循环流化床提升管中固体颗粒停留时间的分布

在内径１４０ｍｍ，高１０ｍ的循环流化床提升管中，采用磷光颗粒示踪法对床内固体颗粒的停留时间分布进行了测定。在气速１．５～９．０ｍ／ｓ，固体循环量１０～１４０ｋｇ／ｍ２ｓ的范围内，实验测得的停留时间分布曲线均有明显的双峰分布。这种双峰分布是由于提升管中弥散颗粒和颗粒团共同作用的结果。本文提出的一维两组分扩散叠加模型可较好地描述提升管中固体的混合行为。考察了在实验条件下，操作条件对固体混合行为的影响。发现：气速及固含对颗粒的轴向Ｐｅｃｌｅｔ数影响不大，提升管中颗粒的返混主要是由于颗粒团引起的。将研究结果与近期文献报道的其他研究进行了对比     

Near UV-based LED fabricated with Ba5SiO4(F,Cl)6:Eu as blue- and green-emitting phosphor

A series of halosilicate phosphor, Ba₅SiO₄(F,Cl)₆:Eu²⁺, were synthesized by a solid state reaction. Excited by 370-nm light, Ba₅SiO₄Cl₆:Eu²⁺ exhibits a broad emission band peaking at 440 nm. Partial substitution of Cl⁻ with F⁻ in the host lattice leads to red-shift in the emission band with centering wavelength from 440 nm to 503 nm. The possible mechanism for the luminescence change was discussed based on the XRD patterns. Blue and green LEDs were fabricated by combination of a 370 nm-emitting near UV chip and the optimal Ba₅SiO₄Cl₆:Eu²⁺ and Ba₅SiO₄(F₃Cl₃):Eu²⁺, respectively. This series of phosphors is considered as a promising blue and green component used in fabrication of near UV-based white LEDs.     

释光探源

释光技术用于年龄测定的依据是磷光体能够储存辐射的能量,但磷光体对不同辐射种类的能量吸收效率和释光响应各不相同,因此释光测定年龄这一技术本身要求各种学科知识的支撑,有些知识甚至是本学科都尚未深入研究的。作者简述了释光测年技术的历史,并以自身的实践阐述在对释光的认识过程中所必须具备的知识。还以长石为例,叙述了在自行开发的BG2003释光谱仪上新进行的研究工作。     

YAG荧光屏的制作与性能

介绍一种YAG荧光屏的结构、制作以及性能。YAG荧光屏不同于传统玻璃荧光屏的一个显著特点就是以具有高热导率、高机械强度、良好绝缘性和透光性的单晶YAG代替玻璃作为荧光屏粉层衬底。我们在YAG衬底上采用离心沉淀法制作荧光粉层;有机膜采用手工旋涂法工艺制作;铝膜采用真空电阻蒸发法制作,并讨论了铝膜的最佳厚度选取。3英寸红、绿、蓝荧光屏在0.5mA电流、29kV电压下亮度分别是6.2×10     

The UV and VUV luminescence properties of the phosphor Mg2GeO4:Tb

A novel green phosphor Mg₂GeO₄:Tb³⁺ with pure phase was prepared by the solid state reaction. The luminescence properties were investigated in detail. The diffusion reflection spectra of the undoped and Tb³⁺ doped Mg₂GeO₄ phosphors were recorded, the result reveals that there is an absorption band superposition of the host material and Tb³⁺ ion. The study on the excitation and diffusion spectra shows that there is an effective energy transfer from the host material to Tb³⁺ ion. Under 277 and 172 nm excitation, the phosphor presents predominant green emission at 543 and 547 nm respectively. The excitation intensity at 172 nm is about 1.8 times of that at 272 nm. The promising luminescence properties make it a candidate for application in Plasma Display Panel.     

