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排序方式: 共有3553条查询结果,搜索用时 15 毫秒
41.
A. Chetouani B. Hammouti A. Aouniti N. Benchat T. Benhadda 《Progress in Organic Coatings》2002,45(4):373-378
The inhibition of pure iron in 1 M HCl by new synthesised pyridazine compounds has been studied by weight loss, electrochemical polarisation and electrochemical impedance spectroscopy (EIS) measurements. The results obtained reveal that these compounds are efficient inhibitors. The inhibition efficiency increases with the increase of inhibitor concentration and reached 98% at 10−4 M for 5-benzyl-6-methyl pyridazine-3-thione. Potentiodynamic polarisation studies clearly reveal that the presence of pyridazines does not change the mechanism of hydrogen evolution and that they act essentially as cathodic inhibitors. The temperature effect on the corrosion behaviour of pure iron in 1 M HCl without and with the pyridazines at 10−4 M was studied in the temperature range from 298 to 353 K. EIS measurements show that the increase of the transfer resistance with the inhibitor concentration. 相似文献
42.
Seong-Soo Hong Gun-Dae Lee Jong-Won Park Dae-Won Park Kyung-Mok Cho Kwang-Jung Oh 《Korean Journal of Chemical Engineering》1997,14(6):491-497
In the present work, we have investigated the reduction of NO by propane over perovskite-type oxides prepared by malic acid
method. The catalysts were modified to enhance the activity by substitution of metal into A or B site of perovskite oxides.
In addition, the reaction conditions, such as temperature, O2 concentration, and space velocity have been varied to understand their effects on the catalytic performance. In the LaCoO3 type catalyst, the partial substitution of Ba and Sr into A site enhanced the catalytic activity in the reduction of NO.
For the La0.6Ba (Sr)o.4 Co1−x
FexO3 (x=0-1.0) catalyst, the partial substitution of Fe into B site enhanced the conversion of NO, but excess amount of Fe decreased
the conversion of NO. The surface area and catalytic activity of perovskite catalysts prepared by malic acid method showed
higher values than those of solid reaction method. The conversion of NO increased with increasing O2 concentration and contact time. The introduction of water into reactant feed decreased the catalytic activity but the deactivation
was shown to be reversible over La0.6Ba0.4Co1−x
,FexO3 catalyst. 相似文献
43.
The decomposition of 2,4-dichlorophenoxyacetic acid in aqueous solutions has bsen studied using ozone and ultraviolet radiation at different pH, ozone production, and initial concentration of pesticide. A mathematical model which incorporates the rate of mass transfer of ozone, the oxidation kinetics of 2,4-D and the kinetics of formation and oxidation of the intermediates was used. A global rate constant was calculated and an empirical equation which correlated that constant with ozone production, initial concentration of 2,4-D and pH at the same temperature was determined. 相似文献
44.
Electrochemical cell current requirements for toxic organic waste destruction in Ce(IV)-mediated electrochemical oxidation process 总被引:1,自引:0,他引:1
Vasily V. Kokovkin Sang Joon Chung Subramanian Balaji Manickam Matheswaran Il-Shik Moon 《Korean Journal of Chemical Engineering》2007,24(5):749-756
The electrochemical cell for cerium oxidation and reactor for organic destruction are the most important operation units for
the successful working mediated electrochemical oxidation (MEO) process. In this study, electrochemical cells with DSA electrodes
of two types, single stack and double stack connected in series, were used. The performances towards the electrochemical generation
of Ce(IV) in nitric acid media at 80 °C were studied. The current-voltage curves and cerium electrolysis kinetics showed the
dependence on number of cell stacks needed to be connected in series for the destruction of a given quantity of organic pollutant.
The presence of an optimum region for Ce(III) oxidation with a contribution of oxygen evolution, especially at low Ce(III)
concentration (high conversion ratios), was found. The cells were applied for the Ce(IV) regeneration during the organic destruction.
