宽频带函数波形产生器的研制

本文介绍以ＭＡＸ０３８为基础而研制的宽频带函数波形产生器，它可以产生２￣２×＾７Ｈｚ频率范围的正弦波、三角波、锯齿波和矩形波以及与它们同步的ＴＴＬ脉冲信号。     

Effect of supports on the redox performance of pyrite cinder in chemical looping combustion

Chemical looping combustion (CLC) is a clean and efficient flame-free combustion technology,which combust the fuels by lattice oxygen from a solid oxygen carrier with inherent CO2 capture.The develop-ment of oxygen carriers with low cost and high redox performance is crucial to the whole efficiency of CLC process.As the solid by-product from the sulfuric acid production,pyrite cinder presented excellent redox performance as an oxygen carrier in CLC process.The main components in pyrite cinder are Fe2O3,CaSO4,Al2O3 and SiO2 in which Fe2O3 is the active component to provide lattice oxygen.In order to sys-tematic investigate the functions of supports (CaSO4,Al2O3 and SiO2) in pyrite cinder,three oxygen car-riers (Fe2O3-CaSO4,Fe2O3-Al2O3 and Fe2O3-SiO2) were prepared and evaluated in this study.The results showed that Fe2O3-CaSO4 displayed high redox activity and cycling stability in the multiple redox cycles.However,both Fe2O3-Al2O3 and Fe2O3-SiO2 experienced serious deactivation during redox reactions.It indicated that the inert Fe-Si solid solution (Fe2SiO4) was formed in the spent Fe2O3-SiO2 sample,which decreased the oxygen carrying capacity of this sample.The XPS results showed that the oxygen species on the surface of Fe2O3-CaSO4 could be fully recovered after the 20 redox cycles.It can be concluded that CaSO4 is the key to the high redox activity and cycling stability of pyrite cinder.     

High cycle fatigue behaviour of Ti–6Al–4V alloy at elevated temperatures

High cycle fatigue behaviour of Ti–6Al–4V alloy was studied at 623 K and 723 K. Fatigue strength decreased at elevated temperatures compared with at ambient temperature. In the short life regime, fatigue strength was lower at 723 K than at 623 K, but in the long life regime it was nearly the same at both temperatures. At elevated temperatures, cracks were generated earlier at applied stresses below the fatigue limit at ambient temperature, indicating lowered crack initiation resistance. Small cracks grew faster at elevated temperatures than at ambient temperature, which became more noticeable with increasing temperature. After allowing for the elastic modulus, small cracks still grew faster at elevated temperatures.     

Modelling water flow,nitrogen transport and root uptake including physical non-equilibrium and optimization of the root water potential

A model is presented for the simulation of water flow, heat flow, and nitrate and ammonium transport. Two approaches are used for modelling plant water uptake as well as for plant nitrogen uptake. Nitrogen transformations are accounted for in a very simple way. This paper focuses mainly on water flow modelling, solute transport, and water uptake. Richards' equation is used to model water flow in layered soil profiles with a great variety of boundary conditions. Solute transport is simulated with either a simple convection dispersion equation or with a two-region physical non-equilibrium model to distinguish between mobile and immobile water and solute exchange between these two regions. A macroscopic sink term is added to Richards' equation to account for plant water uptake. This term can be calculated along two different approaches, one of which is based on the concept of root water potential. The root water potential is then continuously optimized to minimize the difference between the climatic demand and the uptake rate.Simulation results are compared with field data from the Netherlands to illustrate the degree to which the model is able to predict water flow, solute transport and plant water uptake. The root water potential optimization model seems to provide the best prediction of water distribution. In particular the shape of the profile, revealing uptake patterns, is quite well reproduced with this model. Comparison of simulated and observed water content profiles seems also to reveal the presence of preferential pathways. The comparisons show also how predicted solute distributions can be improved by using a two-region approach rather than a simple convection-dispersion model.     

