Enhanced magnetodielectric properties of Co2Z ferrite ceramics for ultrahigh frequency applications achieved via Cr3+ ion doping

Phase formation, microstructure, magnetic properties, and dielectric properties of Ba_1.5Sr_1.5Co₂Fe₍₂₃−_x)Cr_xO₄₁ (0.0 ≤ x ≤ 1.0) ceramics, in which Fe³⁺ ions were substituted by Cr³⁺ ions, were systematically investigated. X-ray diffraction results reveal that Z-type hexagonal ferrite was formed by sintering at 1250 °C, and Cr³⁺ ions successfully enter lattice without destroying crystal structure. Analysis of the microstructure reveals that Cr³⁺ ion doping has significant effect on crystal micromorphology. Samples with x = 0.4 have the most homogeneous micromorphology and the highest sintering density of 5.12 g/cm³. In addition, under the influence of external magnetic field, all samples exhibit typical soft magnetic character and hysteresis characteristics, with saturation magnetization up to 63.86 emu/g (x = 0.6). Particularly, compared with undoped sample, Cr-doped samples have outstanding magnetic–dielectric properties. Firstly, with increasing Cr³⁺ amount, real part of the permeability (μ′) reaches the maximum value of 10.70 at x = 0.4, while cutoff frequency exceeds 2 GHz, and Snoek constant reaches ∼19.50 GHz. Furthermore, due to more homogeneous microstructure, samples with x = 0.4 have low magnetic loss and can maintain high quality factor (Q) over a broad frequency range. Moreover, real part of the permittivity (ε′) reaches the maximum value of 16.90 at x = 0.6, and dielectric loss remains lower than 0.013 for frequencies below 0.7 GHz. Consequently, magnetic–dielectric materials prepared in this work are expected to have extensive application prospects for ultrahigh-frequency devices.     

Recent Applications of Polymer Blends in Gas Separation Membranes

Polymeric membranes are extensively used for gas separations but their performance is limited by the upper bound trade‐off discovered by Robeson in 1991. Among the attractive modifications available to increase the performance of polymeric membranes, polymer blending is a unique technique because it offers a time‐ and cost‐effective method of tuning the properties of membranes. A variety of polymer blends has been explored in recent years. The application of polymer blends in gas separation membranes is described by critically analyzing the performance of polymer blend membranes. Polymer blend membranes of different polymer pairs are reviewed and evaluated in terms of phase behavior, permeability, and selectivity.     

PREPARATION AND PERMEABILITY CONTROL OF ELECTRO-SENSITIVE MICROCAPSULES WITH IMMOBILIZED FERROELECTRIC LIQUID CRYSTALLINE SEGMENTS

Nylon-polystyrene microcapsules with immobilized ferroelectric liquid crystalline segments were prepared, and the permeability control of the encapsulated core material was investigated under an external electric field. A ferroelectric liquid crystal monomer possessing both mesogenicity and chirality effectively responded to an external electrical field. Permeation of the material (oxprenolol) contained in the inner aqueous core of the microcapsules was enhanced under a feeble electric field (2 V). Furthermore, it was found that the permeability of the microcapsules without the ferroelectric liquid crystal group did not depend on the external electrical field. In order to clarify the controlled release mechanism of the core material, the transmittance was quantitatively evaluated under an external electric field using a handmade polarized light transmittance apparatus.     

A Two-Dimensional Finite Element Model for Kiln-Drying of Refractory Concrete

ABSTRACT

A two-dimensional finite element model is developed for kiln-drying of refractory concrete. Using this model simulations are carried out for refractory concrete castings of different thicknesses to investigate the effects of drying schedules on pore steam pressure and moisture removal. Simulation results from both one- and two-dimensional models are compared and discussed. On the basis of the simulation results new realistic drying schedules are suggested.     

