稀土元素对钢铁常温发黑膜微观结构的影响

通过EDS、SEM等测试手段，研究了钢铁常温发黑氧化膜的元素组成、微观组织结构，探讨了稀土元素在发黑成膜反应中的作用机理。结果表明，稀土元素的加入能促进反应离子在金属基体表面的吸附作用，从而有利于新的结晶生长，形成新的晶核，可使膜层组织细化致密，改善发黑膜的表面质量。     

100 MN双动铝挤压机主柱塞的机械加工工艺

介绍了国内首台万吨铝挤压机关键零部件主柱塞的加工工艺 ,以及在大型卧式车床上加工大直径、高光洁度阶梯深孔、盲孔的加工方法及工艺流程和所需工装设计等。     

Surface morphology and photoluminescence properties of ZnO thin films obtained by PLD

ZnO thin films on Si(111) substrate were deposited by laser ablation of Zn target in oxygen reactive atmosphere, Nd-YAG laser with wavelength of 1 064 nm was used as laser source. XRD and FESEM microscopy were applied to characterize the structure and surface morphology of the deposited ZnO films. The optical properties of the ZnO thin films were characterized by photoluminescence. The UV and deep level (yellow-green) light were observed from the films. The UV light is the intrinsic property and deep level light is attributed to the existence of antisite defects (Ozn). The intensity of UV and deep level light depends strongly on the surface morphology and is explained by the surface roughness of ZnO film. A strongly UV emission can be obtained from ZnO film with surface roughness in nanometer range.     

低能离子束辅照对溅射镀TiN膜生长的影响

用诱导型等离子体辅助磁控溅射装置在Si（100）表面低温沉积TiN膜，研究了高密度低能量（≈20eV）离子束辅照对溅射镀TiN膜生长、结构和性能的影响．结果表明，高密度低能离子束辅照会改变TiN膜的择优生长方向并使薄膜致密化。即使沉积温度低于150℃，当入射基板离子数和Ti原子数的比值Ji／JTi≥4.7时，沉积的TiN膜仍可具有完全的（200）面择优生长，薄膜微观结构致密，硬度达到25GPa，残余压应力小．     

溶胶-凝胶法制备纳米TiO2薄膜

用溶胶-凝胶法，以钛酸丁脂为先驱体、无水乙醇为溶剂、二乙醇胺为络合剂，以载玻片为基体采用溶胶．凝胶浸渍提升法制备纳米TiO2薄膜。探讨制备过程中影响薄膜质量的因素，用NDJ-8S数字显示粘度计测定溶胶在溶胶．凝胶过程中的粘度随存放时间的变化；差热分析仪分析有机物的热分解行为和晶型转变；红外光谱仪对干凝胶相组成进行分析；扫描电镜对薄膜的表面形貌、颗粒的均匀性等进行研究。结果表明；可在玻璃基体上镀上纳米TiO2薄膜；粘度随着陈化时间成正比关系；薄膜表面光滑，颗粒较均匀且达到纳米级颗粒。     

Amorphous sol-gel SiO2 film for protection of Ti6Al4V alloy against high temperature oxidation

Amorphous SiO₂ thin films were deposited on Ti6Al4V alloy by sol-gel processing. Isothermal and cyclic oxidation tests of the coated and uncoated specimens were performed at 700 and 800 °C. The SiO₂ film exhibited beneficial effects on the oxidation resistance of the alloy. Titania scales formed on the uncoated specimens, and severe spallation and stratification of the scales were observed. The oxidation rates of the silica coated specimens were decreased significantly. The silica film shrunk to about a quarter in thickness, probably by mechanism of crystallization of silica and evaporation of the organic additments. The oxide scales formed on the coated specimens were multilayered. Beneath the silica film, formation of a thick rutile titania layer followed by a thin alumina layer occurred. Above the silica film, alumina plus minor titania layer formed. It is deduced therefore that the growth of the multilayered and mixed oxide scales was dominated by both outward diffusion of metal and inward diffusion of oxygen.     

铝及铝合金阳极氧化膜中温封闭工艺

研究铝及铝合金阳极氧化膜和电解着色膜的中温封闭工艺,对影响膜层封闭质量的各成分含量及工艺参数进行了试验。使用含有可水解镍盐和NF-2络合剂的中温封闭液可获得满意的封闭质量。     

铝阳极氧化膜在NaCl溶液中的电化学性能

采用交流阻抗法研究了工业纯铝L3阳极氧化膜在中性NaCl溶液中交流阻抗谱的变化规律, 比较了未封闭处理与沸水封闭处理后氧化膜的交流阻抗谱的差异, 并结合等效电路分析了氧化膜多孔层与阻挡层电化学参数的变化.结果表明, 未封闭的阳极氧化膜在NaCl溶液中浸泡初期存在一个自封闭过程, 封闭处理明显提高氧化膜多孔层的初始Rp值并降低初始CPEp值; 溶液中侵蚀性离子浓度越高, 封闭处理提高铝阳极氧化膜的耐蚀性能作用越明显.     

Influence of electroplating conditions on magnetic properties of Fe-36wt.% Ni alloy film

A Fe-Ni soft magnetic film was prepared in sulphate solution by electroplating. The influences of the molar ratio of n [Fe2+ ]/ n [Ni2+ ], current density, bath temperature, pH and L-ascorbic acid concentration on magnetic properties of Fe-Ni alloy film were investigated. The results show that the saturated flux density(BS) of the film increases initially and decreases after it reaches the specific value with the increase of n [Fe2+ ]/ n [Ni2+ ] molar ratio, current density, bath temperature and pH. However, the relationship between L-ascorbic acid concentration and B S keeps linear. It is observed that the coercive force( Hc) is enhanced with the increase of n [Fe2+ ]/ n [Ni2+ ] molar ratio, current density and pH. By comparison, when the bath temperature increases, Hc always decreases. With the increase of L-ascorbic acid concentration, the coercive force increases initially and then decreases.     

用快干硅溶胶生产大型汽轮机导叶片的精铸工艺

介绍采用FOSECO公司生产的D COAT快干硅溶胶制壳工艺替代硅溶胶-硅酸乙酯复合制壳工艺，生产长为950mm、毛坯质量达42kg的汽轮机弯扭导叶片的制壳工艺，并对D COAT快干硅溶胶的快干机理和影响型壳性能的因素进行了探讨。D COAT快干硅溶胶采用水溶性高聚物增强，在湿度为30％～40％、风速为6～8m／s的干燥条件下，层间干燥时间仅为1～2h。D COAT快干硅溶胶型壳湿强度和高温强度高，残留强度低，透气性好，已成功应用于汽轮机大型叶片的批量生产。