制备工艺对碳纤维增强碳化硅基复合材料结构和力学性能的影响

以化学气相沉积碳为界面层,聚碳硅烷为先驱体,经过10个周期的浸渍-裂解制备了三维编织碳纤维增强碳化硅复合材料(3D-Cf/SiC)。考察了碳涂层高温预处理和陶瓷先驱体第一个周期1600℃裂解对复合材料结构与性能的影响。结果表明:碳涂层高温预处理有助于复合材料密度的提高,弱化了复合材料的界面结合,从而显著提高了复合材料的力学性能,复合材料弯曲强度达到571 MPa,剪切强度51 MPa,断裂韧性18 MPa.m1/2。     

含B2O3无氟连铸保护渣物理性能的研究

常规保护渣中配入的助熔剂一般是氟化物和Na2O,但二者都对环境产生严重污染。为此试验研究了含助熔剂B2O3保护渣及其熔点、粘度、结晶性能和表面张力等物理性能。试验表明，当保护渣碱度(CaO/SiO2)等于0．88，成分(％)为37．91CaO-43.09SiO2—5Al2O3—5MgO-2Li2O-7B2O3时的熔点909℃，熔化性温度1160℃，1300℃粘度值0．40Pa．s,1300℃表面张力值0．32N/m，能满足常规钢种和部分特殊钢种对连铸保护渣的使用要求。     

A system for powder transport based on piezoelectrically excited ultrasonic progressive waves

The transport and dosage of granular materials are an important part of Process Engineering. Thereby, the food, chemical, pharmaceutical and coating industries set high demands on the transport and dosage performances of the used plants. In this context, Ultrasound Process Technology in the past years has developed itself into an attractive alternative compared to presently used classical technologies.

This paper describes the application of ultrasonic progressive waves in a powder-feeding device. The use of a specific pipe material with appropriate damping characteristics allows to generate a progressive wave using a single piezoelectric actuator. Small objects can be carried along the surface of a pipe by the elliptic motion at the surface, which is the result of a flexural progressive wave. The operational principle is the same as in travelling wave ultrasonic motors.

It was experimentally confirmed that the device can be used for feeding and supplying small amounts of powder. The powder-fed performance, however, strongly depends on environmental conditions, so that a control of the system is required. Construction and characteristics of a trial device are shown.     

Study of TiN/BN bilayers produced by pulsed arc plasma

Bilayers of TiN/BN were produced by using a PAPVD (Plasma Assisted Physical Vapor Deposition) pulsed vacuum arc system. The equipment is formed by a reactor composed by a vacuum chamber with two face-to-face electrodes and an RLC circuit to produce the arc discharge. To obtain the BN coating a target of h-BN was used placed on the cathode and a substrates of silicon placed on the anode. The work gas was nitrogen at a pressure of 4.4×10⁻¹ mbar and a voltage of 240 V. In order to improve the adherence of the BN film, an interlayer of TiN was grown. In this case the chamber was filled with N₂ to produce the TiN coating, with a pressure of 1.7 mbar and a voltage of 300 V. By means of XRD (X-ray diffraction), the existence of TiN was determined finding different crystalline orientation in FCC phase. An FTIR (Fourier Transform Infrared Spectroscopy) was employed to determine sp³/sp² bonding ratio in the BN film.By plotting I-V curves the electrical properties of the bilayer were studied, observing a semiconductor behavior and this result was compared to the silicon substrate without coating.     

Processing of Net‐shaped Nanocrystalline Fe‐Ni Material

Development of nanoparticulate materials technology is essential to processing of highly functional nanoparticulate materials and components with small and complex shape. This paper provides an overview on our recent investigations on the processing of net‐shaped nanocrystalline Fe‐Ni powder and related material property such as mechanical property. The key‐processing concept is the synthesis of nanopowders and subsequent consolidation with controlled microstructure by using powder injection molding (PIM) process. Especially, the pressureless sintering process is inevitable for consolidation of the PIMed nanopowder. The present review focuses on the densification process and related mechanical property of the PIMed Fe‐Ni nanopowder in association with microstructural evolution and diffusion process.     

