生物降解型聚碳酸顺丁烯二酸亚乙酯 1、合成和表征

用CO_2、环氧乙烷、顺丁烯二酸酐进行三元共聚首次得到聚碳酸顺丁烯二酸亚乙酯(PECM),并用IR、~1H NMR、DSC等进行了表征,共聚物链中CO_2和MA单元随机分布,不饱和单元可在0～0.5mol分数之间调节。共聚过程不发生双键交联和构型转化。环氧乙烷的转化率可高达到93％。控制PECM链上的双键含量并使之发生自由基加成反应,得到对热较稳定的可溶性产物。     

A theory for the formation of tetrahedral amorphous carbon including deposition rate effects

A theoretical model is presented to describe the effect of ion beam bombardment rate on the formation of tetrahedral amorphous carbon (ta-C) films. The critical ion energy, E_c, corresponding to a 50% sp³ content in the films, is found to be dependent on both the effective thermal resistance and the ion beam bombardment rate. In the model, the ‘window’ width in the ion energy scale for the formation of ta-C material increases with decreasing deposition rate and with a reduction in the effective thermal resistance, until limited by lower and upper boundary thresholds. Experimental data are reproduced by the model. The plasmon energy, which correlates with sp³ fraction, is found experimentally of be higher for lower deposition rate and smaller effective thermal resistance. Data points for high sp³ content ta-C films deposited on silicon substrates at room temperature occupy a region in the ion energy-deposition rate (E-r) diagram similar to that predicated from the theory.     

1477 nm LD泵浦掺铒光纤放大器的研究

报道了采用１４７７ｎｍ激光二极管（ＬＤ）泵浦的掺铒光纤放大器的实验结果。研究了放大器的增益和时域特性。对１５２０ｎｍ的信号光，获得了２３ｄＢ的增益，泵浦效率为２．２８ｄＢ／ｍＷ。低频脉冲信号经过放大器后未发生波形畸变。     

被动锁模复合环形腔掺饵光纤激光器的自启动分析

本文对被动锁模复合环形腔掺饵光纤激光器的自启动工作特性进行了分析，指出谐振腔内残余反射面的存在是阻碍激光器实现自启动锁模的主要原因。利用半导体激光器有源区的折射率随注入电流的变化而改变的特性，在谐振腔中获得了一个可移动腔镜，克服了腔内残余反射面的影响，实现了锁模的自启动。     

Evolution of BET internal surface area in glassy carbon powder during thermal oxidation

It is demonstrated that glassy carbon powder can be thermochemically activated. During activation, a film with open pores is created on the glassy carbon particles. This film has a large internal surface area, which is accessible to liquids and gases. A simple model for the evolution of the internal surface area in glassy carbon powder during thermochemical gas-phase oxidation is also presented and compared with experimental data. Experimental results are in qualitative agreement with the model. We found that a sharp particle size distribution is desirable with regard to potential technical applications.     

钱塘江光缆管穿越施工技术

钱塘江光缆管穿越长度2454.15m,穿越深度为32m,穿越中采用了多项新技术、新工艺、新方法。文章介绍了导向孔对穿技术、套管技术、水下磁场电缆铺设技术、长距离泥浆回流技术、长距离穿越钻杆组合技术在钱塘江光缆管穿越施工中的应用。     

Vinyl acetate monomer—a pilot plant study

The kinetics of the reaction of acetic acid and acetylene over zinc acetate-activated carbon catalyst was investigated over a wide range of process variables in a pilot reactor. Although various catalytic reaction mechanisms were postulated, the rate of reaction was most satisfactorily correlated by a mechanism of surface reaction between charged adsorbed acetic acid and acetylene, which assumes that the rate controlling step was the irreversible charged adsorption of acetylene and acetic acid.     

气相色谱在线分析变压吸附法制纯氢中的总碳

利用带镍加氢转化炉的气相色谱仪 ,在线分析变压吸附法制纯氢中的总碳。该法用变压吸附法制的纯氢作燃气 ,在检测器前端将氢气中的CO和CO2 转化为CH4,然后用氢火焰离子化检测器检测 ,直接以检测器的信号 (mV)进行定量。当氢气中总碳体积分数在 1 9～ 5 0 0 μl/L时 ,FID信号值与总碳体积分数有良好的线性关系。方法回收率为 99 90 %～ 10 1 9%,相对标准偏差 <1%。     

超高相对分子质量聚乙烯纤维研究进展

介绍了超高分子质量聚乙烯纤维的制备、表面改性及应用的研究进展 ,指出了今后超高分子质量聚乙烯纤维的研究及应用的发展方向