野外试验场黄土的理化分析

本实验为低,中水平放射性废物浅地层处置安全评价提供现场土壤的物理化学参数。采样深度在０．５－９．１ｍ范围内,每个样品进行１０项测定;矿物组成,粒度分布、密度、总孔隙度、有效孔隙度、给水度、持水度、渗透系数、阳离子交换容量、含水量。     

Molecular Formation upon Ionization of van der Waals Clusters and Implication to Astrochemistry

The presence and formation of a large variety of organic molecules in the interstellar medium is evident from both astronomical data of absorption and emission bands at different regions of the spectrum. Specifically, polycyclic aromatic hydrocarbons (PAHs) are ubiquitous in the interstellar medium (ISM). The mechanism for their formation in ISM‘s low temperature environment is, as of yet, a mystery nonetheless. Understanding the mechanism of formation of complex molecules such as PAHs and nitrogen-based PAHs (PANH) in the ISM is a long-standing challenge which has been drawing a growing attention for the past several decades. In this review we wish to emphasize two things: Firstly, the essential role quantum chemistry can play in the study of astrochemical reactions. Secondly, we wish to demonstrate that said variety of possibilities for chemical reaction, starting upon ionization of van der Waals clusters. The potential for different chemical reactions to occur within a cluster environment arises from the fact that such processes can take place at low temperatures as the systems pose large amounts of energy upon ionization. Moreover, the spectator molecules in the cluster can provide a dissipation route for energy by detachment from the cluster, thus the system can stabilize efficiently even at low densities. The spectator molecules can also change the potential energy surface, by which it will pose a catalytic effect for certain reactions. We will demonstrate this by presenting Ab Initio Molecular Dynamic results on ionization of small acetylene clusters.     

On the use of 1g physical models for ground movements and soil-structure interaction problems

The paper focusses on the use of physical modelling in ground movements (induced by underground cavity collapse or mining/tunnelling) and associated soil-structure interaction issues. The paper presents first an overview of using 1g physical models to solve geotechnical problems and soil-structure interactions related to vertical ground movements. Then the 1g physical modelling application is illustrated to study the development of damage in masonry structure due to subsidence and cavity collapse. A large-scale 1g physical model with a 6 m³ container and 15 electric jacks is presented with the use of a three-dimensional (3D) image correlation technique. The influence of structure position on the subsidence trough is analysed in terms of crack density and damage level. The obtained results can improve the methodology and practice for evaluation of damage in masonry structures. Nevertheless, ideal physical model is difficult to achieve. Thus, future improvement of physical models (analogue materials and instrumentation) could provide new opportunities for using 1g physical models in geotechnical and soil-structure applications and research projects.     

Protium removal from deuterium-tritium mixture with displacement chromatography method: Experiments and simulations

The displacement chromatography technique with a tri-column system was used to reduce the protium (H) in the deuterium-tritium (D-T) mixture, and the separation performance was studied numerically by ANSYS FLUENT. The experimental results showed that the isotopic abundance of H in the D-T mixture dropped from 2.7% to an acceptable level of 0.88%. The simulation results showed that a lower porosity (θ) of the filling material made a higher separation factor, but a lower separation efficiency. The velocity of the product gas at the outlet of the separation column approximately had a linear relationship with θ^5/3/(1-θ)², which partly indicated the pore diffusion resistance. The mixed gas could contact the filling materials more sufficiently under a lower flow rate resulting in a lower protium concentration in the product gas. The separation column with a thin and long shape had a better separation performance and a lower product gas loss.     

Do men and women really live in different taste worlds?

In this review, I highlight what is currently known about the sensory, psychological, and physical/nutritional, differences between men and women in terms of their sensory-discriminative and hedonic responses to multisensory tasting experiences. However, despite the evidence for there being numerous individual differences in tasting, few neatly support the claim that men and women live in different worlds of taste. Perhaps the only situation in which consumed products directed specifically at men and women would appear to succeed is when they are advertised as providing some sort of nutritional benefit to the end user.     