粉末——粘结剂两相流模型的碰撞分析与计算机模拟

分析了粉末注射成形中粉末—粘结剂两相流动中粒子(颗粒与分子)碰撞的情况。假设粉末颗粒完全由粘结剂包裹,在成形阶段将粉末颗粒视为非完全弹性体,给出了粉末—粘结剂两相流动模型中碰撞项的碰撞模式,简化了粉末—粘结剂固液两相流动模型的一般方程。为进一步对粉末—粘结剂两相流动进行计算机数值模拟和分析粉末—粘结剂两相分离现象奠定了理论基础。     

Computerized relational model for powder technology: powder and process selection

Part of a complete expert-system software design for powder technology is presented. This part of the system deals with powder selection according to predetermined, recommended or required material properties, and specific powder characteristics. Then the optimum powder production, i.e processing, method is determined, which satisfies the requirements of the specified powder. For this purpose a detailed database relational model is developed, and the system's software modules are described. A relational model is formulated and a structured query language (SQL) is used in the detailed software design presented.     

纳米结构陶瓷涂层的外圆磨削力以及磨削表面精度的实验研究

使用功率计监测磨削加工的能量消耗，探讨了纳米结构陶瓷涂层的外圆磨削过程；对纳米陶瓷涂层和传统陶瓷涂层在磨削力和磨削表面精度方面进行了比较．磨削实验使用了外圆磨床和陶瓷结合剂金刚石砂轮．通过测量主轴功率获得切向磨削力，讨论了加工参数，如切深、进给率以及砂轮粒度对切向磨削力的影响．还对磨削后的涂层表面用粗糙度仪和扫描电镜进行了评估，揭示了表面粗糙度与加工参数的关系．     

化学镀Ni-W-P-SiC复合镀层的性能研究

研究了化学镀Ni W P SiC复合镀层的性能。结果表明,该化学复合镀层在HCl、H2SO4、H3PO4和FeCl34种腐蚀介质中的耐蚀性优于1Cr18Ni9Ti不锈钢的,经600℃以下热处理的镀层的耐蚀性优于镀态镀层的,其中400℃热处理后镀层的耐蚀性最好。镀层硬度和耐磨性随温度的升高而升高,在400～600℃之间硬度和耐磨性都较高,加热温度继续升高,镀层硬度和耐磨性下降较快。在400℃热处理条件下,随着热处理时间的延长,镀层的硬度和耐磨性提高,当热处理时间达到3h时,镀层硬度和耐磨性最高,若继续延长时间,镀层的硬度和耐磨性又降低。     

纳米TiO2和紫外线吸收剂对丙烯酸酯涂层抗光氧化性能的影响

讨论了锐钛矿型和金红石型纳米TiO2以及2．4-二羟基二苯甲酮和2-(2-二羟基-5-苯甲基)苯并三唑等有机紫外线吸收剂的光活性．并借助失重分析和SEM分析探讨它们对丙烯酸复合涂层抗光氧化性能的影响。UV分析表明：2，4-二羟基二苯甲酮、2-(2-二羟基-5-苯甲基)苯并三唑等有机紫外线吸收剂对400nm以下的紫外线有强烈的吸收作用；金红石和锐钛矿型纳米TiO2对紫外线也有较强烈的吸收和散射作用，紫外光透过率低。且有机紫外线吸收剂随着辐射时间的延长会分解失效，而纳米TiO2较稳定。失重分析和SEM分析结果显示：锐钛矿型纳米TiO2具有光催化性，加速丙烯酸酯聚合物的光降解，而金红石型纳米TiO2则是一种有效的遮光剂。同时添加金红石型纳米TiO2和有机紫外线吸收剂能更有效提高丙烯酸酯复合涂层的抗光氧化性能。