Calorimetric determination of the enthalpy change for the binding of methyl orange to poly(vinylpyrrolidone) in aqueous solution

Thermodynamic parameters have been determined for the interaction of methyl orange and poly(vinylpyrrolidone) in aqueous solutions containing tris, tris and hydrochloric acid, or water only. Enthalpy changes were determined by use of a flow microcalorimeter. Free energy changes were calculated from the results of equilbrium dialysis studies. The results are interpreted in terms of the behaviour of poly(vinylpyrrolidone) in these systems. Analysis of data shows that the hydrophobic interactions in the systems are in the order: tris > wateronly > tris-HC1.     

50W CO_2激光雕刻机控制系统

介绍非金属材料表面加工的CO2激光雕刻机的基本原理其控制系统。     

云南锰矿选矿现状与前景分析

云南锰矿资源丰富,具有品位高、低磷低铁、易选等特点。文章概述了斗南、鹤庆、建水等锰矿的选矿科研进展情况,三个锰矿均可采用强磁选或磁-重选流程选别,可提高品位8—12％;精矿含锰可达33—35％,锰回收率在80％以上的好结果。     

混合结构楼房爆破拆除倒塌范围的确定

通过对混合结构楼房爆破倾倒过程特点的分析,提出了楼房在倾倒过程中的运动计算模型,并应用体积平衡原理,得到这类楼房爆破爆堆参数计算公式,用该公式计算的结果与实例中爆堆实测数据相比较,相对误差不超过11%.     

羰基铁类随机混合吸波材料等效电磁参数的计算

本文为计及多重散射偶极子间的相互作用，引入参量εｈ和μｈ，导得一组公式。它不仅能计算铁氧体类也能计算羰基铁类的随机混合吸波材料的等效电磁参数，均与实验结果吻合良好。     

均匀设计在遗传算法中的应用研究

通过分析均匀设计和遗传算法的内在关系，指出从某个角度上可以把均匀设计看作是遗传算法的一种特例，并针对遗传算法初始参数众多、难配置的问题，提出了利用均匀设计优化配置选择参数的方法，在一定程度上可以避免遗传算法参数配置的盲目性．仿真试验结果证明了该方法是合理、可行的。     

宣汉——达县地区飞仙关组储层预测方法研究

在宣汉-达县地区,以往仅依据地震属性来预测飞仙关组储层分布,钻探结果与实际情况不符,为此本文提出量化分析预测结合主参数分析的新方法和新思路。在量化分析中首先对飞仙关组储层进行高分辨率反演,获得储能系数图;然后结合主振幅剖面和主频率剖面分析,对储层进行预测。在研究区,本方法的预测结果与实钻情况相吻合。     

Color characteristics of Cu-Zn-Al alloys

ＣＯＬＯＲＣＨＡＲＡＣＴＥＲＩＳＴＩＣＳＯＦＣｕ－Ｚｎ－ＡｌＡＬＬＯＹＳ￣①Ｌｉ，Ｂａｏｍｉａｎ；Ｚｈａｎｇ，Ｘｉｕｈｕａ（ＳｈｅｎｙａｎｇＩｎｓｔｉｔｕｔｅｏｆＧｏｌｄＴｅｃｈｎｏｌｏｇｙ，Ｓｈｅｎｙａｎｇ１１００１５）ＣＯＬＯＲＣＨＡＲＡＣＴＥＲ...     

Structural and electrical properties of brush plated ZnTe films

Zinc telluride thin films were deposited by the brush plating technique at a potential of −0.90 V (SCE) on conducting glass and titanium substrates at different temperatures in the range 30–90 °C. The films were polycrystalline in nature with peaks corresponding to the cubic phase. Direct band gap of 2.30 eV was observed. XPS studiers indicated the formation of ZnTe. Depth profiling studies indicated a uniform distribution of Zn and Te throughout the entire thickness. EDAX measurements were made on the films and it was found that there was a slight excess of Te. The carrier concentration was found to vary from 10¹⁴–10¹⁵ cm⁻³ with increase of substrate temperature. The mobility was found to vary from 5 to 60 cm² V⁻¹ s⁻¹.     

Testing of electrochromic materials using symmetrical devices

“Symmetric materials” devices, where both electrodes are made of the same electrochromic materials, allow the in situ study of side reactions. Each transferred charge that is not used for the expected electrochromic reaction will cause a colour change in the whole symmetric device. Two electrochromic materials, WO₃ and IrO₂, are successively used to show how to obtain information about side reactions such as faradaic efficiency, reversibility and potential limits from the symmetric experiment. This in situ approach with a polymer electrolyte shows significant differences compared to results obtained with studies in aqueous electrolytes.