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81.
82.
Maurus Biedermann 《LWT》2006,39(6):633-646
Phenolic resins (resoles) are used for curing expoxy and polyester coatings, e.g., for food cans. They consist of oligomeric materials prepared from phenols (phenol, cresol, tert.-butyl phenol), formaldehyde and butanol and are an analytical challenge because of the complexity of their composition. A phenol-based resole was selected for a first investigation of various analytical techniques: gas chromatography (GC)-mass spectrometry (MS), comprehensive two-dimensional GC (GC×GC), normal phase high-performance liquid chromatography (NPLC, primarily of interest for preseparation for GC analysis), and size exclusion chromatography (SEC). Mass spectra are discussed for some selected compounds and a list of spectra is added. GC×GC was the most powerful method for separating and visualizing the composition of the complex mixture, but the whole battery of methods might be needed to characterize resoles and to analyse their migration into food or food simulants. 相似文献
83.
Ekrem Köksal Ercan Bursal İlhami Gülçin Mustafa Korkmaz Cüneyit Çağlayan Ahmet C. Gören 《International Journal of Food Properties》2017,20(3):514-525
Like tea, the leaves of Turkish thyme (Thymus vulgaris) can be boiled in water to produce an extract. This is widely used as syrup for the treatment of coughs and bronchitis at alternative medicine clinics in many parts of the world. In the current study, we assessed the phenolic content and antioxidant activity of thyme. The antioxidant activities of both ethanol and aqueous extracts of thyme were determined using various in vitro methods. The total phenolic and total flavonoid contents were determined to be a gallic acid equivalent and a quercetin equivalent, respectively. Finally, the quantities of the phenolic compounds were detected using high-performance liquid chromatography and tandem mass spectrometry. The total phenolic compounds in the aqueous extract and ethanol extracts of Turkish thyme were 256.0 μg gallic acid equivalent/mg dried extract and 158.0 μg gallic acid equivalent/mg dried extract, respectively. Conversely, the total flavonoid compounds in both extracts were 44.2 μg and 36.6 μg quercetin equivalent/mg dried extract, respectively. For the first time, we determined phenolic contents and investigated the antioxidant potential of thyme. The results indicate that Turkish thyme is a good dietary source with phenolic properties. 相似文献
84.
使用合适的有机溶剂将有机样品稀释后直接导入电感耦合等离子体发射光谱仪(ICP-OES)测定有机物中金属元素的方法,前处理简单,测定速度快,但由于ICP-OES直接分析有机物时常出现点炬困难、容易熄炬、炬管断裂等问题,此方法未得到广泛应用。本文以美国Perkin Elmer公司Optima 7000DV型ICP-OES为例,对ICP-OES在分析易挥发有机样品过程中出现的常见故障及排除方法进行探讨,并介绍了分析有机物的注意事项。 相似文献
85.
Vitamin C and polyphenol content as well as total antioxidative activity were investigated in fresh leaves of kale; in leaves after blanching or cooking; and in frozen and canned leaves. In 100 g fresh matter, kale leaves contained 384.9 mg polyphenols and 112.1 mg vitamin C, with a Trolox equivalent antioxidant capacity (TEAC) level of 1175 μM Trolox. Of the polyphenols identified in kale leaves, ferulic acid occurred in the highest amount (240.44 mg/100 g, constituting 62% of total polyphenols). Freezing was a better method of preserving kale leaves since the loss of nutritive constituents was lower than in the case of canning. Depending on preliminary processing and storage temperature, after one-year storage frozen leaves contained 82.9–171.3 mg polyphenols and 39.3–65.4 mg vitamin C, with TEAC at the level of 501–681 μM Trolox in 100 g. In canned leaves these values were: 91.3–94.1 mg polyphenols, 16.1–19.3 mg vitamin C and 268–293 μM Trolox. 相似文献
86.