高阻隔液态牛奶包装膜

介绍新型的高阻隔材料——丙烯酸酯共聚物。将其配制成高阻隔涂布液,再用涂布设备将高阻隔涂布液涂布于三层共挤聚乙烯底膜上,干燥后在高阻隔层上复合一层聚乙烯薄膜,得到高阻隔高保香性的液态牛奶包装膜。该产品在阻隔效果、投资成本、包装成本和卫生环保等诸多方面,都要比市场上的其他阻隔材料优秀很多。     

FUNDAMENTALS OF DRYING TECHNIQUES

The samples of sliced and mashed apples were freeze-dried by controlling their surface temperatures over the usual pressure range of commercial operations. The surface of sliced samples could not be maintained at above 10°C in order to prevent the frozen layer from melting, while that of mashed samples was allowed to heat up to 70°C.

Thermal conductivities and permeabilities were determined by applying the uniformly-retreating-ice front model to the dried layer of the samples undergoing freeze-drying. The values of permeability for the mashed samples were found to depend on the ice-crystallization time during freezing. The results indicated that the drying rate of sliced samples was limited by the transfer rate of water vapor flowing through the dried layer. A cellular structural model is proposed for predicting the permeability of the dried layer, based on the resistance of the cell membrane to molecular transfer of water vapor.     

POWER-LAW FLUIDS IN POROUS MEDIA

An analysis is presented to describe the parallel flow of power-law fluids within a channel bounded by porous media. It is shown that there is an excess flow above the Darcy's law prediction for the porous medium region adjacent to the channel/ porous medium boundary. This also leads to a higher flow rate in the channel. The excess flow increases with a decreasing value of the power law index, and with increasing permeability. The excess flow is found to reach a maximum at an intermediate value of the dimensionless channel width (=½H/K^½and it vanishes in the limit of h→∞and h→0. Experimental evidence is also presented to demonstrate the excess flow. The experimental data are found to be in reasonable agreement with the proposed flow model.     

THE INFLUENCE OF COMPRESSION WOOD ON THE DRYING CURVES OF PINUS RADIATA DRIED IN DEHUMIDIFIER CONDITIONS

ABSTRACT

Measurements of drying rate of Pinus radiata at 55°C and 30% RH are presented. The data, which has been used to establish empirical models for P. radiata under dehumidifier drying conditions, was obtained in four drying runs in a drying tunnel, each yielding detailed drying curves for twelve sample sapwood boards of size 350 × 100 × 50 mm. Compression wood was found to have a significant effect on the drying rate curve, giving lower drying rates at 40–100% MC. This effect is interpreted through the use of a numerical multiple-mechanism two-zone model and quantified by using best-fit diffusion parameters from an isothermal diffusion model. A positive correlation was discovered between the moisture diffusion coefficient and initial moisture content, a strong indicator for the presence of compression wood. In the two-zone model, the compression wood effect was replicated by using a tenfold decrease in permeability to liquid flow. Attributes of compression wood that could cause reduced permeability include an increased proportion of latewood, narrower lumen, and a scarcity of bordered pits on the radial walls of longitudinal tracheids.     

Radio Frequency Vacuum Drying of Wood. III. Two-Dimensional Model,Optimization, and Validation

Abstract

A simple two-dimensional model is presented for the radio frequency vacuum drying of thick timbers. The developed code is linked to powerful optimization methods to account for the variability of the permeability and the internal pressure deviation from the saturated vapor pressure above the fiber saturation point. The model is compared with recently obtained experimental results where the radio frequency heating source is an amplifier. Despite the simplicity of the model, good agreement with experimental data was obtained for a variety of drying conditions, especially in predicting the average moisture evolution and the drying time as well as the development of the temperature profiles in two types of softwood timbers.     

粉煤灰在油田开发中的应用

在对某热电厂粉煤灰全面的性能分析的基础上,介绍了一种以粉煤灰为主剂的水井用调剖剂。经室内实验分析和现场应用的效果分析,证明FP-2型粉煤灰类调剖剂的堵水调剖效果好,为粉煤灰的综合利用找出了一条新的应用途径。