UHMWPE/蒙脱土纳米复合材料结构与流动性的关系

采用甲基丙烯酰氧乙基三甲基氯化铵对微米尺度的蒙脱土进行离子交换，所得有机蒙脱土与少量引发剂和超高分子量聚乙烯(UHMWPE)共混后，在双螺杆挤出机上进行反应挤出，得到了具有一定流动性能的UHM—WPE／蒙脱土纳米复合材料。该纳米复合材料熔体的流动性能较UHMWPE高出许多；用X衍射、透射电子显微镜等表征方法研究了这种纳米复合材料的相结构，通过稳态和动态流变试验研究了其流变性能与蒙脱土含量的关系，分析了UHMWPE熔体大分子解缠结机理。     

A free space frequency‐time‐domain technique for electromagnetic characterization of materials using reflection‐based measurement

In this report, a free space frequency‐time‐domain technique is presented for characterizing the electrical properties and thickness of the sample using multiple reflections and fabry‐perot resonance phenomenon. The retrieval of constitutive electromagnetic parameters of the sample has been carried out by comparing the measured reflection coefficient data from the sample at two different incident angles. The relative permittivity as well as relative permeability along with the thickness of different samples viz., beryllia, silicon, and plexiglass have been evaluated with high accuracy in the frequency range 1 to 15 GHz. The method is also experimentally validated by successfully reconstructing the unknown material properties of two different samples. The unique advantage of this method lies in non‐requirement of any prior knowledge of the sample's thickness for measuring the complex relative dielectric constant as well as relative permeability of the sample. To determine the electromagnetic properties of the sample, the sole knowledge of reflection coefficient data are needed. Moreover, the method does not involve any additional measurement for the reference calibration. The simple, cost‐effective proposed scheme is quite useful in many applications like accurate determination of signal strength in indoor wireless communication, through wall imaging, food industry, and so on.     

基于双重权重偏差建模的无监督域适应

无监督域适应(Unsupervised Domain Adaptation,UDA)是一类新兴的机器学习范式,其通过对源域知识在无标记目标域上的迁移利用,来促进目标域模型的训练。为建模源域与目标域之间的域分布差异,最大均值差异(Maximum Mean Discrepancy,MMD)建模被广泛应用,其对UDA的性能提升起到了有效的促进作用。然而,这些方法通常忽视了领域之间对应类规模与类分布等结构信息,因为目标域与源域的数据类规模与数据分布通常并非一致。为此,文中提出了一种基于跨域类和数据样本双重加权的无监督域适应模型(Sample weighted and Class weighted based Unsupervised Domain Adaptation Network,SCUDAN)。具体而言,一方面,通过源域类层面的适应性加权来调整源域类权重,以实现源域与目标域之间的类分布对齐;另一方面,通过目标域样本层面的适应性加权来调整目标域样本权重,以实现目标域与源域类中心的对齐。此外,文中还提出了一种CEM(Classification Expectation Maximization)优化算法,以实现对SCUDAN的优化求解。最后,通过对比实验和分析,验证了所提模型和算法的有效性。     

A practical application of photogrammetry to performing rib characterization measurements in an underground coal mine using a DSLR camera

Understanding coal mine rib behavior is important for inferring pillar loading conditions as well as ensuring the safety of miners who are regularly exposed to ribs. Due to the variability in the geometry of underground openings and ground behavior, point measurements often fail to capture the true movement of mine workings. Photogrammetry is a potentially fast, cheap, and precise supplemental measurement tool in comparison to extensometers, tape measures, or laser range meters, but its application in underground coal has been limited. The practical use of photogrammetry was tested at the Safety Research Coal Mine, National Institute for Occupational Safety and Health(NIOSH). A commercially available, digital single-lens reflex(DSLR) camera was used to perform the photogrammetric surveys for the experiment. Several experiments were performed using different lighting conditions, distances to subject,camera settings, and photograph overlaps, with results summarized as follows: the lighting method was found to be insignificant if the scene was appropriately illuminated. It was found that the distance to the subject has a minimal impact on result accuracy, and that camera settings have a significant impact on the photogrammetric quality of images. An increasing photograph resolution was preferable when measuring plane orientations; otherwise a high point cloud density would likely be excessive. Focal ratio(F-stop) changes affect the depth of field and image quality in situations where multiple angles are necessary to survey cleat orientations. Photograph overlap is very important to proper three-dimensional reconstruction, and at least 60% overlap between photograph pairs is ideal to avoid unnecessary post-processing. The suggestions and guidelines proposed are designed to increase the quality of photogrammetry inputs and outputs as well as minimize processing time, and serve as a starting point for an underground coal photogrammetry study.     

