Study of Compatibilized Liquid Crystalline Polymer/Cyclic Olefin Copolymer Blends

The technology to produce compatibilized blends of liquid crystalline polymer and highly amorphous cyclic olefin copolymers through two novel approaches were studied. The first approach was to use silane-functionalized halloysite nanotube as nonspecific compatibilizer and the second method was reactive compatibilization. The study of blends and their resulting microstructure; their thermal, mechanical, and viscoelastic properties were investigated. The kinetic study of blends compatibilized through both routes was performed.     

Mechanism of smoke suppression by melamine in rigid polyurethane foam

The smoke suppression of rigid polyurethane foam (RPUF) modified by melamine was investigated based on three sections: the condensed phase, the carbon layer, and the gas phase. In the condensed phase, the results of thermogravimetry, X‐ray photoelectron spectroscopy (XPS) N1S spectrum, and Fourier transform infrared spectroscopy indicated that melamine could suppress the degradation of RPUF by reacting with the aromatic hydrocarbons. It also reduced the smoke generation because the volatilizable aromatic hydrocarbons were the principal smoke precursors in a fire. In the carbon layer, the decrease from 38.50% to 24.76% of the inner layer oxygen content identified by XPS full‐spectrum and C1S spectrum indicated that melamine could prevent oxygen from transferring into the inner foam by the formation of an enhanced surface carbon layer, and the enhanced carbon layer could also block the release of smoke precursors. In the gas phase, the content of total aromatic hydrocarbons declined to 59.12% according to pyrolysis gaseous chromatography mass spectroscopy and indicated that melamine could reduce the smoke precursors. The results of smoke density chamber and cone calorimeter tests revealed that the addition of the melamine could decrease the smoke density of burning RPUF. Copyright © 2014 John Wiley & Sons, Ltd.     

柯克亚油气田混合来源天然气的地球化学特征

柯克亚油气田是我国开发比较早的一个油气田,但由于受混源和其他因素的影响,对气源的认识众说纷纭。通过对天然气的地球化学特征的分析,并参照国内外关于甲烷、乙烷、丙烷碳同位素关系方面的资料,提出了如下看法:柯克亚天然气碳同位素相对较重,与塔里木盆地下古生界海相天然气的碳同位素组成区别较大;根据天然气40Ar/36Ar组成,柯克亚油气田的气源不是单一来源;柯克亚油气田绝大多数天然气的甲烷和乙烷碳同位素值关系符合Faber推断的 型有机质方程直线关系,说明有机质属于较好的有机质类型,或者是由原油裂解形成的天然气;除了K2井和K18井天然气成熟度较低以外,绝大多数天然气的成熟度大约在1.8%～2.2%之间,属于高过成熟气,但也混有一些成熟度在0.9%～1.2%的源岩形成的天然气;推测天然气主要来源于石炭系―二叠系源岩,而混有成熟度低的源岩形成的天然气则有可能来自侏罗系源岩。     

Fe3O4/PSt/TiO2多层包覆电磁响应微球的制备

首先采用分散聚合法将自制的Fe3O4磁流体和苯乙烯反应合成有磁核的Fe3O4/PSt磁性聚合物微球，然后，用非均匀成核水解反应在Fe3O4/PSt微球外包覆无定形二氧化钛，获得Fe3O4/PSt/TiO2复合微粒。用红外光谱、扫描电镜和热分析对粒子的形貌和结构进行了表征。并测试了微粒的介电性能和磁性，结果表明，所制得复合微粒有良好的电、磁响应性。     

氧化钨物理特征的测量

对铵钨青铜（ATB）、氢钨青铜（HTB），紫色氧化钨（TVO）和蓝色氧化钨（TBO）四种氧化钨粉的氮气吸附/脱附等温线数据的分析。可以得出其表面积，微孔体积，微孔分布，中孔体积，平均孔径和分数维数。吸附/脱附等温线数据的分析表明，TVO粉末具有最大的中孔体积，最小的微孔体积，最窄的孔径分布，最小的分数维数和最大的平均孔径，其有利于氢还原制取超细钨粉，而不利于掺杂工艺，HTB粉末具有最大的微孔体积，最宽的孔径分布，最高的分数维数和最小的平均孔径，对于掺杂工艺来说是有利的，ATB和ABO的上述参数界于TVO和HTB之间。结果表明，利用吸附/脱附等温线来研究氧化物的物理特征是一个很好的方法；在氧化钨用于氢还原工艺和掺杂工艺之前必须研究其物理特征。     

人骨骼中~(228)Th、~(230)Th和~(232)Th含量的同时测定

本文介绍了用α谱仪同时测定人骨骼中~(228)Th、~(230)Th和~(232)Th含量的方法。样品用浓 HNO_3和 H_2O_3湿灰化,草酸钙共沉淀载带、CL-5208萃淋树脂和743阳离子交换树脂联合分离后,电沉积制源,在低温半导体α谱仪上测量。该方法对~(234)Th的全程回收率为95.0±1.7%,对铀和镭的去污系数分别为6.3×10~4和1.5×10~3,对~(228)Th、~(230)Th、~(232)Th 的探测下限分别为0.432、0.135和0.108Bq/kg(鲜重)。     

Synthesis,characterization and ion exchange properties of zirconium(IV) tungstoiodophosphate,a new cation exchanger

Zirconium(IV) tungstoiodophosphate has been synthesized under a variety of conditions. The most chemically and thermally stable sample is prepared by adding a mixture of aqueous solutions of 0·5 mol L⁻¹ sodium tungstate, potassium iodate and 1 mol L⁻¹ orthophosphoric acid to aqueous solution of 0·1 mol L⁻¹ zirconium(IV) oxychloride. Its ion exchange capacity for Na⁺ and K⁺ was found to be 2·20 and 2·35 meq g⁻¹ dry exchanger, respectively. The material has been characterized on the basis of chemical composition, pH titration, Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis. The effect on the exchange capacity of drying the exchanger at different temperatures has been studied. The analytical importance of the material has been established by quantitative separation of Pb²⁺ from other metal ions.     

QFT control design for an approximately linearized pneumatic positioning system

A block‐oriented approximate feedback linearization for control of a pneumatic cylinder positioning system is introduced and a rather detailed discussion is presented on the uncertain linearization residual characterization. It is shown that making use of the characterized gain–phase information of the linearized system leads to a more reasonable trade‐off between performance and stability in the QFT control design and thus results in high control performance. Simulation and experimental results are shown. Copyright © 2003 John Wiley & Sons, Ltd.     

L-抗坏血酸亚铁的合成及表征

研究了VeCO3的制备以及利用自制的FeCO3与L-抗坏血酸作用合成L-抗坏血酸亚铁.主要探讨了溶剂的用量、反应时间以及温度对产物收率和产品质量的影响.确定了最佳反应条件为:溶剂用量为20mL,时间为120min,反应温度为100℃,产率可达68.1%.并通过x射线能谱和红外吸收光谱等测试手段对产品进行了表征.     

Stability of hydrogenated nanodiamonds under extreme ultraviolet irradiation

It is generally accepted that diamond is resistant to a wide spectrum of electromagnetic radiation from the ultraviolet through to the soft X-ray range, which makes it very attractive for the fabrication of diamond-based photodetectors. However the effect of photon radiation on the diamond structure has not yet been examined. In the work presented here, photoelectron spectroscopy has been used to study the graphitization of nanodiamond crystallites exposed to extreme ultraviolet radiation. Under such irradiation, the surface hydrogen groups and graphite species are found to prevent graphitization. The mechanism of radiation-induced nanodiamond graphitization is discussed.