silane films in degrading environments was investigated by exposing them to acidic and alkaline solutions at 40°C, followed by analysis with reflection-absorption infrared spectroscopy. Desorption of the silane from the surface occurred at pH 4, and at a much slower rate at pH 7, while the silane film was stable at pH 8. Two models for the degradation of the silanized aluminum surface in an acidic environment were proposed: one involving simultaneously hydrolysis of the siloxane network and corrosion of the underlying aluminum surface, and the other involving only corrosion of the aluminum surface. The durability of the silane treated surface was determined using wedge tests on joints made with XD4600 one-component epoxy adhesive. The durability was significantly reduced in highly acidic environment (pH 2), but no significant differences in durability were observed in the pH range from 4 to 11, except that the durability was slightly higher in higher alkaline environment during the initial period of testing. Better durability in an alkaline environment is connected to a better stability of both the siloxane network and the aluminum surface in this environment.     

Modification of epoxy resins for improvement of adhesion: a critical review

Modification of epoxy resins for improvement of adhesion has been the subject of intense research throughout the world. Unlike for thermoplastics, physical blending is not successful for improvement of bond strength and impact strength of epoxy resins. The bond strength of an epoxy resin can be improved only by chemical modification with a suitable flexible modifier. Such chemical modification may either plasticize the epoxy matrix or lead to a two-phase microstructure. Both methods of chemical modifications are discussed critically in the present review.     

Strength and finite element analyses of single-lap joints with adhesively-bonded columns

This paper introduces a novel approach to increase the loading ability of adhesive joints by incorporating adhesively-bonded columns. Strengths of single-lap adhesive joints with adhesively-bonded columns were measured experimentally. Stress and strain distributions at selective positions in the adhesive layer were analyzed using the Finite Element Method (FEM). Failure mechanisms of the joints were analyzed. It was found that the metal-adhesive columns increased the joint strength and also the joint strength increased with increasing length of the metal-adhesive columns. Therefore, using metal-adhesive columns in adhesive joints is an effective approach for enhancing the strength of bulk adhesive joints.