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41.
42.
Erika von Schneidemesser Tauseef A. Quraishi James J. Schauer 《The Science of the total environment》2010,408(7):1640-1648
Aerosol mass (PM10 and PM2.5) and detailed elemental composition were measured in monthly composites during the calendar year of 2007 at a site in Lahore, Pakistan. Elemental analysis revealed extremely high concentrations of Pb (4.4 μg m− 3), Zn (12 μg m− 3), Cd (0.077 μg m− 3), and several other toxic metals. A significant fraction of the concentration of Pb (84%), Zn (98%), and Cd (90%) was contained in the fine particulate fraction (PM2.5 and smaller); in addition, Zn and Cd were largely (≥ 60%) water soluble. The 2007 annual average PM10 mass concentration was 340 μg m− 3, which is well above the WHO guideline of 20 μg m− 3. Dust sources were found to contribute on average (maximum) 41% (70%) of PM10 mass and 14% (29%) of PM2.5 mass on a monthly basis. Seasonally, concentrations were found to be lowest during the monsoon season (July-September). Principle component analysis identified seven factors, which combined explained 91% of the variance of the measured components of PM10. These factors included three industrial sources, re-suspended soil, mobile sources, and two regional secondary aerosol sources likely from coal and/or biomass burning. The majority of the Pb was found to be associated with one industrial source, along with a number of other toxic metals including As and Cr. Cadmium, another toxic metal, was found at concentrations 16 times higher than the maximum exposure level recommended by the World Health Organization, and was concentrated in one industrial source that was also associated with Zn. These results highlight the importance of focusing control strategies not only on reducing PM mass concentration, but also on the reduction of toxic components of the PM as well, to most effectively protect human health and the environment. 相似文献
43.
ROBOT软件在特种结构计算中的应用 总被引:2,自引:0,他引:2
结合实例介绍有限元结构分析软件ROBOT在特种结构空间分析中的应用。 相似文献
44.
中山陵园风景区系统分析及其格局重组与完善 总被引:6,自引:0,他引:6
在对中山陵园风景区进行系统分析的基础上,明确存在问题与价值取向,并着重就该风景区格局的重组与完善提出对策。 相似文献
45.
The computer model developed has been used successfully for studying the large pipe-bending problem frequently encountered in offshore structural engineering. The pipe-soil interaction is modelled by using the Coulomb friction law. The modified finite element approach coupled with a modified tangent stiffness procedure is used to handle the nonlinearities (geometric and material, etc.) in the problem. The material nonlinearity has been considered both by the plastic-hinge method and by an elastic-plastic method. Before studying the practical problems, sufficient check problems were analysed and a good agreement was found between theoretically exact solutions and the results obtained from the developed computer model. 相似文献
46.
应用ANSYS软件对某公司设计的新型澄清池结构建立了三维有限元模型,进行了静力、模态和地震反应谱分析,着重对该结构在地震荷载作用下的安全性进行了研究,对原设计方案的锥体壁厚进行了优化计算。 相似文献
47.
A field-portable anion exchange resin method (often cited as the Ficklin method (1983)) has been extensively used to distinguish between dissolved arsenite (As(III)) and arsenate (As(V)) species in natural waters. As(III) occurs largely as As(OH)(3), which is uncharged at ca. pH 7, while As(V) is negatively charged and will sorb to the resin. However, we show that negatively charged As(III)-sulfide (thioarsenite) species, important at sulfide concentrations >10 microM, also bind to the anion exchange resins, and therefore might be interpreted incorrectly as As(V). Furthermore, we show that nitrogen-purging, which results in a conversion of As(III)-sulfides to arsenite, can be used to obtain accurate arsenic speciation when resins are used on sulfidic water samples. 相似文献
48.
R. Pietra U. Wtjen E. Sabbioni M. Gallorini G.P. Tartaglia 《The Science of the total environment》1994,150(1-3)
Tungsten carbide and cobalt are the main components of hard metal alloy while other metals such as chromium, niobium, tantalum, titanium and vanadium are sometimes added in smaller amounts. Exposure to hard metal dusts can induce a lung fibrosis with cobalt playing a major role. In order to provide information on the role that each metal may have in causing this disease, determination of the total content and the distribution of inhaled metals in lung tissue of hard metal workers is of paramount importance. However, samples such as transbronchial biopsy and bronchoalveolar lavage (BAL), often used in the medical diagnosis of pneumoconiosis, only allow for a small amount of material. This calls for sensitive and accurate analytical procedures for microdetermination and distribution of metals in pulmonary tissue and cellular material, such as macrophages. This work proposes a combination of sophisticated analytical techniques such as neutron activation analysis (NAA), currently applied to the determination of the total concentration of more than 30 elements in biological specimens, and PIXE analysis, particularly microPIXE, which has a great potential for microdistribution analysis in small biological samples. Principles and perspectives for the combined use of these techniques for the analysis of human tissue are outlined and discussed. NAA: determination of hard metals in lung tissue are carried out by neutron irradiation (2 × 1014 neutrons cm−2 s−1) in the HFR reactor of Petten. After neutron activation, radiochemical separations of 60Co, 187W, 182Ta, 51Cr followed by computer-based high resolution gamma ray spectrometry allow the measurement of these elements in pulmonary tissues with sensitivities ranging from 10−4 μg (Cr) to 10−6 μg (W). PIXE: this technique is multielemental and of relatively high sensitivity (μg/g) even in small total sample masses of from 10 to 100 μg, thus allowing the analysis of parts of needle biopsies. Whereas PIXE has been successfully applied to many medical problems, its usefulness is limited in the total samples analysis for cobalt-related hard metal disease, due to the low levels of cobalt in tissue combined with severe element interferences from the generally more abundant metal, iron. Nevertheless, microPIXE, a special variety of the method scanning over the sample with a focussed ion beam of about 2 × 2 μm2, could complement the NAA findings in total samples in the sense of achieving a microdistribution analysis of hard metals (including cobalt) in suitable thin tissue sections.The availability of specialized facilities at the JRC such as the powerful HFR reactor (Petten), the NAA laboratories (Ispra) and the microPIXE facility (Geel) could represent a European ‘reference pole’ for the study of metals in tissues of hard metal diseased subjects. 相似文献
49.
50.
The aim of this study is to analyse and compare three variants of a family house in order to evaluate the total environmental impacts produced during the whole building life cycle. The first variant corresponds to the standard in force in Switzerland, the second alternative to the requirements of a quality control label for houses with low energy consumption and the third case is a very low energy consumption building. The three variants have the same architectural aspect but different insulation thicknesses and types, different energy production systems and the use of different renewable energies. The calculation of the environmental impacts is carried out by means of a life cycle analysis, which includes not only the impact related to the energy consumption during the occupancy stage, but also the materials manufacture, transport, replacement and elimination at the end of the building lifetime. The results are expressed with the Swiss and the UCTE (Union for the Co-ordination of Transmission of Electricity) electricity mix to analyse how they influence the building impact. 相似文献