Phenolic acids in caryopses of two cultivars of wheat, rye and triticale that display different resistance to pre-harvest sprouting 总被引:3,自引:0,他引:3
S. Weidner R. Amarowicz M. Karamać G. Dąbrowski 《European Food Research and Technology》1999,210(2):109-113
This study confirmed the significant role of phenolics in the dormancy of cereal caryopses. Investigations were conducted
on two cultivars of wheat (Elena and Alba), rye (Amilo and Dańkowskie Złote), and triticale (Ugo and Bogo), with characteristic
deeper or shallow dormancy, respectively. In germination studies, cultivars susceptible to sprouting (Alba, Dańkowskie Złote
and Bogo) displayed higher germination percentages than those resistant to sprouting (Elena, Amilo and Ugo). The phenolic
acid contents (i.e. free, liberated from soluble esters, and liberated from soluble glycosides) in caryopses were determined
by an HPLC method. Caffeic, p-coumaric, ferulic and sinapic acids were the dominant phenolic acids detected. The majority of phenolic acids were found
in the form of soluble esters. For all species examined, the levels of phenolic acids liberated from soluble esters and the
total phenolic acid contents in caryopses showing shallow dormancy were higher than in those showing deeper dormancy. Slight
differences in the UV spectra of extracts of phenolic compounds from caryopses showing shallow or deeper dormancy were noted.
Received: 6 April 1999 相似文献
87.
The method of using spent liquor (SL) obtained from the chemical pretreatment stage of wheat straw semi-chemical pulping to prepare spent liquor phenolic resins (SLPR) was investigated in the present work. In this work spent liquor was modified with phenol, and then the modified spent liquor was further synthesized with phenol and formaldehyde under appropriate conditions. Experimental data shows that the substitution mass fraction of spent liquor for phenol, the mole ratios of formaldehyde and sodium hydroxide to phenol, temperature and duration time of addition and condensation reaction all show significant influence on the properties of SLPR. SLPR and pure phenolic resins (PR) exhibited almost the same macromolecular structures characterized by FT-IR, and the main properties of the SLPR such as free formaldehyde content, gel time and bonding strength demonstrated superiority to that of PR. 相似文献
88.
89.
Jozef Ková?ik Ji?i Grúz Bo?ivoj KlejdusFrantišek Štork Josef Hedbavny 《Food chemistry》2012,131(1):55-62
Accumulation of metals and selected nutritional parameters of chamomile (Matricaria chamomilla) anthodia cultured under natural condition on an experimental field in Košice (Slovak Republic) were studied. Two official cultivars (diploid ‘Novbona’ and tetraploid ‘Lutea’) and two ontogenetic phases of anthodia (‘bud’ and ‘flower’) were compared. K, Ca, Mg, Al, Cu, Cr, Hg and Cd were more accumulated in both bud and flower of diploid plants while accumulation of Fe, Zn, Ni and Pb was ploidy-independent. Bioaccumulation factor was lower than one for toxic metals, indicating that chamomile is an excluder. Tetraploid plants contained lower concentrations of amino acids but higher concentrations of phenolic acids compared to diploid plants. Among phenolic acids, caffeic and vanillic acids were mainly present in the glycosidic form. Reducing sugars (glucose equivalents), total soluble phenols, sum of flavonols, individual flavonols (quercetin and kaempferol), apigenin and herniarin were more accumulated in anthodia of tetraploid plants. Our data indicate that increase in ploidy level reduces accumulation of toxic metals and amino acids but enhances accumulation of phenolic metabolites. Thus polyploidisation is a good tool to achieve safer chamomile cultivars for pharmaceutical purposes. 相似文献
90.
Hanen Falleh Samia Oueslati Sylvain Guyot Alia Ben Dali Christian Magné Chedly Abdelly Riadh Ksouri 《Food chemistry》2011
Mesembryanthemum edule is used as a food ingredient and in traditional medicine. In this study, we investigated antioxidant activities of several extracts (methanol/acidified water, v/v: 20/80; 40/60 and 60/40) obtained from M. edule leaf, stem and root. Then, individual phenolics were characterised by reverse-phase HPLC coupled to electrospray ionisation mass spectrometry and multi-stage MS fragment analysis. Results showed that 40% methanol leaf extract, 40% methanol root extract and 20% methanol stem extract displayed the highest scavenging activity against DPPH and ABTS radicals. Regarding LC/ESI-MS/MS identification of active phenols, there were significant differences among the fractions of interest. In fact, 40% leaf extract mainly contained procyanidins, whereas propelargonidins were the major phenolics in 20% methanol stem extract, while, in 40% root extract, the active compounds remained unidentified. These results indicate that edible M. edule can be used as a nutraceutical in the pharmaceutical industry. 相似文献