全文获取类型
收费全文 | 2550篇 |
免费 | 194篇 |
国内免费 | 28篇 |
专业分类
电工技术 | 21篇 |
综合类 | 105篇 |
化学工业 | 460篇 |
金属工艺 | 42篇 |
机械仪表 | 56篇 |
建筑科学 | 24篇 |
矿业工程 | 24篇 |
能源动力 | 69篇 |
轻工业 | 1747篇 |
水利工程 | 9篇 |
石油天然气 | 30篇 |
武器工业 | 2篇 |
无线电 | 29篇 |
一般工业技术 | 59篇 |
冶金工业 | 45篇 |
原子能技术 | 5篇 |
自动化技术 | 45篇 |
出版年
2024年 | 21篇 |
2023年 | 43篇 |
2022年 | 89篇 |
2021年 | 99篇 |
2020年 | 93篇 |
2019年 | 78篇 |
2018年 | 77篇 |
2017年 | 93篇 |
2016年 | 89篇 |
2015年 | 104篇 |
2014年 | 113篇 |
2013年 | 150篇 |
2012年 | 179篇 |
2011年 | 202篇 |
2010年 | 107篇 |
2009年 | 115篇 |
2008年 | 104篇 |
2007年 | 140篇 |
2006年 | 142篇 |
2005年 | 91篇 |
2004年 | 83篇 |
2003年 | 73篇 |
2002年 | 69篇 |
2001年 | 69篇 |
2000年 | 68篇 |
1999年 | 59篇 |
1998年 | 37篇 |
1997年 | 30篇 |
1996年 | 29篇 |
1995年 | 19篇 |
1994年 | 30篇 |
1993年 | 13篇 |
1992年 | 11篇 |
1991年 | 7篇 |
1990年 | 4篇 |
1989年 | 8篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 8篇 |
1984年 | 4篇 |
1982年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 2篇 |
1975年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有2772条查询结果,搜索用时 15 毫秒
11.
BiologicalEffectsofFlammulinaVelutipesRichinREonChineseKunmingMiceLiangDingbang(梁定邦);CuiDefang(崔德芳);ZhangJintong(张金桐)(Departm... 相似文献
12.
耐热钢在还原性气氛下工作时,常发生粉化剥落现象.经分析与实体零件的宏观与微观组织观察,此现象是因为还原介质渗入,引起合金体积膨胀而产生引力,造成应力裂纹.加入与介质结合力不强的元素铝,有阻碍介质渗入和扩散的作用. 相似文献
13.
Marta Martinez-Garcia Winnie Dejonghe Lieve Cauwenberghs Miranda Maesen Karolien Vanbroekhoven Yamini Satyawali 《European Journal of Lipid Science and Technology》2021,123(2):2000225
Glucose- and xylose laurate esters are enzymatically synthesized using equimolar substrate concentrations in 2-methyl-2-butanol, comparing free lauric acid with methyl- and vinyl-laurate as acyl donors. All reactions result in ≥70% acyl donor conversions after 72 h but the activated donors are also partially hydrolyzed to lauric acid, highlighting the difficulty in controlling water presence in this particular reaction system. The esterification of xylose generates a complex product profile, with several regioisomers of monoesters and diesters. The esterification of glucose is quite selective, forming mainly the 6-O monoester (≥96%) with a small presence of two diester isomers (4%). Increasing substrate concentration up to 800 millimoles kg−1 results in lower conversion values (down to 58%) but shows that the reaction proceeds successfully even in the presence of high amounts of insoluble glucose. However, the reaction is less selective and the proportion of diester increases, becoming up to 46% (molar fraction) of the final product. Solvent recovery after esterification can be achieved by organic solvent nanofiltration through a polymeric membrane able to retain ≥80% of all reaction substrates and products. Practical Applications: The use of high substrate concentrations during the enzymatic synthesis of sugar ester biosurfactants leads to product titers that are more industrially appealing, without the need to find a solvent that can solubilize all initial substrate. The sustainability of the enzymatic conversion at mild temperatures can be enhanced by recycling of the reaction solvent through organic solvent nanofiltration, an energy efficient alternative to other traditional methods like distillation. 相似文献
14.
