2-羟基-3-烯丙氧基丙磺酸钠的合成

采用新方法合成了2-羟基-3-烯丙氧基丙磺酸钠。先由环氧氯丙烷和亚硫酸氢钠合成中间体3-氯-2-羟基丙磺酸钠，然后中间体再与丙烯醇在氢氧化钠催化下生成目标产物2-羟基-3-烯丙氧基丙磺酸钠。2步反应总收率在70％左右，中间体和产物分别进行了光谱表征。     

Detonation velocity of BTNEN/Al

The effect of the addition of Al on the detonation velocity of bis(2,2,2-trinitroethyl) nitramine (BTNEN) was studied experimentally. It is shown that the dependence of the detonation velocity of BTNEN on the initial density is nearly linear, and a 75/25 BTNEN/Al mixture is characterized by an increase in the slope of the dependence with increasing density. The addition of Al decreases the detonation velocity of BTNEN. The density range characterized by a maximum decrease in the detonation velocity is determined. A comparison of experimental detonation velocities of BTNEN/Al mixtures with literature data obtained by calculations taking into account a possible change in the phase state of Al₂O₃ showed that the thermodynamic model used in the calculations needs to be improved. __________ Translated from Fizika Goreniya i Vzryva, Vol. 42, No. 4, pp. 125–130, July–August, 2006.     

移动视频通信业务的应用研究

移动视频通信业务是通过移动网络和移动终端为移动用户提供的一种新型通信服务。本文主要研究了基于3G和Vo LTE技术的移动视频通信业务的应用。分别从技术、资费、用户体验、互通性四个方面对两种移动视频通信业务进行了分析和对比。     

水中"一锅"合成7,7-二甲基-4-(3-氯苯基)-5-氧代-3,4,5,6,7,8-六氢香豆素的洁净方法

研究了四丁基溴化铵(TBAB)催化下的水介质中,3-氯苯甲醛、丙二酸亚异丙酯和5,5-二甲基-1,3-环己二酮三组分缩合,一步合成系列7,7-二甲基-4-(3-氯苯基)-5-氧代-3,4,5,6,7,8-六氢香豆素。产物的结构经IR和1HNMR进行了表征确证。该方法具有反应条件温和、操作简便、环境友好的优点。     

基于Flash 3D的在线虚拟漫游系统设计与实现

对目前虚拟漫游系统的瓶颈进行分析,提出并实现了一个基于Flash 3D的、优化了的在线虚拟旅游系统。系统对三维场景文件包括模型文件、材质文件及其构建步骤进行优化,并在实现了对多种媒体元素支持的基础上,设计了独创的热点系统,实现对三维场景按需进行加载和展示,以及游客在场景中的互动漫游。系统测试结果表明,该设计方案优化效果显著,系统性能得到了极大的提升。     

基于糊模ID3算法的高校学生流失数据挖掘研究

目前高校不断扩招,生源却逐渐减少,于是预防和减少学生流失正成为各高校必须面对的问题。通过对高校学生流失情况进行数据挖掘,可发现一些有价值的信息,为解决高校学生流失问题提供帮助。基于糊模理论提出了糊模ID3算法,并将该算法运用于分析高校学生流失原因之中。通过实验证明,该算法生成的决策树更加合理,分类速度更快,为解决高校学生流失问题提供了理论依据。     

2-氯甲基-4-甲氧基-3,5-二甲基吡啶盐酸盐的合成

2,3,5 三甲基吡啶用双氧水/冰醋酸氧化制得2,3,5 三甲基吡啶 N 氧化物,收率91%;该氧化吡啶与发烟硝酸/浓硫酸反应得4 硝基 2,3,5 三甲基吡啶 N 氧化物,收率80 4%;将其与甲醇钠反应得到4 甲氧基 2,3,5 三甲基吡啶 N 氧化物,收率91%;4 甲氧基 2,3,5 三甲基吡啶 N 氧化物与乙酸酐反应得到2 乙酰基氧甲基 4 甲氧基 3,5 二甲基吡啶,收率66 6%;2 乙酰基氧甲基 4 甲氧基 3,5 二甲基吡啶在碱性条件下水解得2 羟甲基 4 甲氧基 3,5 二甲基吡啶,收率93%;再用氯化亚砜氯代制得2 氯甲基 4 甲氧基 3,5 二甲基吡啶盐酸盐,收率90 6%。通过TLC、IR、1HNMR对产物进行了表征。     

4-乙基-2,3-双氧哌嗪酰氯的提取及分析

用双-三氯甲基碳酸酯(三光气)代替光气和4-乙基-2,3-双氧哌嗪发生酰氯化反应制备哌嗪酰氯(EOCP),反应液用硅醚提取,得到产品4-乙基-2,3-双氧哌嗪.反应收率可达92.28%,产品纯度为82.49%.     

The SMSI between supported platinum and CeO2–ZrO2–La2O3 mixed oxides in oxidative atmosphere

CeO₂–ZrO₂–La₂O₃ (CZL) mixed oxides were prepared by citric acid sol–gel method. The as-received gel was calcined at 500, 700, 900 and 1050 °C to obtain the so-called C5, C7, C9 and CK, respectively. The C5, C7 and C9 powders were impregnated with H₂PtCl₆ and then calcined at 500 °C to prepare P5C5, P5C7 and P5C9, respectively. The impregnated CK powders were calcined at 500, 700 and 900 °C to prepare P5CK, P7CK and P9CK, respectively. The XRD and XPS analyses show that the surface distribution of Pt is evidently influenced by the structural and textural properties of the support. The CO adsorption followed by FTIR reveals that the dispersion and the chemisorption sites of Pt are reduced as the calcination temperature of CZL support increases. The chemisorption ability of the CK samples is even completely deactivated. The encapsulation mechanism, which has been applied to explain the so-called strong metal–support interaction (SMSI) after reductive treatment, is introduced here to demonstrate the abnormal observations though the samples were prepared in oxidative atmosphere. The HRTEM results also confirm this explanation. The effects of oxygen vacancies, the chemisorption sites on the Pt surface and Pt/Ce interfacial sites on the three-way catalytic activities are discussed.     

微波辅助合成1-(3-羟丙基)-4-哌啶酮

以3-羟基丙胺和丙烯酸甲酯为起始原料,在微波辅助下进行Michael加成、Dieckmann环合和脱羧反应合成了1-(3-羟丙基)-4-哌啶酮.并对Michael加成、Dieckmann环合和脱羧反应的工艺参数进行了优化,通过核磁共振波谱对目标化合物和中间体的结构进行表征.得到的最优Michael加成工艺条件为:n(3-羟基丙胺):n(丙烯酸甲酯)=1.0:2.4,微波辐射功率为120 W,反应温度40℃,反应时间30 min.在该条件下制备3-[(2-甲氧羰乙基)(3-羟丙基)氨基]丙酸甲酯的收率为92.6％;在微波辐射功率为200 W下,Dieckmann环合反应和脱羧反应分别为20和25 min,以88.5％的收率得到1-(3-羟丙基)-4-哌啶酮;目标产物总收率为82.0％.