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Duygu Kocaefe;Julie Bureau;Armita Rastegari;Karthikeyan Rajan;Yasar Kocaefe; 《加拿大化工杂志》2024,102(1):129-142
Aluminium is produced by electrolysis using carbon anodes. These anodes are manufactured with dry aggregate (mainly calcined petroleum coke, butts, and rejected green and baked anodes) and coal tar pitch, which acts as a binder. Utilization of good quality anodes decreases the consumption of carbon and energy, hence the process cost as well as the emission of greenhouse gases (GHG). The interactions between coke and pitch play an important role in determining the anode quality. If they are compatible, pitch can penetrate into the pores of the coke particles as well as into the voids between the particles, resulting in denser anodes. One way to improve these interactions is to modify the chemical composition of pitch using an additive. The objective of this study is to investigate the effect of the pitch type on the effectiveness of pitch modification in improving the anode properties. Two types of pitch with different quinoline insoluble (QI) contents were used: one with high QI (HQI pitch) and the other with low QI (LQI pitch). They were modified using the same additive. The interactions between the pitches and the coke were studied by measuring the wettability of coke by the pitches. The pitch chemical composition was studied using FTIR and XPS. Then, anodes were produced and characterized. Their apparent density, electrical resistivity, air and CO2 reactivities, and permeability were compared. The results showed that the properties of anodes produced using modified HQI pitch were improved. Modifying LQI pitch did not significantly improve the anode properties. 相似文献
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Primary or True QIs, and also the so-called ‘dirt’ were separated from seven tar sources available in Canada from four different steel companies, by filtering hot tar solution of quinoline and other good solvents. After washing with quinoline and acetone and drying, the filter cake was examined under scanning electron microscope (SEM) and analysed for inorganic impurities by wave length and energy dispersive X-ray spectrometers. A limited amount of work was carried out on a production pitch blend, utilizing optical microscopy. After the filtration process, the filtrates which represented the QI free tars were subjected to distillation at atmospheric pressure and various pitches were prepared with a softening point range of 70–100°C. The pitches were dissolved in quinoline and analysed for QIs. The small amount of QI from each pitch was extracted and dispersed with solvent onto a microscope slide. The samples then were subjected to SEM and in one case to optical microscope studies; the sizes and shapes of the QIs were determined and compared with the QIs originally found in the individual tars. Photographs have been taken during the scanning work to record findings which have been considered typical and demonstrative of the findings. In order to gather further information on the role of QI in tars and pitches, particle size distribution was determined of QI extracted from a tar and a production pitch by a Coulter Counter. 相似文献
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Xinying LI Bo HUANG Yufeng SHAO Junwen ZHANG Shumin ZOU Wuliang FANG Li TAO Jiangbo ZHU Chi NAN 《中国光电子学前沿》2011,(3)
In this paper,we describe the impact of quadrature imbalance (QI) in the presence of frequency offset in an optical coherent offset quadrature phase shift keying (OQPSK) receiver.Arbitrary conjugate misalignment was realized in a 2×4 90° optical hybrid,and the ellipse correction (EC) method of quadrature imbalance was applied in our simulation.In the case of transmission,the EC method can significantly improve the system performance. 相似文献
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郑长波 《电子技术与软件工程》2021,(15):88-89
本文设计依据电磁感应原理出发,采用IP6808芯片设计了一款电磁感应耦合式的无线手机充电电路,实现了电能的无线传输,传输效率可以达到80%。本设计电路主要由桥式整流电路、滤波电路、高频逆变电路、LC谐振电路、整流变换电路、恒压充电电路、发射线圈和接收线圈等相关电路构成。 相似文献