基于改进的BASS模型的服装产品生命周期研究

为提高服装的销售预测准确度,通过产品的生命周期曲线模型,使得服装销售预测的定性分析与定量预测有机地结合在一起。针对目前服装产品生命周期曲线模型的局限性,引入改进的BASS模型,对服装产品生命周期进行研究。通过销售实例探讨改进的BASS模型用于描述服装生命周期的可行性,建立了以改进的BASS模型为基础的服装产品生命周期模型,并利用该模型对服装销售量做预测,取得了比其他模型更高的精度。     

考虑过程能力和成本的刀具策略研究

为了提高定期维修的刀具所加工的产品质量,减少停机时间和生产成本.考虑生产过程中工件尺寸的残差是时间的函数,利用Glejser检验方法,拟合工件尺寸残差符合的递增型异方差模型,提出了刀具磨损过程的过程能力指数计算方法;使用Bernstein概率密度函数描述刀具寿命和刀具磨损过程的一般特征,在每一个维修周期内均满足顾客要求的最小过程能力指数基础上,考虑质量损失、换刀成本、由刀具的突然失效引发的惩罚成本及维修刀具所需的成本,将过程能力与成本相结合,提出了用于确定最佳刀具初始状态和维修周期的模型.该模型为实际生产提供了一种离线的刀具管理方法.     

Electrocatalytic activity of oxidation products of guanine and 5′-GMP towards the oxidation of NADH

We have studied the potential electrocatalytic activity towards the oxidation of NADH of several oxidation products of guanine and its derivative guanosine-5′-monophosphate (5′-GMP) on pyrolytic graphite electrodes (PGE). The distribution of products generated strongly depends on the experimental conditions. Our investigations focused on the oxidation products that are adsorbed on the electrode surface, are redox active and, exhibited electrocatalytic activity toward the oxidation of NADH. These compounds were electrochemically and kinetically characterized in terms of dependence of the formal potential on pH and electron transfer rate constant (k_s). The voltammetric and catalytic behavior of both guanine and 5′-GMP oxidation products was compared with that of other guanine derivatives we have previously studied. Some mechanistic aspects concerning the generation of the catalysts are also discussed.     

Radical entry mechanisms in redox-initiated emulsion polymerizations

The mechanisms and kinetics of radical entry in emulsion polymerizations utilizing redox initiation are investigated using polymerization rate data obtained by reaction calorimetry and electrospray mass spectroscopy analysis of initiator-derived aqueous-phase products. These data have been used to evaluate an initiation scheme for redox-initiated emulsion polymerizations of common monomers such as styrene and methyl methacrylate based around the oxidant, tert-butyl hydroperoxide. Redox initiators are broadly classed by the solubility of their radical products: Hydrophilic radicals enter by propagating to a critical degree of polymerization to become surface-active whilst more hydrophobic radicals may enter particles directly. When direct entry is applicable (the hydrophobic case), initiation efficiency will always be very high.     

核电站数字化反应堆保护系统停堆响应时间分析

为了评价出核电站数字化反应堆保护系统停堆响应的最大时间,根据数字化反应堆保护系统结构,分析出保护系统的响应过程须经过AI输入、IO总线通讯、CPU运算、网络通讯、DO输出处理。并基于DCS定周期扫描的运行方式,得出了各处理过程所需最大响应时间的计算方法,DCS停堆响应时间的评价值就是各部分最大响应时间的累加。最后提出了可缩短响应时间的改进方法。     

一种改进编码器角度解算过程的方法与实现

在机械电子一直是一个热门学科,其目的是通过软件控制机械操作来代替机械的哑巴解决方案。DS-25旋转电子编码器能够很好地与机械电子应用相匹配,其输出为两路标准的sine和cosine曲线,通过分析sine和cosine数值来计算编码器所对应的绝对角度位置。通过对DS-25的工作模式分析和实际应用情况提出角度解算的改进方案,该方案利用DS-25工作于粗略模式下测试到的角度值来推算精确模式下的信号周期,结合精确模式下测试到的角度值来计算编码器所对应的绝对角度。摒弃其原有的复杂查表过程进而节省电子表格的存储空间,在降低硬件成本的同时提升了软件灵活性。实验证明,算法的改进能够节省约2KB的存储空间,角度位置误差能控制在1‰以内。