Characteristics of the medical waste generated at the Jordanian hospitals

Recently, Jordan has witnessed increased amounts of medical waste generated at different healthcare facilities. This has resulted in issuance of Medical Waste Regulation that aimed at regulating the management processes of such hazardous waste. To provide information on medical waste generation rates, composition and statistical characteristics, a comprehensive sampling survey was initiated after a regulatory definition of the medical waste was established. Hospitals from Public, private and educational categories were covered by the survey. This paper presents the findings of the survey. The average generation rates ranged from 0.29 to 1.36 kg/bed/day, while in terms of patient numbers it is from 0.36 to 0.87 kg/patient/day. The total daily amount of medical waste generated at the Jordanian hospitals was estimated to be 6 tones/day. The daily amounts of medical waste generated at King Abdullah University Hospital were found to follow a log normal probability distribution. Physical composition analysis of the medical waste, which conducted based on the categories identified by the Jordanian Regulation, indicated that the infectious waste category is the highest, followed by sharps category and finally pathological, cytotoxic and pharmaceutical categories were the lowest. The study concluded that all hospitals covered by the survey are practicing segregation of hazardous medical waste from general medical waste. However, the segregation process in some hospitals is still inefficient and there is a potential for improvements toward minimizing the hazardous medical waste generation.     

Physical and chemical properties and adsorption type of activated carbon prepared from plum kernels by NaOH activation

Activated carbon was prepared from plum kernels by NaOH activation at six different NaOH/char ratios. The physical properties including the BET surface area, the total pore volume, the micropore ratio, the pore diameter, the burn-off, and the scanning electron microscope (SEM) observation as well as the chemical properties, namely elemental analysis and temperature programmed desorption (TPD), were measured. The results revealed a two-stage activation process: stage 1 activated carbons were obtained at NaOH/char ratios of 0-1, surface pyrolysis being the main reaction; stage 2 activated carbons were obtained at NaOH/char ratios of 2-4, etching and swelling being the main reactions. The physical properties of stage 2 activated carbons were similar, and specific area was from 1478 to 1887m(2)g(-1). The results of reaction mechanism of NaOH activation revealed that it was apparently because of the loss ratio of elements C, H, and O in the activated carbon, and the variations in the surface functional groups and the physical properties. The adsorption of the above activated carbons on phenol and three kinds of dyes (MB, BB1, and AB74) were used for an isotherm equilibrium adsorption study. The data fitted the Langmuir isotherm equation. Various kinds of adsorbents showed different adsorption types; separation factor (R(L)) was used to determine the level of favorability of the adsorption type. In this work, activated carbons prepared by NaOH activation were evaluated in terms of their physical properties, chemical properties, and adsorption type; and activated carbon PKN2 was found to have most application potential.     

Friction factor correlation and pressure loss of single-phase flow inside herringbone microfin tubes

Pressure drop of single-phase turbulent flow inside herringbone microfin tubes of different fin dimensions has been measured experimentally to develop a general correlation of single-phase friction factor for the herringbone tubes. Water has been used as a working fluid and the mass flow rate has been varied from 0.03 to 0.2 kg/s, where the Reynolds number range is 10⁴ to 6.5 × 10⁴. Comparison of experimental data of the herringbone microfin tubes with those of helical microfin and smooth tubes shows that pressure drop of the herringbone tube is significantly higher than the helical and smooth tubes depending on the fin geometric parameters and mass velocity of the working fluid. Through semi-analytical approach and using the present experimental data, a new correlation of single-phase friction factor for the herringbone microfin tubes has been proposed incorporating the effects of fin geometric parameters. The proposed correlation can predict the experimental data within ±10%.     

Experimental thermal performance study of an inclined heat pipe heat exchanger operating in high humid tropical HVAC systems

In an earlier paper [Y.H. Yau, Application of a heat pipe heat exchanger to dehumidification enhancement in tropical HVAC systems – a baseline performance characteristics study, International Journal of Thermal Sciences 46 (2) (2007) 164–171], the author had established the baseline performance characteristics of the eight-row wickless heat pipe heat exchanger (HPHX) for a vertical configuration under a range of conditions appropriate for a tropical climate. Now, the same basic experimental set-up was to be used in the present research with the HPHX tilted 30°. In this configuration, the gravitational force would be expected to enhance drainage of any condensation forming on the extended fin surfaces of the HPHX evaporator section, and therefore, the effectiveness of the HPHX could be anticipated to be better than the vertical configuration, particularly when processing inlet air with high RH. The investigation has been carried out for 32 experiments with typically high RH and the results are presented in this paper. The results suggested that the possibly adverse influence of condensate forming on the fins of the HPHX was negligible, and therefore the HPHX in a typically-used vertical configuration could perform equally as well as it would if the HPHX was installed in an inclined position.     

从动螺旋伞齿轮精锻成形的物理模拟及数值模拟研究

通过对从动螺旋伞齿轮的精锻成形过程进行物理模拟和数值模拟研究,分析了成形过程中齿轮齿形的填充情况、等效应力等效应变的分布以及金属内部质点的流动规律,得出了从动螺旋伞齿轮精锻过程的金属流动规律,揭示了从动螺旋伞齿轮精锻过程的变形机理,物理模拟结果与数值模拟结果吻合。