作为携带、沉积纳米荧光粉颗粒和纳米铁电体颗粒到FEDs 和 EL 器件上的载体的可印刷的油墨、粘结剂

文章介绍了两种移植和可控纳米沉积荧光粉颗粒和纳米铁电体颗粒的载体.第一种载体是一种可以悬浮和沉积合成的具有亚微米级尺寸大小的荧光粉颗粒的油墨.解决了该油墨的聚集和沉降问题,并发现该油墨具有良好的液流学性能,从而可用于印刷高分辨率的荧光粉.测量了相关的单个象素的阴极发光密度以评定这种丝网印刷油墨的可重复性.第二种载体是一种粘结剂,这种粘结剂不仅可以携带 30 μm 以及更大的尺寸的电致发光的荧光粉,还可以携带纳米铁电体颗粒.这种新型的粘结剂可应用于不需要额外的绝缘反射层的低造价的 EL 显示器.从衬底按要求将发射层剥下来就形成了柔性薄膜,将该薄膜置于两电极之间,仍可保持其电致发光的活性.该粘结剂薄膜可以很容易地印刷和定型制成显示屏.     

Effect of Al3+ on the spectroscopic properties of Eu2+- and Tb3+-Doped high silica glass

In this study, Eu²⁺/Al³⁺-, Eu²⁺/Tb³⁺-, and Eu²⁺/Tb³⁺/Al³⁺-doped high silica glasses were prepared, and the effect of Al³⁺ on the spectroscopic properties of Eu²⁺ and Tb³⁺ and the energy transfer of Eu²⁺→Tb³⁺ was investigated. The results revealed that the addition of Al³⁺ increased the luminescent intensity of the Eu²⁺-doped glass by approximately 400 times. An obvious Eu²⁺→Tb³⁺ energy transfer occurred in the Eu²⁺/Tb³⁺-doped high silica glass, whose transfer efficiency can reached 66.9%. However, the efficiency continuously decreased as the Al³⁺ concentration increased, and eventually, it dropped to 7.2%. These phenomena can be explained by the following: Al³⁺ not only disperses Eu²⁺ but also changes the field strength and symmetry of its neighboring environment, thus increasing its emission intensity. Moreover, Al³⁺ destroys the strong dipole–dipole interactions between Eu²⁺ and Tb³⁺ in high silica glass due to its dispersive ability, which inhibits the energy transfer of Eu²⁺→Tb³⁺. This indicates that a small amount of Al³⁺ can significantly modify the neighboring environment of Eu²⁺ and change its light-emitting characteristics, potentially yielding efficient blue and green phosphors excited by near-ultraviolet light for use in white light-emitting diodes.     

InP中的Be、P共注入及其退火特性研究

本文对InP中的Be单注入和Be、p共注入及其退火特性进行了比较.SIMS和电化学C-V测试结果表明:采用Be、P共注入可以抑制退火过程中的Be扩散再分布,提高载流子的激活率,改善Pn结的电特性.与单注入相比,共注入样品Be的激活率提高了近一倍.pn结的击穿电压提高,漏电流明显减小.文中对共注入改善退火特性的机理进行了讨论.     

Mixing behavior of wide-size-distribution particles in a FCC riser

A comparison study on the axial and lateral mixing of wide-size-distribution (WSD) particles with normal-size-distribution (NSD) FCC particles is presented. The fines smaller than 20 μm contribute 24.5% in volume in the WSD particles. Phosphor tracer method is used. The axial backmixing of the WSD is slightly lower than the NSD. However, the lateral solids Peclet number increases linearly with the increase of the content of fines smaller than 20 μm because of the serious agglomeration of the fines, which leads to very poor lateral mixing for the WSD particles. And the solids lateral mixing for the WSD particles decreases significantly with increasing solids fraction. These results show that the particle size and the particle-size-distribution is a very important factor that controls the lateral solids mixing and hence the heat and mass transfer in lateral direction, which should be taken into full consideration in the riser reactor. And the NSD may be a good particle size distribution for the FCC riser, the lateral solids mixing of which is satisfactory in the reactor.     

Ca_xSr_(1-x)Al_2O_4∶Eu~(2+)磷光体的制备及性能研究

采用高温固相合成法还原气氛中分别制备了CaxSr( 1-x) Al2 O4∶Eu2 + (x≤ 0 .5 )发光粉 ,其发射光范围为蓝绿色到黄色。合成温度为 1 2 0 0℃ ,激活剂Eu2 + 的最佳摩尔浓度为 0 .6% ,并研究了Sr CO3 与Al2 O3 比值、CaCO3 的添加量对发光材料发光性能的影响。实验中四硼酸钠·十水作为添加剂 ,不仅起到了助熔的作用 ,还提高了磷光体的余辉发光性能。