The cell and reactor processes were fitted in a simple model proposed and used to calculate the current needed in terms of
Ce(III) oxidation rate and the number of cell stacks required for maintaining Ce(IV)/Ce(III) ratio at the same level during
the organic destruction. This consideration was based on the kinetic model previously developed by us for the organic destruction
in the MEO process. 相似文献
45.
Environmental etch damage to automotive coatings, and scratch and mar of these coatings are an important element of customer satisfaction as well as a significant warranty repair consideration for automotive companies. The conditions that result in environmental etch are examined and a laboratory test proposed. Data from this test are compared to automotive hoods exposed in Florida. The performance of various crosslinking chemistries is discussed and the requirements for improved environmental etch are outlined. Scratch and mar performance of these systems is also reviewed. We have found that coatings respond to physical stress by elastic recovery, by plastic flow and by brittle fracture. Classifying types of damage in this way is important for understanding the chemistry needed for improved scratch and mar of coatings. 相似文献
46.
The process of ozonation of glyoxal in aqueous solution has been studied by following its chemical and kinetic evolution. Results show that the oxidative process leads to formation of carboxylic functions and carbon dioxide according to a constant selectivity ratio at varying conversion degree.. Comparison between the oxygen amounts of reaction products and the corresponding ozone consumptions reveals that molecular oxygen takes part in the reaction process. System behavior is explained on the basis of radical reaction mechanism. 相似文献
47.
Y. B. Che Man L. S. Wei A. I. Nelson N. Yamashita 《Journal of the American Oil Chemists' Society》1991,68(7):471-473
Soaking soybeans in dilute acids affected activities of lipoxygenase, trypsin inhibitor and urease. Effects of soaking time,
acid concentration and soaking temperature were investigated. Lipoxygenase activity was completely eliminated by soaking in
0.3 M HC1 at either 23°C or 40°C for 8 hr. Less than 50% trypsin inhibitor remained and urease was inactivated to an acceptable
level (0.04 ΔpH). 相似文献
48.
Maritza F. Díaz Gómez Goitybell Martínez Téllez Maikel Arteaga Cruz Rafael Garcés Mancheno 《Journal of the American Oil Chemists' Society》2006,83(11):943-946
Ozonized theobroma fat is used as raw material in the manufacture of pessaries and cosmetic creams. Ozonization of theobroma
fat with water was carried out at different applied ozone dosages, and the resultant PV, acid value, iodine value, total hydroperoxide
content, and FA content were determined. PV and total hydroperoxide content showed a notable increase with applied ozone dosage
up to 35.7 mg/g. Acid value varied slightly from 4.1 to 9.9 mg KOH/g, and the iodine value fell to zero. PV and total hydroperoxide
content increased slightly with a higher applied ozone dosage. The comparison of total hydroperoxide measurement using ferrous
oxidation in xylenol orange assay and traditional iodometric assay for PV determination showed a significant linear correlation.
Small amounts of oleic acid were found in ozonized theobroma fat samples with iodine value equaling zero, which demonstrated
that iodine value determination is an inexact assay. During ozonization of theobroma fat, an increase in acid value of 18.9-fold
with respect to the initial value was observed owing to decomposition of peroxide. 相似文献
49.
Sung-Yong Cho Seung-Shik Park Seung-Jai Kim Tae-Young Kim 《Korean Journal of Chemical Engineering》2006,23(4):638-644
Adsorption and desorption characteristics of the 2-methyl-4-chlorophenoxyacetic acid (MCPA) from aqueous solution onto the
activated carbon (GAC, F-400) were studied. Adsorption equilibrium capacities of the MCPA increased with decreasing pH and
temperature of the solution. Adsorption equilibrium of the MCPA could be represented by the Sips equation. The internal diffusion
coefficients were determined by comparing the experimental concentration decay curves with those predicted from surface diffusion
model and pore diffusion model. The adsorption model based on the linear driving force approximation (LDFA) was used for simulating
the adsorption behavior of the MCPA in a fixed bed. Over ninety five percent desorption of the MCPA could be obtained using
distilled water. 相似文献
50.