Maltose long-chain fatty acid esters (MFAE), esterified at the 6 and 6′ position, were synthesized with stearic, palmitic,
myristic, and oleic groups. Synthesis yields were 15–20% based on initial maltose present, and structural confirmation was
obtained using plasma desorption mass spectrometry and nuclear magnetic resonance spectroscopy. These surfactants have surface
tensions in the range of 34–36 dyn/cm at their critical micelle concentrations (CMC) of approximately 10−5–10−6 mol/L. The increased chain lengths have a marked effect, reducing CMC values for MFAE by approximately three orders of magnitude
over similar carbohydrate-based dodecyl chain sources. Within chain lengths between 14 and 18 carbons, the rate of change
in CMC is significant and decreases with increasing chain length for MFAE. The melting points of MFAE are approximately 40°C,
and the heat capacities range from 1.6 to 1.9 J/g·K. These numbers are comparable to those of sucrose esters, indicating their
applicability in similar uses. However, because MFAE, unlike sucrose, possess an anomeric carbohydrate carbon position, these
surfactants maintain their reducing nature and are susceptible to further derivatization. They are also synthesized from renewable,
economical carbohydrates and lipids and may provide an excellent alternative to pertrochemical-derived products. 相似文献
15.
Dorota Johansson Björn Bergenståhl 《Journal of the American Oil Chemists' Society》1992,69(8):728-733
The influence of water on the interactions between fat and sugar crystals dispersed in triglyceride (vegetable) oils was qualitatively
estimated from sedimentation and rheological experiments. The experiments were performed both with and without food emulsifiers
(monoglycerides and lecithins) present in the oil. The effects of minor natural oil components (nontriglycerides) on the interactions
and on emulsifier adsorption to the crystals were examined by comparing a commercial refined oil and a chromatographically
purified oil. The results show that water generally increases the adhesion between fat and sugar crystals in oils and also
increases the surface activity of the oil-soluble food emulsifiers. Minor oil components give a small increase in the adhesion
between fat and sugar crystals in oils, but do not influence the adsorption of food emulsifiers in any systematic way. 相似文献
16.
核苷酸生产技术现状及展望 总被引:14,自引:0,他引:14
核苷酸的生产方法主要有化学合成法、RNA酶解法、微生物发酵法以及生物催化法。探讨了这些方法的原理和发展及其在工业化生产中的优劣势。化学合成法的路线长、立体选择性差,所用试剂昂贵并有一定毒性,生产成本较高;酶解法能一次得到4种核苷酸的混合物且收率较高,是目前我国核苷酸工业生产所用的主要技术,但其后提取难度大,产品纯度不高;微生物发酵法难以解决细胞通透性的问题;生物催化法是发酵法的延伸,菌体培养和酶催化反应分两步进行,有效地解决了细胞通透性问题,并可以通过偶联不同的基因工程菌株生产多种复杂核苷酸、核苷糖乃至寡聚糖,这在核苷酸工业、医药及糖化学、糖生物学合成工业中是极其重要的一个环节。 相似文献
17.
LIUHuilin RENXiangyang YUANCuiju LIYong SHENWeiping 《中国耐火材料》2004,13(2):29-32
Special grade bauxite and roll scale were used as raw materials to investigate the influences of reducing atmosphere and firing temperature on sintering clinker. The results showed that: 1) The mixture of the materials could be sintered enough to synthesise hercynite under reducing atmosphere by adding reducing reagent ; 2) The hercynite dinker could be sintered to high density and the content of FeAl2O4 may attain 80~90% under the firing tempera-ture of 1550℃. 相似文献
18.
19.
It is necessary to study the effect of dyebath additives on decolorization efficiency in order to optimize ozone-based decolorization processes as the consumption of ozone can be reduced through selecting ozone favorable additives. The effect of 5 dyebath additives viz. electrolytes (sodium chloride and sodium sulfate), chelating agent (ethylene diamine tetra acetic acid or EDTA), reducing agent (sodium dithionite), optical brightener (Uvitex BHT), and dispersing agent (Zetex DNVL) was investigated. All of the additives showed synergistic effect as addition of sodium chloride, sodium dithionite and Zetex DN-VL markedly improved decolorization efficiency, but EDTA and optical brightener showed negative effect. Sodium sulfate did not show any positive or negative effect on decolorization efficiency. 相似文献
20.
针对甘蔗种植信息化管理的需求,在模型.视图-视图模型(MVVM)设计模式下,运用Windows Presentation Founda-tion(WPF)技术开发基于农业物联网的甘蔗种植管理系统的后台管理软件,拟实现甘蔗种植地图管理、采集数据查询、田地信息管理和种植户管理等功能。重点描述后台管理系统的设计架构和MVVM框架在系统搭建时的运用,并对实现过程中的MVVMLight运用,NHibernate实现对象与数据库映射等关键技术进行解析。系统能正常稳定运行,有较好的稳定性和适用性,可为种植甘蔗提供科学依据。 相似文献