高速移动环境下无线信道模型的性能

针对移动网络在高铁通讯时存在接收信号不稳定问题,开展了多普勒效应及多径时延对正弦波叠加(Sum-of-Sinusoid,SOS)模型、XIAO模型(Jakes仿真器)和LIU Qian模型的影响研究.分析了3种模型的信噪比、相关性以及处理信号衰减的程度,结果表明,在多普勒效应及多径时延的环境下,SOS模型的算法复杂度最低,LIU Qian模型反之,而传递函数相关性最佳,XIAO模型对接入信号的衰落程度最小;在保证传输效率、信道容量足够的前提下,LIU Qian模型中接收信号的失真程度较小,更适宜作为高速移动环境下无线信道的研究模型.     

Fractal characterization for the mining crack evolution process of overlying strata based on microseismic monitoring technology

In order to study the evolution laws during the development process of the coal face overburden rock mining-induced fissure,we studied the process of evolution of overburden rock mining-induced fissures and dynamically quantitatively described its fractal laws,based on the high-precision microseismic monitoring method and the nonlinear Fractal Geometry Theory.The results show that:the overburden rock mining-induced fissure fractal dimension experiences two periodic change processes with the coal face advance,namely a Small→ Big→ Small process,which tends to be stable;the functional relationship between the extraction step distance and the overburden rock mining-induced fissure fractal dimension is a cubic curve.The results suggest that the fractal dimension reflects the evolution characteristics of the overburden rock mining-induced fissure,which can be used as an evaluation index of the stability of the overburden rock strata,and it provides theoretical guidance for stability analysis of the overburden rock strata,goaf roof control and the support movements in the mining face.     

Evaluation Indicators and Extraction Method for Pitting Corrosion of Structural Steel

A set of evaluation indicators based on corrosion ratio in theory for assessing the extent of pitting corrosion and performance reduction are proposed. In order to quantify the morphology of pitting co...     

ODPA-ODA型聚醚酰亚胺膜的预氧化机理

为了开发新型高性能炭膜前驱体材料,研究了ODPA-ODA型聚醚酰亚胺膜经430~530℃空气氛围的预氧化机理.借助热重分析、红外光谱、元素分析及x-射线衍射等手段,分析了预氧化温度对预氧化膜的溶解度、柔韧度、表面官能团、元素质量分数及微观结构的影响.结果表明:优化预氧化过程是制备无缺陷高质量炭膜的关键.预氧化可提高热稳定性,形成的交联结构有利于提高残炭量和成膜性.随预处理温度的提高,交联程度提高,但当温度高于490℃时会发生过渡氧化.     

Comparison of TiAIN,AICrN, and AICrN/TiAIN coatings for cutting-tool applications

Monolayer and bilayer coatings of TiAlN, AlCrN, and AlCrN/TiAlN were deposited onto tungsten carbide inserts using the plasma enhanced physical vapor deposition process. The microstructures of the coatings were characterized using scanning electron microscopy （SEM） and atomic force microscopy （AFM）. The SEM micrographs revealed that the AlrN and AlCrN/TiAlN coatings were uniform and highly dense and contained only a limited number of microvoids. The TiAIN coating was non-uniform and highly porous and contained more micro droplets. The hardness and scratch resistance of the specimens were measured using a nanoindentation tester and scratch tester, respectively. Different phases formed in the coatings were analyzed by X-ray diffraction （XRD）. The AlCrN/TiAlN coating exhibited a higher hardness （32.75 GPa）, a higher Young＇s modulus （561.97 GPa）, and superior scratch resistance （LcN = 46 N） compared to conventional coatings such as TiAlN, A1CrN, and TiN.     

锂交换法制备六氟磷酸锂及表征

六氟磷酸和吡啶反应生成吡啶六氟磷酸,吡啶六氟磷酸和氢氧化锂通过锂交换反应生成吡啶六氟磷酸锂,在四氢呋喃溶剂中,吡啶六氟磷酸锂与浓硫酸反应生成六氟磷酸锂。实验研究了溶剂、反应温度、反应时间、配料比等对锂交换反应的影响,得到适宜的工艺条件:65℃反应4 h,原料配比n(C5H5NHPF6)∶n(LiOH)=1.0∶1.0,此条件下吡啶六氟磷酸锂收率94.5%;经核磁共振、红外光谱检测,吡啶六氟磷酸锂和LiPF6是目的产物。